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    • 1. 发明专利
    • Conductive ink and method for producing the same
    • 导电油墨及其制造方法
    • JP2013072022A
    • 2013-04-22
    • JP2011212749
    • 2011-09-28
    • Kuraray Co Ltd株式会社クラレ
    • YOSHIMOTO JUNICHITSURUTA MIKISUGIOKA TAKASHIOKI HIROYUKI
    • C09D11/00C09D11/52
    • PROBLEM TO BE SOLVED: To provide conductive ink that is favorable in solubility or dispersibility to a solvent containing an organic solvent, is excellent in workability, is useful as a transparent electrode material or the like having high conductivity and transparency, and can be used in inkjet printing.SOLUTION: In the conductive ink, a random copolymer of a thienothiophene compound which may be substituted by an alkyl group or an alkoxy group, and a thiophene compound which may be substituted by an alkyl group or an alkoxy group, and a dopant such as transition metal salt or the like are dispersed or dissolved in a solvent. The copolymer contained in the conductive ink is produced by a chemical oxidative polymerization method under the presence of an oxidizing agent and a surfactant.
    • 要解决的问题:为了提供对含有有机溶剂的溶剂的溶解性或分散性良好的导电性油墨,加工性优异,作为具有高导电性和透明性的透明电极材料等可以使用,可以 用于喷墨打印。 解决方案:在导电油墨中,可以被烷基或烷氧基取代的噻吩并噻吩化合物的无规共聚物和可被烷基或烷氧基取代的噻吩化合物和掺杂剂 如过渡金属盐等分散或溶解在溶剂中。 包含在导电油墨中的共聚物通过化学氧化聚合法在氧化剂和表面活性剂的存在下制备。 版权所有(C)2013,JPO&INPIT
    • 2. 发明专利
    • Metal complex, and method of producing the same
    • 金属复合材料及其制造方法
    • JP2010265245A
    • 2010-11-25
    • JP2009120108
    • 2009-05-18
    • Kuraray Co Ltd株式会社クラレ
    • INUBUSHI YASUTAKAOKI HIROYUKI
    • C07D213/79B01D53/02B01J20/22C07F1/08C07F3/06C07F3/08C07F13/00C07F15/04
    • Y02C10/08Y02C20/10
    • PROBLEM TO BE SOLVED: To provide a material for separating a gas, having excellent capability of separating a gas. SOLUTION: The metal complex includes a dicarboxylic acid compound (I) represented by formula (I); at least one species of metal selected from chromium, molybdenum, tungsten, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, copper, zinc and cadmium; and a bidentate organic ligand capable of coordinating to the metal. In the formula, R 1 , R 2 , R 3 , and R 4 may be the same or different and each represent a hydrogen atom, an alkyl group that may contain a substituent, or a halogen atom, provided that R 1 and R 2 , and R 3 and R 4 together may respectively form an alkylene group, an oxyalkylene group or an alkenylene group, each of which may contain a substituent. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种气体分离材料,具有优异的气体分离能力。 解决方案:金属络合物包括由式(I)表示的二羧酸化合物(I); 选自铬,钼,钨,锰,铁,钌,钴,铑,镍,钯,铜,锌和镉中的至少一种金属; 和能够与金属配位的二齿有机配体。 在该式中,R 1 ,R 2 ,R 3 和R 4 可以相同或不同 并且各自表示氢原子,可以含有取代基的烷基或卤素原子,条件是R 1 和R 2 和R 3 < / SP>和R 4 可以分别形成亚烷基,氧化烯基或亚烯基,每个可以含有取代基。 版权所有(C)2011,JPO&INPIT
    • 3. 发明专利
    • Metal complex and method for producing the same
    • 金属复合物及其制造方法
    • JP2010070546A
    • 2010-04-02
    • JP2009188951
    • 2009-08-18
    • Kuraray Co Ltd株式会社クラレ
    • INUBUSHI YASUTAKAOKI HIROYUKI
    • C07D401/14B01J20/22C07C51/41C07C51/43C07C65/05C07F1/08
    • Y02C10/08
    • PROBLEM TO BE SOLVED: To provide a metal complex usable as a gas adsorber having excellent gas-adsorbing characteristics, a gas-occluding material having a large effective occlusion capacity, and a gas-separating material having excellent gas-separating properties and a large adsorption capacity. SOLUTION: The metal complex comprises 2,5-dihydroxybenzoic acid, at least one of a metal selected from chromium, molybdenum, tungsten, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, copper, zinc and cadmium, and a bidentate ligand (I) represented by general formula (I) (wherein, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are the same or different and each a hydrogen atom, an alkyl group which may have a substituent, or a halogen atom, or R 1 and R 2 , R 3 and R 4 , R 5 and R 6 , and R 7 and R 8 may form an alkylene group, an oxyalkylene group or an alkenylene group which may have a substituent in combination). The method for producing the metal complex is also provided. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供可用作具有优异气体吸附特性的气体吸附器的金属络合物,具有大的有效闭塞能力的气体阻塞材料和具有优异气体分离性能的气体分离材料,以及 吸附能力大。 解决方案:金属络合物包含2,5-二羟基苯甲酸,选自铬,钼,钨,锰,铁,钌,钴,铑,镍,钯,铜,锌和镉中的至少一种, 和由通式(I)表示的二齿配位体(I)(其中R 1,R 2,R SP 3,R SP, > 4 ,R 5 ,R 6 ,R 7 和R 8 不同的和各自为氢原子,可以具有取代基的烷基,或卤素原子,或者R SP2和R SP2, >和R 4 ,R 5 和R 6 和R 7 和R SP>可以组合形成可以具有取代基的亚烷基,氧化烯基或亚烯基。 还提供了生产金属络合物的方法。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Metal complex and method for producing the same
    • 金属复合物及其制造方法
    • JP2010070545A
    • 2010-04-02
    • JP2009188950
    • 2009-08-18
    • Kuraray Co Ltd株式会社クラレ
    • INUBUSHI YASUTAKAOKI HIROYUKI
    • C07D213/06B01J20/22B01J20/30C01B32/40C01B32/50C07C51/347C07C65/05C07F1/08
    • PROBLEM TO BE SOLVED: To provide a metal complex usable as a gas adsorber having excellent gas-adsorbing characteristics, a gas-occluding material having a large effective occlusion capacity, and a gas-separating material having excellent gas-separating properties and a large adsorption capacity.
