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    • 2. 发明专利
    • Method for producing precursor for rare earth-activated alkaline earth metal fluoride halide-based photostimulable phosphor, and rare earth-activated alkaline earth metal fluoride halide-based photostimulable phosphor, and radiation image conversion panel
    • 用于生产稀土激活的碱性碱金属氟化物基卤化物的可光化磷酸盐和稀土激活的碱性碱金属氟化物基卤化物的可光化磷光体和辐射图像转换面板的方法
    • JP2006232969A
    • 2006-09-07
    • JP2005048719
    • 2005-02-24
    • Konica Minolta Medical & Graphic Incコニカミノルタエムジー株式会社
    • WAKAMATSU HIDEAKINABETA HIROYUKI
    • C09K11/61C01F11/20C09K11/00C09K11/08G03B42/02G21K4/00
    • PROBLEM TO BE SOLVED: To provide a method for producing photostimulable phosphor imparting an image free from unevenness of luminescence, high in sensitivity and image quality, and to provide a photostimulable phosphor, and a radiation image conversion panel.
      SOLUTION: The invention relates to the method for producing a precursor for photostimulable phosphor, based on alkaline earth metal fluoride halide activated with rare earth metal, expressed by general formula (1) comprising a process obtaining a crystal of the precursor for the photostimulable phosphor by carrying out a process forming a precipitate of the precursor for photostimulable phosphor based on alkaline earth metal fluoride halide by adding an aqueous solution of an inorganic fluoride into a reaction mother liquid dissolving barium halide and a process concentrating and removing solvent from the reaction mother liquid at the same time, and a process forming a rare earth metal halide layer on the surface of the crystal of the precursor for photostimulable phosphor. The general formula (1); Ba
      1-x M2
      x FBr
      y I
      1-y : aM1, bLn, cO (in the formula, M1 is an alkali metal, M2 is an alkaline earth metal, Ln is a rare earth element, 0≤x≤0.3, 0≤y≤0.3, 0≤a≤0.05. 0
    • 解决问题的方法:提供一种赋予不发光不均匀,高灵敏度和图像质量的图像的可光激发荧光体的制造方法,提供可光激发的荧光体和放射线图像转换面板。 解决方案:本发明涉及一种基于由稀土金属活化的碱土金属氟化物卤化物,由通式(1)表示的用于制备可光激发荧光体的前体的方法,该方法包括获得前体的晶体的方法, 通过向溶解卤化钡的反应母液中加入无机氟化物的水溶液和从反应中浓缩除去溶剂的方法,通过进行基于碱土金属氟化物卤化物的可光激发的荧光体的前体的沉淀物的处理而形成光刺激性荧光体 母液,以及在可光激发荧光体的前体的结晶表面形成稀土金属卤化物层的工序。 通式(1); aM1,bLn,cO(式中,R 1,R 2,R 3,X 1,X 3, M1是碱金属,M2是碱土金属,Ln是稀土元素,0≤x≤0.3,0≤y≤0.3,0≤a≤0.05,0