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1. 发明专利

JP2011179012A Catalyst composition for vinyl monomer polymerization, and use thereof for vinyl monomer polymerization using the composition 有权
标题翻译：用于乙烯单体聚合的催化剂组合物及其用于使用组合物的乙烯单体聚合反应
公开(公告)号：JP2011179012A
公开(公告)日：2011-09-15
申请号：JP2011113568
申请日：2011-05-20
申请人： Kuraray Co Ltd , Univ Of Tokyo , 国立大学法人東京大学 , 株式会社クラレ
发明人： NOZAKI KYOKO , YAMASHITA MAKOTO , IDA HIROSHI , UOZUMI TOSHIYA
IPC分类号： C08F4/70 , C08F4/26
摘要： PROBLEM TO BE SOLVED: To provide a vinyl monomer polymerization catalyst having a functional group in a side chain under a milder condition.
SOLUTION: A vinyl monomer is polymerized by using a metal compound having a metallic element of the tenth group of the periodic table, and a phosphine ligand per a metal, or a composition composed of combination of the metal compound and a compound having two or more selected from a group composed of: (a) at least one element selected from the first, the second, the eleventh, the twelfth, the thirteenth, the fifteenth, and the sixteenth group of the periodic table; (b) a 1-20C aliphatic hydrocarbon group optionally having a substituent and/or a 6-40C aromatic hydrocarbon group optionally having a substituent; and (c) a perchloric acid group.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供在较温和的条件下在侧链中具有官能团的乙烯基单体聚合催化剂。解决方案：通过使用具有元素周期表第十族的金属元素的金属化合物和每种金属的膦配位体或由金属化合物和具有选自由以下组成的组中的两个或更多个：（a）选自周期表的第一，第二，第十一，第十二，第十三，第十五和第十六组中的至少一个元素; （b）任选具有取代基的1-20C脂族烃基和/或任选具有取代基的6-40C芳族烃基; 和（c）高氯酸基团。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2006241325A Catalyst composition for vinyl monomer polymerization and use thereof in vinyl monomer polymerization 有权
标题翻译：用于乙烯单体聚合的催化剂组合物及其在乙烯单体聚合中的应用
公开(公告)号：JP2006241325A
公开(公告)日：2006-09-14
申请号：JP2005059697
申请日：2005-03-03
申请人： Kuraray Co Ltd , Univ Of Tokyo , 国立大学法人東京大学 , 株式会社クラレ
发明人： NOZAKI KYOKO , YAMASHITA MAKOTO , IDA HIROSHI , UOZUMI TOSHIYA
IPC分类号： C08F4/62
摘要： PROBLEM TO BE SOLVED: To polymerize a vinyl monomer bearing a functional group in its side chain under a milder condition.
SOLUTION: At least one catalyst selected from the group consisting of metal compounds represented by formulae (I), (II) and (III) (wherein R
1 , R
2 , R
3 , R
4 , R
5 and R
6 are each a specific hydrocarbon group; X
1 , X
2 , X
3 and X
4 are each a specific group; and M
1 and M
2 are each a group 10 element in the periodic table) is used.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：在较温和的条件下，使其侧链上具有官能团的乙烯基单体聚合。解决方案：选自由式（I），（II）和（III）表示的金属化合物（其中R 1，R 2，R 2， SB>，R SB 3，R SB 4，R SB 5和R SB 6各自是特定的烃基; X 1 ，X 2 ，X 3 和X 分别是特定组; M < ＆lt; / SB＆gt;和M＆lt; SB＆gt; 2＆lt; / SB＆gt;各为元素周期表中的10族元素）。版权所有（C）2006，JPO＆NCIPI

3. 发明专利

JP2006241326A Carried catalyst composition for vinyl monomer polymerization and use thereof in vinyl monomer polymerization 有权
标题翻译：用于乙烯单体聚合的载体催化剂组合物及其在乙烯单体聚合中的应用
公开(公告)号：JP2006241326A
公开(公告)日：2006-09-14
申请号：JP2005059699
申请日：2005-03-03
申请人： Kuraray Co Ltd , Univ Of Tokyo , 国立大学法人東京大学 , 株式会社クラレ
发明人： NOZAKI KYOKO , YAMASHITA MAKOTO , IDA HIROSHI , UOZUMI TOSHIYA
IPC分类号： C08F4/70
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for simple isotactic polymerization of a vinyl monomer under a milder condition.