      SOLUTION: The metal complex comprises 2,5-dihydroxybenzoic acid, at least one kind of a metal selected from chromium, molybdenum, tungsten, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, copper, zinc and cadmium, and a bidentate ligand (I) represented by general formula (I) (wherein, R
      1 , R
      2 , R
      3 and R
      4 are the same or different and each a hydrogen atom, an alkyl group which may have a substituent, or a halogen atom, or R
      1 and R
      2 , and R
      3 and R
      4 may form an alkylene group, an oxyalkylene group or an alkenylene group which may have a substituent in combination; n is 1 or 2; R
      5 , R
      6 , R
      7 and R
      8 are the same or different, and each a hydrogen atom, an alkyl group which may have a substituent, or a halogen atom, or R
      5 and R
      6 , and R
      7 and R
      8 may form an alkylene group, an oxyalkylene group or an alkenylene group in combination). The method for producing the metal complex is also provided.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供可用作具有优异气体吸附特性的气体吸附器的金属络合物,具有大的有效闭塞能力的气体阻塞材料和具有优异气体分离性能的气体分离材料,以及 吸附能力大。 解决方案:金属络合物包含2,5-二羟基苯甲酸,选自铬,钼,钨,锰,铁,钌,钴,铑,镍,钯,铜,锌和镉中的至少一种金属 ,和由通式(I)表示的二齿配位体(I)(其中R 1,R 2,R 3,R 3, SP> 4 相同或不同,各自为氢原子,可具有取代基的烷基或卤素原子,或者R 1为SP&lt; SP&gt; SP>和R 3 和R 4 可以组合形成可以具有取代基的亚烷基,氧化烯基或亚烯基; n为1或2; R 5 ,R 6 ,R 7 和R 8 相同或不同, ,可以具有取代基的烷基或卤素原子,或者R SP5和R SP6,和R 7 和R SP > 8 可以组合形成亚烷基,氧化烯基或亚链烯基)。 还提供了生产金属络合物的方法。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Manufacturing method of membrane-electrode assembly for polymer electrolyte fuel cell
    • 用于聚合物电解质燃料电池的膜电极组件的制造方法
    • JP2008153175A
    • 2008-07-03
    • JP2006342857
    • 2006-12-20
    • Kuraray Co Ltd株式会社クラレ
    • NAKAI SHINJIOKI HIROYUKIONO TOMOHIROKUBO KEIJI
    • H01M8/02H01M8/10
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To enhance cell performance of a membrane-electrode assembly such as an output by improving a joint state of the membrane-electrode assembly, decreasing interface resistance between a membrane and an electrode, and decreasing electric resistance of the membrane-electrode assembly. SOLUTION: The manufacturing method of the membrane-electrode assembly for a polymer electrolyte fuel cell comprising a polymer electrolyte and two gas diffusion electrodes formed by interposing the membrane between the polymer electrolyte membranes and joining them is that the electrolyte membrane and the gas diffusion electrodes are joined and the joint body is immersed in hot water of 55-100°C until the electric resistance of the joint body decreases significantly. When the hot water treatment is conducted in such a state that pressure of 0.1-5 MPs is applied between the membrane and the electrode, effect on decrease in electric resistance and on increase in output are furthermore increased. As the polymer electrolyte membrane, a perfluorocarbon sulfonic acid polymer, a phase separation substance separating a phase having an ion conductive group and that having no ion conductive group, or the like is used. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了通过改善膜 - 电极组件的接合状态来提高诸如输出的膜 - 电极组件的电池性能,降低膜和电极之间的界面电阻,并且降低电阻 膜 - 电极组件。 解决方案:包含聚合物电解质和通过将膜插入聚合物电解质膜并接合它们而形成的两个气体扩散电极的聚合物电解质燃料电池的膜 - 电极组件的制造方法是电解质膜和气体 扩散电极接合,接头体浸入55-100℃的热水中,直到接头体的电阻显着降低。 当在膜和电极之间施加0.1-5MPs的压力的状态下进行热水处理时,电阻降低和输出增加的效果进一步增加。 作为聚合物电解质膜,使用全氟化碳磺酸聚合物,分离具有离子导电性基团且不具有离子传导性基团的相的分离物质等。 版权所有(C)2008,JPO&INPIT
