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    • 2. 发明专利
    • Gas separation method and gas separation apparatus
    • 气体分离方法和气体分离装置
    • JP2009023907A
    • 2009-02-05
    • JP2008230055
    • 2008-09-08
    • Kobe Steel Ltd株式会社神戸製鋼所
    • YAMAMOTO SEIICHIYURA KEITA
    • C01B32/40B01D53/04
    • PROBLEM TO BE SOLVED: To obtain a product gas having higher purity in the case when the product gas is separated and recovered through adsorption onto an adsorbent. SOLUTION: A raw material gas containing carbon monoxide is supplied into adsorption columns 16A, 16B and thereafter, carbon monoxide is separated and recovered by desorbing carbon monoxide from an adsorbent. At this time, the pressure of the adsorption columns 16A, 16B is reduced by an ejector 18 operated with steam as a primary fluid (driving fluid) and carbon monoxide (secondary fluid) desorbed from the adsorbent is discharged together with steam (primary fluid) while being sucked into the ejector 18. Then, the discharged fluids are cooled to an ordinary temperature or near to the ordinary temperature to condense steam. The discharged fluids are thereby vapor-liquid separated and carbon monoxide being a gas component is recovered as the product gas. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:在通过吸附分离和回收产物气体的情况下获得具有较高纯度的产物气体。 解决方案:将含有一氧化碳的原料气体供应到吸附塔16A,16B中,此后通过从吸附剂中解吸一氧化碳来分离和回收一氧化碳。 此时,吸附塔16A,16B的压力由作为主要流体(驱动流体)的蒸汽操作的喷射器18减少,并且从吸附剂解吸的一氧化碳(二次流体)与蒸汽(主要流体)一起排出, 同时被吸入喷射器18.然后,排出的流体被冷却到常温或接近常温以冷凝蒸汽。 排出的流体由此气液分离,作为气体成分的一氧化碳作为产物气体被回收。 版权所有(C)2009,JPO&INPIT
    • 4. 发明专利
    • Method for separating gas and its device
    • 分离气体及其装置的方法
    • JP2006181479A
    • 2006-07-13
    • JP2004377908
    • 2004-12-27
    • Kobe Steel Ltd株式会社神戸製鋼所
    • YAMAMOTO SEIICHIYURA KEITA
    • B01D53/04C01B32/40
    • PROBLEM TO BE SOLVED: To obtain a higher purity product gas in the case of separation and recovery by adsorbing the product gas by an adsorbent. SOLUTION: A raw gas containing carbon monoxide is supplied to adsorption towers 16A, 16B and then carbon monoxide is separated and recovered by desorbing carbon monoxide from the adsorbent. At this time, the pressure of the adsorption towers 16A, 16B is reduced by an ejector 18 operated with steam as a primary fluid (driving fluid) and carbon monoxide (secondary fluid) desorbed from the adsorbent together with steam (primary fluid) is discharged while carbon monoxide is sucked into the ejector 18. Then, the discharged fluids are cooled to an ordinary temperature or near and steam is condensed. The discharged fluids are thereby vapor-liquid separated and carbon monoxide, a gas component, is recovered as the product gas. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:在通过吸附剂吸附产物气体进行分离和回收的情况下获得更高纯度的产物气体。 解决方案:将含有一氧化碳的原料气体供应到吸附塔16A,16B,然后通过从吸附剂中解吸一氧化碳来分离和回收一氧化碳。 此时,吸附塔16A,16B的压力由作为主要流体(驱动流体)的蒸汽操作的喷射器18减少,并且与蒸汽(主流体)一起从吸附剂解吸的一氧化碳(二次流体)被排出 而一氧化碳被吸入喷射器18.然后,排出的流体被冷却到常温或接近并且蒸汽冷凝。 排出的流体由此气液分离,一氧化碳(气体组分)作为产物气体被回收。 版权所有(C)2006,JPO&NCIPI
    • 5. 发明专利
    • Zeolite-membrane supporting base material and zeolite-membrane composite body
    • 支撑基底材料和沸石 - 薄膜复合材料的ZEOLITE-MEMBRANE
    • JP2005125313A
    • 2005-05-19
    • JP2004252799
    • 2004-08-31
    • Kobe Steel Ltd株式会社神戸製鋼所
    • TANAKA TAKEHARUMITANI HIROYUKIYAMAMOTO KOJIYURA KEITASATO TOSHIKI
    • B01D69/10B01D71/02C01B39/14C01B39/22C01B39/24
    • PROBLEM TO BE SOLVED: To provide a zeolite-membrane supporting base material capable of preferably forming a film from a zeolite excepting a high-silica zeolite, and to provide a zeolite-membrane composite body.