SOLUTION: A vinyl monomer is subjected to isotactic polymerization using a carried catalyst composition for isotactic polymerization of the vinyl monomer comprising at least one selected from the group consisting of metal compounds having one phosphine ligand per metal atom carried on an inorganic or organic carrier, or using a composition comprising a combination of the component above with a compound containing at least two selected from the group consisting of (a) at least one element selected from the group 1, 2, 11, 12, 13, 15 and 16 elements of the periodic table, (b) a 1-20C aliphatic hydrocarbon group and/or a 6-40C aromatic hydrocarbon group and (c) a perchlorate group.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：在较温和的条件下提供用于乙烯基单体的简单全同立构聚合的催化剂。解决方案：乙烯基单体使用负载的乙烯基单体全同立构聚合的催化剂组合物进行全同立构聚合，所述催化剂组合物包含选自由无机或有机物上携带的每个金属原子具有一个膦配位体的金属化合物组成的组中的至少一种载体或使用包含上述组分的组合的组合物与含有至少两种选自以下的化合物的化合物：（a）选自组别1,2,11,12,13,15和16中的至少一种元素元素周期表，（b）1-20C脂族烃基和/或6-40C芳烃基和（c）高氯酸酯基。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2012188413A Process for producing aldehyde, and process for producing alcohol 有权
标题翻译：制备醛类的方法和生产醇的方法
公开(公告)号：JP2012188413A
公开(公告)日：2012-10-04
申请号：JP2011228100
申请日：2011-10-17
申请人： Mitsubishi Chemicals Corp , Univ Of Tokyo , 三菱化学株式会社 , 国立大学法人東京大学
发明人： TANAKA YOSHIYUKI , NOZAKI KYOKO , YAMASHITA MAKOTO
IPC分类号： C07C45/50 , C07B61/00 , C07C47/02 , C07F15/00 , C07F17/02
摘要： PROBLEM TO BE SOLVED: To produce an aldehyde inexpensively by reducing the cost of a catalyst in production of a corresponding aldehyde in high linear selectivity by reacting a raw material olefin having ≥2 carbon atoms with hydrogen and carbon monoxide.SOLUTION: The aldehyde is produced by reacting a raw material olefin having ≥2 carbon atoms with hydrogen and carbon monoxide in the presence of a polydentate ligand originated from an organophosphorus compound and a transition metal complex having a structure represented by formula (a). The molar ratio of the polydentate ligand originated from the organophosphorus compound to the transition metal complex is ≥1 and ≤20. In the formula, M is a group 8 to 10 transition metal of the periodic table, excluding rhodium.
摘要翻译：要解决的问题：通过使具有≥2个碳原子的原料烯烃与氢气和一氧化碳反应，以高线性选择性降低生产相应醛的催化剂的成本，从而廉价地生产醛。解决方案：通过在有机磷化合物的多齿配体和具有由式（a）表示的结构的过渡金属络合物的存在下，使具有≥2个碳原子的原料烯烃与氢气和一氧化碳反应来制备醛）。源自有机磷化合物的多齿配体与过渡金属络合物的摩尔比为≥1且≤20。在该式中，M是周期表的8-10族过渡金属，不包括铑。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2008088247A Method for producing norbornene polymer having fluorosulfonyl group, polymer having sulfonic acid group and electrolyte membrane for fuel cell by using the polymer 审中-公开
标题翻译：生产具有氟聚醚类的正戊烯聚合物的方法，使用聚合物的燃料电池的磺酸类聚合物和电解质膜的制备方法
公开(公告)号：JP2008088247A
公开(公告)日：2008-04-17
申请号：JP2006269306
申请日：2006-09-29
申请人： Asahi Glass Co Ltd , Univ Of Tokyo , 国立大学法人東京大学 , 旭硝子株式会社
发明人： MUROTANI EISUKE , NOZAKI KYOKO , YAMASHITA MAKOTO
IPC分类号： C08F32/08 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a norbornene polymer having a fluorosulfonyl group, and an electrolyte membrane for a fuel cell by using the polymer.