    • 8. 发明专利
    • Ion conductive binder, membrane-electrode assembly and fuel cell
    • 离子导电粘合剂,膜电极组件和燃料电池
    • JP2008004312A
    • 2008-01-10
    • JP2006170666
    • 2006-06-20
    • Kuraray Co Ltd株式会社クラレ
    • NAKAI SHINJIONO TOMOHIROOKI HIROYUKIKUBO KEIJINAKANO TAKESHI
    • H01M4/86C08F297/00H01M8/02H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide an ion conductive binder which is excellent in the electrode reaction efficiency, and is useful in reducing the amount of precious metal catalysts used in the catalyst layer, and in improving the battery efficiency in the membrane-electrode assembly and the solid polymer electrolyte fuel cell. SOLUTION: The ion conductive binder is used for a gas diffusion electrode composing a membrane-electrode assembly for a solid polymer electrolyte fuel cell comprising a polymer electrolyte membrane and two gas diffusion electrodes joined to the electrolyte membrane by sandwiching the membrane, and contains, as components, an aromatic vinyl polymer block (A) such as polystyrene and a rubber-like polymer block (B) consisting of conjugated diene unit or isobutylene unit such as hydrogenated isoprene, butadiene or the like, resulting in a star-shaped block copolymer having ion conductive group being contained which is expressed by the equation (A-B-) n X (X is a residue of coupling agent, and n is any number exceeding 2). COPYRIGHT: (C)2008,JPO&INPIT
    • 解决的问题:提供电极反应效率优异的离子导电性粘合剂,可用于减少催化剂层中使用的贵金属催化剂的使用量,提高电池效率, 电极组件和固体聚合物电解质燃料电池。 解决方案:离子导电粘合剂用于构成用于固体聚合物电解质燃料电池的膜 - 电极组件的气体扩散电极,其包含聚合物电解质膜和通过夹住膜而连接到电解质膜的两个气体扩散电极,以及 含有作为成分的芳香族乙烯基聚合物嵌段(A)如聚苯乙烯和由共轭二烯单元或异丁烯单元如氢化异戊二烯,丁二烯等组成的橡胶状聚合物嵌段(B),形成星形 含有离子导电基团的嵌段共聚物,其由式(AB-)表示:X(X是偶联剂的残基,n是任何数目超过2)。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • Polymer electrolyte membrane for solid polymer fuel cell, membrane-electrode assembly, and fuel cell
    • 用于固体聚合物燃料电池,膜电极组件和燃料电池的聚合物电解质膜
    • JP2007214064A
    • 2007-08-23
    • JP2006034682
    • 2006-02-13
    • Kuraray Co Ltd株式会社クラレ
    • ONO TOMOHIRONAKAI SHINJIOKI HIROYUKI
    • H01M8/02C08F297/00C08J5/22H01B1/06H01M8/10
    • Y02E60/523
    • PROBLEM TO BE SOLVED: To provide a polymer electrolyte membrane or the like for a solid polymer fuel cell which is economical and environment-friendly, and which has high ion conductivity and superior methanol-barrier property. SOLUTION: This is the polymer electrolyte membrane for the solid polymer fuel cell, as well as a membrane-electrode assembly and a solid polymer fuel cell wherein a polymer block (A) has an aromatic vinyl series compound which is made as a repetition unit and in which hydrogen atom bonded to α-carbon atom is either non-substituted or substituted with alkyl group of carbon number 1 to 4, and in which at least one of the hydrogen atoms bonded directly to aromatic ring has been substituted with alkyl group of carbon number 1 to 8, and a flexible polymer block (B) are made as constituents, while a block co-polymer having an ion conductive group is contained in the polymer block (A). COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:提供一种经济,环保的固体高分子型燃料电池用高分子电解质膜等,其离子传导性高,甲醇阻隔性优异。 解决方案:这是用于固体聚合物燃料电池的聚合物电解质膜,以及膜 - 电极组件和固体聚合物燃料电池,其中聚合物嵌段(A)具有芳族乙烯基系列化合物,其制成为 重复单元,其中与α-碳原子键合的氢原子未被取代或被碳数为1〜4的烷基取代,并且其中至少一个与芳环直接键合的氢原子被烷基取代 碳原子数1〜8的基团和柔性聚合物嵌段(B)作为成分,而在聚合物嵌段(A)中含有具有离子导电性基团的嵌段共聚物。 版权所有(C)2007,JPO&INPIT