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    • 1. 发明专利
    • Welded joint and welded structure excellent in corrosion resistance
    • 焊接接头和焊接结构优良的耐腐蚀性
    • JP2012135817A
    • 2012-07-19
    • JP2012035620
    • 2012-02-21
    • Kobe Steel Ltd株式会社神戸製鋼所
    • SAKASHITA SHINJIHISAMOTO ATSUSHIYAMASHITA TORU
    • B23K35/30C22C38/00C22C38/38C22C38/60
    • PROBLEM TO BE SOLVED: To provide a welded joint and a welded structure which are excellent in corrosion resistance under environment where they are exposed to salt caused by seawater and high temperature and high humidity and environment which contains sulfur which comes from oil or the like without applying painting and electric corrosion protection especially the welded joint and the welded structure which are raised in the corrosion resistance to local corrosion and crevice corrosion.SOLUTION: In this welded joint, mutual base metal is welded and the welded joint satisfies under formula (5), (6) and (7): 0.30≤[A]/[B]≤3.0...(5), 0.30≤[A]/[B]≤3.0...(6) and 0.30≤[A]/[B]≤3.0...(7). In the formula, [A] means the content (mass%) of Al which is contained in the weld metal in the welded part, [B] means the content (mass%) of Al which is contained in the base metal, [A] means the content (mass%) of Cu which is contained in the weld metal in the welded part, [B] means the content (mass%) of Cu which is contained in the base metal, [A] means the content (mass%) of Cr which is contained in the weld metal in the welded part, and [BCr] means the content (mass%) of Cr which is contained in the base metal.
    • 要解决的问题:提供一种焊接接头和焊接结构,其在由海水暴露于盐的环境中具有优异的耐腐蚀性,并且由于含有来自油的硫的高温高湿环境 不需要涂漆和电腐蚀保护,特别是焊接接头和焊接结构,其耐腐蚀性高于局部腐蚀和缝隙腐蚀。 解决方案:在该焊接接头中,焊接相互贱金属,焊接接头满足公式(5),(6)和(7):0.30≤[A A1 ] / [B A1 ]≤3.0...(5),0.30≤[A Cu SB POS =“POST”> Cu ]≤3.0...(6)和0.30≤[A Cr ] / [B 的Cr ]≤3.0...(7)。 在该公式中,[A Al ]是指包含在焊接部的焊接金属中的Al的含量(质量%),[B Al表示含有在母材中的Al的含量(质量%),[A Cu ]是指Cu的含量(质量%) 包含在焊接部的焊接金属中,[B Cu ]是指包含在母材中的Cu的含量(质量%),[A Cr 是指焊接部中焊接金属中含有的Cr的含量(质量%),[BCr]表示包含在基材中的Cr的含量(质量%) 金属。 版权所有(C)2012,JPO&INPIT
    • 2. 发明专利
    • Titanium electrode material and surface treatment method of titanium electrode material
    • 钛电极材料的钛电极材料与表面处理方法
    • JP2010236083A
    • 2010-10-21
    • JP2009194963
    • 2009-08-26
    • Kobe Steel Ltd株式会社神戸製鋼所
    • SATO TOSHIKISUZUKI JUNITO YOSHINORIHISAMOTO ATSUSHI
    • C23C28/00B32B9/00H01M8/02H01M8/10
    • H01M4/8657H01M4/8803H01M4/8817H01M4/8867H01M4/92H01M4/921H01M8/0206H01M2008/1095
    • PROBLEM TO BE SOLVED: To provide a titanium electrode material which is low in cost and is excellent in electric conductivity, corrosion resistance and hydrogen absorption resistance, and to provide a surface treatment method of a titanium electrode material. SOLUTION: The titanium electrode material includes: a titanium oxide layer having a thickness of 3 nm or more and 75 nm or less, and having an atomic concentration ratio of oxygen and titanium (O/Ti) at a site having the maximum oxygen concentration in the layer of 0.3 or more and 1.7 or less, on the surface of a titanium material including pure titanium or a titanium alloy; and an alloy layer including at least one noble metal selected from Au, Pt, and Pd, and at least one non-noble metal selected from Zr, Nb, Ta, and Hf, having a content ratio of the noble metal and the non-noble metal of 35:65 to 95:5 by atomic ratio, and having a thickness of 2 nm or more, on the titanium oxide layer. Also, the surface treatment method of a titanium electrode material includes a titanium oxide layer formation step, an alloy layer formation step, and a heat treatment step. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种成本低且导电性,耐腐蚀性和耐氢吸收性优异的钛电极材料,并提供钛电极材料的表面处理方法。 解决方案:钛电极材料包括:具有3nm以上且75nm以下的厚度的氧化钛层,并且在具有最大值的部位具有氧和钛的原子浓度比(O / Ti) 在包括纯钛或钛合金的钛材料的表面上,该层中的氧浓度为0.3以上且1.7以下; 以及包含选自Au,Pt和Pd中的至少一种贵金属和选自Zr,Nb,Ta和Hf中的至少一种非贵金属的合金层,其具有贵金属和非金属的含量比, 在氧化钛层上的原子比为35:65〜95:5的贵金属,厚度为2nm以上。 此外,钛电极材料的表面处理方法包括氧化钛层形成步骤,合金层形成步骤和热处理步骤。 版权所有(C)2011,JPO&INPIT