      SOLUTION: (1) The zeolite-membrane supporting base material is a base material for supporting a zeolite membrane, wherein a metal oxide layer is formed on the surface of a metallic base material. (2) In the zeolite-membrane supporting base material, a thickness of the metal oxide layer is 1 nm-10 μm, the metallic base material is porous, an average pore diameter is ≥10 nm and ≤50 μm, the metallic base material is an iron-based metal, and the metal oxide layer is composed of chromia, silica or alumina. (3) The zeolite membrane composite body has the zeolite membrane which is formed on the surface of a metal-oxide layer forming side and/or in a pore inner part, of the zeolite-membrane supporting base material. (4) In the zeolite-membrane supporting base material, the zeolite membrane is a zeolite of SiO
      2 /Al
      2 O
      3 ≤10.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种能够优选由除了高硅石沸石之外的沸石形成膜的沸石膜支撑基材,并提供沸石 - 膜复合体。 解决方案:(1)沸石膜支撑基材是用于支撑沸石膜的基材,其中金属氧化物层形成在金属基材的表面上。 (2)在沸石膜支撑基材中,金属氧化物层的厚度为1nm〜10μm,金属基材多孔,平均孔径为≥10nm,≤50μm,金属基材 是铁基金属,金属氧化物层由氧化铬,二氧化硅或氧化铝构成。 (3)沸石膜复合体在沸石膜支撑基材的形成有金属氧化物层的表面和/或孔内部的表面上形成沸石膜。 (4)在沸石膜支撑基材中,沸石膜是SiO 2 / SB 3 / SB 3 / SB 3的沸石。 版权所有(C)2005,JPO&NCIPI
    • 6. 发明专利
    • Psa apparatus for producing high purity hydrogen gas
    • 用于生产高纯度氢气的PSA装置
    • JP2008063152A
    • 2008-03-21
    • JP2006239208
    • 2006-09-04
    • Kobe Steel Ltd株式会社神戸製鋼所
    • NAKAO NOBORUYAMASHITA TAKESHIFUJISAWA AKITOSHIYURA KEITA
    • C01B3/56B01D53/02B01D53/04B01J20/02
    • Y02C10/08
    • PROBLEM TO BE SOLVED: To provide a PSA apparatus for producing high purity hydrogen gas which recovers high purity hydrogen gas with high recovery rate from a hydrogen-containing gas and can contribute to miniaturization of equipment, that is, reduction of equipment cost. SOLUTION: In a PSA apparatus for producing high purity hydrogen gas B from a hydrogen-containing gas A by adsorbing and removing an unnecessary gas which includes CO gas, there is provided an adsorbent bed 2 in which a CO adsorbent layer 5 which does not substantially adsorb CO 2 and a carbon-based adsorbent layer 4 for adsorbing CO 2 are laminated in this order from the upstream of the flowing direction of the hydrogen-containing gas A toward the downstream without providing a zeolite layer in an adsorption tower 1 of the PSA apparatus. At the time of regenerating the adsorbent bed 2, a cleaning gas C is flowed through the carbon-based adsorbent layer 4 and the CO adsorbent layer 5 in this order. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种用于生产高纯度氢气的PSA装置,其从含氢气体回收高回收率的高纯度氢气,并且可以有助于设备的小型化,即减少设备成本 。 解决方案:在通过吸附除去包括CO气体的不必要气体的含氢气体A生产高纯度氢气B的PSA装置中,提供吸附剂床2,其中CO吸附剂层5 基本不吸附CO 2 ,并且从含氢气体的流动方向的上游依次层叠用于吸附CO 2 SBB的碳系吸附剂层4 A在PSA装置的吸附塔1中不向沸水层提供沸石层。 在再生吸附剂床2时,清洁气体C依次流过碳系吸附剂层4和CO吸附剂层5。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Method of removing heavy metal in hydrochloric acid containing heavy metal, and unit for use therein
    • 在含有重金属的氢氯酸盐中除去重金属的方法及其使用单元
    • JP2007015900A
    • 2007-01-25
    • JP2005200797
    • 2005-07-08
    • Kobe Steel Ltd株式会社神戸製鋼所
    • YAKOU YASUKOMURAKAMI YUTAKAYURA KEITAKITAGAWA NOBUHISA
    • C01B7/01B01J41/04B01J41/12B01J47/02B01J49/00C02F1/42