SOLUTION: This method for obtaining a polymer containing a unit expressed by formula (a) is provided by polymerizing a compound expressed by formula (A) by using an organometallic complex catalyst. In the formula, X is methylene, methylmethylene, dimethylmethylene, O or S; Q
F is a polyfluoro divalent organic group; R is H, F or a polyfluoro monovalent organic group; and (k) is 0, 1 or 2.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种通过使用聚合物制备具有氟磺酰基的降冰片烯聚合物的方法和用于燃料电池的电解质膜。解决方案：通过使用有机金属配合物催化剂聚合由式（A）表示的化合物，获得含有式（a）表示的单元的聚合物的方法。在该式中，X是亚甲基，甲基亚甲基，二甲基亚甲基，O或S; Q F 是多氟二价有机基团; R是H，F或多氟一价有机基团; （k）为0，1或2.版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2012065578A Production of tricyclic non-natural type alkaloid using vegetable polyketide synthase 审中-公开
标题翻译：使用蔬菜多糖合成酶生产三磷酸非天然型碱性磷酸酶
公开(公告)号：JP2012065578A
公开(公告)日：2012-04-05
申请号：JP2010212208
申请日：2010-09-22
申请人： Univ Of Tokyo , 国立大学法人東京大学
发明人： ABE IKURO , WAKIMOTO TOSHIYUKI , MORITA HIROYUKI , YAMASHITA MAKOTO
IPC分类号： C12N15/09 , C07D223/20 , C12N1/15 , C12N1/19 , C12N1/21 , C12N5/10 , C12N9/00 , C12P17/10
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a means to make a complicated alkaloid skeleton efficiently and at once under the clean and mild conditions and under the ordinary temperature and normal pressure.SOLUTION: A compound expressed by formula (I) (the definition of substituents in the formula is given in the specification) or its salt is disclosed. A method of producing the compound expressed by the formula (I) includes a process in which a mutation III type polyketide synthase is used as a catalyst, and thereby the condensation reaction of a 2-carbamoyl benzoyl CoA derivative and a malonyl-CoA derivative is carried out.
摘要翻译：要解决的问题：提供一种在清洁和温和的条件下，在常温常压下有效地一次制造复杂的生物碱骨架的手段。解决方案：由式（I）表示的化合物（式中的取代基的定义在说明书中给出）或其盐。制备由式（I）表示的化合物的方法包括使用突变型III型聚酮化合物合酶作为催化剂的方法，由此2-氨基甲酰基苯甲酰基CoA衍生物与丙二酰辅酶A衍生物的缩合反应为执行。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2010215604A Production method of alcohol 有权
标题翻译：生产醇的方法
公开(公告)号：JP2010215604A
公开(公告)日：2010-09-30
申请号：JP2009150069
申请日：2009-06-24
申请人： Mitsubishi Chemicals Corp , Univ Of Tokyo , 三菱化学株式会社 , 国立大学法人東京大学
发明人： TANAKA YOSHIYUKI , NOZAKI KYOKO , YAMASHITA MAKOTO
IPC分类号： C07C29/16 , B01J31/22 , B01J31/24 , B01J37/04 , C07B61/00 , C07C31/12 , C07C31/125
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an alcohol, comprising reacting an olefinic compound with hydrogen and carbon monoxide in the presence of a catalyst, by which the alcohol having high straight chain selectivity can be produced in one step reaction process. SOLUTION: This method for producing the alcohol is characterized by reacting an olefinic compound with hydrogen and carbon monoxide in the presence of a rhodium compound, a bidentate organophosphorous compound, and a compound containing one or more of the group 8 to 10 transition metals in the periodical table excluding rhodium. The reaction is performed in the coexistence of a hydroformylation reaction catalyst comprising a rhodium-bidentate organophosphorous compound for expressing high straight chain selectivity, with one or more group 8 to 10 transition metals in the periodic table excluding the rhodium as a selective hydrogenation reaction catalyst for an aldehyde produced in the reaction system. Thereby, the alcohol largely improved in straight chain selectivity can be produced in one step reaction process. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供一种制备醇的方法，包括在催化剂存在下使烯烃化合物与氢气和一氧化碳反应，通过该催化剂可以在一步反应中产生具有高直链选择性的醇处理。解决方案：该醇的制造方法的特征在于，在铑化合物，二齿有机磷化合物和含有一个或多个第8〜10族转变物的化合物的存在下，使烯烃化合物与氢气和一氧化碳反应金属在周期表中除铑外。该反应在包含用于表现高直链选择性的铑 - 二齿有机亚磷酸化合物的加氢甲酰化反应催化剂与作为选择性氢化反应催化剂的周期表中不包括铑的一种或多种8-10族过渡金属共存下进行在反应体系中产生的醛。因此，可以在一步反应过程中产生大大提高直链选择性的醇。版权所有（C）2010，JPO＆INPIT

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