    • 3. 发明专利
    • Corrosion resistant film for fuel cell separator, and fuel cell separator
    • 燃料电池分离器和燃料电池分离器的耐腐蚀膜
    • JP2010182593A
    • 2010-08-19
    • JP2009026749
    • 2009-02-06
    • Kobe Steel Ltd株式会社神戸製鋼所
    • ITO YOSHINORISATO TOSHIKISUZUKI JUNHISAMOTO ATSUSHI
    • H01M8/02C22C5/02C22C5/04C22C21/00C22C27/02C23C28/02H01M8/10
    • H01M8/0206H01M8/021H01M8/0228H01M2008/1095
    • PROBLEM TO BE SOLVED: To provide a corrosion resistant film producible inexpensively with good productivity, for coating the surface of a separator in a fuel cell to give an effect to maintain a low contact resistance over a long term, and to provide a separator using the corrosion resistant film. SOLUTION: The separator 10 includes the corrosion resistant film 2 formed by layering a corrosion resistant layer 21 and a conductive layer 22 composed of one or more noble metal elements selected from Au and Pt, on the surface of a base material 1 composed of metallic materials such as Ti, Al and stainless steel. In the corrosion resistant layer 21 formed of an alloy of one or more noble metal elements selected from Au and Pt and one or more non-noble metal elements selected from Nb, Ta, Zr and Hf, when the content of the non-noble metal elements is set to 50-90 atom%, the alloy becomes an amorphous alloy, and pin holes are hardly formed and exposure of the base material 1 is prevented even if film forming into a thin film is carried out by an ordinary sputtering method and the like. When this corrosion resistant layer 21 is equipped in a substrate, the conductive layer 22 on the surface can be formed into a thin film and cost can be lowered in the separator 10. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供廉价生产的耐腐蚀膜,具有良好的生产率,用于在燃料电池中涂覆隔板的表面以产生长期保持低接触电阻的效果,并提供一种 分离器使用耐腐蚀膜。 解决方案:隔板10包括通过在基材1的表面上分层形成耐腐蚀层21和由一种或多种选自Au和Pt的贵金属元素构成的导电层22形成的耐腐蚀膜2, 的金属材料,如Ti,Al和不锈钢。 在由选自Au和Pt的一种或多种贵金属元素和选自Nb,Ta,Zr和Hf的一种或多种非贵金属元素的合金形成的耐腐蚀层21中,当非贵金属 元素设定为50-90原子%,合金变为非晶合金,并且即使通过普通溅射法进行薄膜成膜,也难以形成针孔,并且防止基材1的曝光,并且 喜欢。 当该耐腐蚀层21装配在基板中时,表面上的导电层22可以形成为薄膜,并且可以在隔板10中降低成本。版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Anode oxidation-treated aluminum alloy combining durability and low stain
    • 阳极氧化处理的铝合金组合耐久性和低水平
    • JP2009046747A
    • 2009-03-05
    • JP2007216239
    • 2007-08-22
    • Kobe Steel Ltd株式会社神戸製鋼所
    • WADA KOJIHISAMOTO ATSUSHI
    • C25D11/04
    • C22C21/00C22C21/02C22C21/08C22F1/04C22F1/043C22F1/047C22F1/05C25D11/04
    • PROBLEM TO BE SOLVED: To provide an anode oxidation-treated aluminum alloy combining durability and low stain in spite of its high hardness.
      SOLUTION: The anode oxidation-treated aluminum alloy is provided with: an aluminum alloy having a composition composed of, by mass, 0.1 to 2.0% Mg, 0.1 to 2.0% Si and 0.1 to 2.0% Mn, and in which each content of Fe, Cr and Cu is regulated to ≤0.03%, respectively, and the balance Al with inevitable impurities; and an anodic oxide film formed on the surface of the aluminum alloy. The aluminum alloy has parts with different hardness in the thickness direction of the anodic oxide film, and the difference in the hardness between the maximum part and the minimum part is ≥5 by Vickers hardness.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:尽管硬度高,但是提供结合耐久性和低污渍的阳极氧化处理的铝合金。 阳极氧化处理的铝合金具有:以质量计为0.1〜2.0%的Mg,0.1〜2.0%的Si和0.1〜2.0%的Mn的组成的铝合金,其中, Fe,Cr和Cu的含量分别调节至≤0.03%,余量为不可避免的杂质; 以及形成在铝合金表面上的阳极氧化膜。 铝合金在阳极氧化膜的厚度方向上具有不同硬度的部件,维氏硬度的最大部分和最小部分之间的硬度差为≥5。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Al OR Al-ALLOY
    • 铝或铝合金
    • JP2008285742A
    • 2008-11-27
    • JP2007134503
    • 2007-05-21
    • Kobe Steel Ltd株式会社神戸製鋼所
    • HISAMOTO ATSUSHIWADA KOJI
    • C25D11/04
    • C25D11/04
    • PROBLEM TO BE SOLVED: To provide Al or an Al-alloy having an anodically oxidized film which is excellent in crack-resistance although it has high hardness.