    • PROBLEM TO BE SOLVED: To provide a method of removing heavy metals in a hydrochloric acid containing a heavy metal by the use of a strongly-basic anion exchange resin, which is capable of increasing the adsorption quantity of an anionic metal chlorine complex formed by a heavy metal than a conventional method and capable of decreasing the quantity of the regenerated liquid of the strongly-basic anion exchange resin than the conventional method. SOLUTION: In this method of removing heavy metals in a hydrochloric acid containing a heavy metal, the hydrochloric acid containing a heavy metal is heated to a prescribed temperature higher than an ordinary temperature and brought into contact with the strongly-basic anion exchange resin, to allow the strongly-basic anion exchange resin to adsorb an anionic metal chlorine complex formed by the heavy metal. COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供一种通过使用强碱性阴离子交换树脂除去含有重金属的盐酸中的重金属的方法,其能够增加阴离子金属氯络合物的吸附量 由常规方法的重金属形成,并且能够减少强碱性阴离子交换树脂的再生液体的量比常规方法。 解决方案:在这种除去含有重金属的盐酸中的重金属的方法中,将含有重金属的盐酸加热至比常温高的规定温度并与强碱性阴离子交换 树脂,以使强碱性阴离子交换树脂吸附由重金属形成的阴离子金属氯络合物。 版权所有(C)2007,JPO&INPIT
    • 8. 发明专利
    • Method for producing high purity treatment gas
    • 生产高纯度处理气体的方法
    • JP2006021935A
    • 2006-01-26
    • JP2004199315
    • 2004-07-06
    • Kobe Steel Ltd株式会社神戸製鋼所
    • MIURA SHINICHISHIMIZU TAKAHIROYAMASHITA TAKESHIYURA KEITA
    • C01B3/56B01D53/02B01J20/02B01J23/889C01B21/04H01M8/06H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a method for producing a treatment gas, by which CO contained as a harmful impurity in various gases to be industrially used can be surely removed over a long period of time from an initial stage even in the presence of moisture by a relatively simple, practically applicable process. SOLUTION: In the method for producing the treatment gas, carbon monoxide contained in a gas is removed by passing the CO-containing gas through a packed layer including a CO adsorbing material with a copper salt carried on one or more kinds of substrate selected from the group consisting of alumina, silica, zeolite and activated carbon, and a CO oxidation catalyst with a manganese-based catalyst carried on one or more kinds of substrate selected from the group consisting of alumina, silica, zeolite and activated carbon. (However, this method cannot be used in a fire site). COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:为了提供一种处理气体的制造方法,即使在工业上使用的各种气体中作为有害杂质而含有的CO也可以从初始阶段在长时间内可靠地除去,即使在 通过相对简单,实际应用的过程存在水分。 解决方案:在处理气体的制造方法中,通过使含CO气体通过包含CO吸附材料的填充层与携带在一种或多种基材上的铜盐通过而除去气体中所含的一氧化碳 选自由氧化铝,二氧化硅,沸石和活性炭组成的组的氧化催化剂,以及负载在选自氧化铝,二氧化硅,沸石和活性炭的一种或多种基材上的锰系催化剂的CO氧化催化剂。 (但是,这种方法不能在火灾现场使用)。 版权所有(C)2006,JPO&NCIPI
    • 10. 发明专利
    • Method of manufacturing hydrogen
    • 制氢方法
    • JP2009184901A
    • 2009-08-20
    • JP2008125098
    • 2008-05-12
    • Kobe Steel Ltd株式会社神戸製鋼所
    • FUJISAWA AKITOSHIYAMASHITA TAKESHINAKAO NOBORUMIURA SHINICHIYURA KEITA
    • C01B3/38C01B3/48C01B3/56H01M8/06H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing hydrogen which can realize size reduction and low cost of a manufacturing apparatus of gaseous hydrogen in a method in which from a modified gas prepared by reforming and modifying a fossil fuel, CO is removed and refined, thereby to manufacture gaseous hydrogen for a fuel cell. SOLUTION: A fossil fuel such as a natural gas or kerosene is used as a raw material A, a reformed gas B prepared by adding steam and carrying out the reforming by a reforming reactor 1 is modified using for example only an elevated temperature modification reactor 2 in one step. After adjusting so that CO concentration in a modified gas C may become 1% to 8% by volume, a CO adsorbent CO in the modified gas C is removed to 10 ppm or less by a CO removing apparatus 3, to produce gaseous hydrogen D for a fuel cell 4. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种制造氢气的方法,其可以实现气态氢制造装置的尺寸减小和低成本的方法,其中从通过重整和改性化石燃料制备的改性气体,CO为 去除和精制,从而制造用于燃料电池的气态氢。 解决方案:使用诸如天然气或煤油的化石燃料作为原料A,通过加入蒸汽并通过重整反应器1进行重整制备的重整气体B使用例如仅仅升高的温度 改性反应器2。 调整后,改性气体C中的CO浓度可以为1〜8体积%,CO除去装置3将改性气体C中的CO吸附剂CO除去至10ppm以下,生成气态氢D, 燃料电池4.版权所有(C)2009,JPO&INPIT