      SOLUTION: (1) The Al or the Al-alloy has an anodized film having parts different in hardness in the thickness direction and is characterized in that the difference between Vickers hardnesses of a part having a maximum hardness and a part having a minimum hardness is ≥5. (2) In the Al or the Al-alloy, the Vickers hardness of the part having a minimum hardness is ≥300. (3) In the Al or the Al-alloy, the Fe content in the anodized film is ≤500 ppm.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供具有优异的耐龟裂性的,具有高硬度的阳极氧化膜的Al或Al合金。 (1)Al或Al合金具有在厚度方向上硬度不同的阳极氧化膜,其特征在于,具有最大硬度的部件的维氏硬度与具有最大硬度的部分的维氏硬度之差 最低硬度≥5。 (2)在Al或Al合金中,具有最小硬度的部件的维氏硬度≥300。 (3)在Al或Al合金中,阳极氧化膜中的Fe含量≤500ppm。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Steel material having excellent corrosion resistance
    • 具有优异耐腐蚀性的钢材
    • JP2008208452A
    • 2008-09-11
    • JP2007303333
    • 2007-11-22
    • Kobe Steel Ltd株式会社神戸製鋼所
    • YUSE FUMIOHISAMOTO ATSUSHI
    • C22C38/00C22C38/60
    • PROBLEM TO BE SOLVED: To provide a steel material excellent in corrosion resistance which can be suitably used as a material for a steel structure requiring excellent corrosion resistance in air-polluted environment containing large amounts of sulfur oxides.
      SOLUTION: This steel material is characterized in that: it has a composition which contains, by mass, at least one element selected from among C, Si, Mn, S, Ti, Ca, Cu and Ni and Al in respectively specified percentages and has the balance Fe with inevitable impurities, wherein a relationship represented by [(Ni+4.5×Cu)×S×2500×Ti>5] is present among the respective contents of Ni, Cu, S and Ti; its surface is covered with rust containing respectively specified percentages of S and at least one element selected from among Ti, Cu, Ni, Nb, Zr and V; a rust layer in which a crystallite size of β-FeOOH component is 2 /g.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供耐腐蚀性优异的钢材,其可以适合用作在含有大量硫氧化物的空气污染环境中需要优异耐腐蚀性的钢结构材料。 解决方案:该钢材的特征在于:其具有以质量计含有选自C,Si,Mn,S,Ti,Ca,Cu和Ni和Al中的至少一种元素的组分,分别指定 在Ni,Cu,S和Ti的各自含量中存在由[(Ni + 4.5×Cu)×S×2500×Ti> 5]表示的不可避免的杂质的平衡Fe, 其表面被含有分别指定百分比的S和选自Ti,Cu,Ni,Nb,Zr和V中的至少一种元素的锈覆盖; 表面形成有β-FeOOH成分的微晶尺寸<50nm的锈层; 锈层的比表面积≥10m 2 / g。 版权所有(C)2008,JPO&INPIT
    • 8. 发明专利
    • Highly corrosion resistant steel
    • 高耐腐蚀钢
    • JP2006169626A
    • 2006-06-29
    • JP2005331956
    • 2005-11-16
    • Kobe Steel Ltd株式会社神戸製鋼所
    • YUSE FUMIOSAKASHITA SHINJIYASUNAGA TATSUYAKOBAYASHI YOICHIROOKANO SHIGEOHISAMOTO ATSUSHI
    • C22C38/00C22C38/58
    • PROBLEM TO BE SOLVED: To provide a highly corrosion resistant steel having excellent corrosion resistance without reducing its mechanical properties and weldability caused by the surplus addition of corrosion resistance improving elements.
      SOLUTION: (1) The highly corrosion resistant steel has a composition comprising, by mass, 0.01 to 3.0% Zn, 0.05 to 3.0% Cu and 0.05 to 6.0% Ni, and further comprising one or more kinds selected from 0.0005 to 0.0050% Ca, 0.0005 to 0.010% Mg and 0.0005 to 0.010% rare earth metals. (2) Regarding the highly corrosion resistant steel, the region to a depth of 500 μm from the outermost surface of the steel is provided with a Cu+Ni concentrated layer in which the content of Cu+the content of Ni are ≥1.2 times the content of Cu+the content of Ni in the steel and are also ≥1.0 mass%, and the thickness of the concentrated layer is ≥1 μm. (3) In the highly corrosion resistant steel, the average ferrite crystal grain size in the specified region of the surface layer part in the steel sheet is ≤5 μm.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供具有优异耐腐蚀性的高耐腐蚀性钢,而不会降低由耐腐蚀性改进元素的多余添加性引起的机械性能和焊接性。 解决方案:(1)高耐腐蚀性钢的组成为:含有0.01〜3.0%的Zn,0.05〜3.0%的Cu和0.05〜6.0%的Ni,并且还含有选自以下的一种或多种:0.0005〜 0.0050%Ca,0.0005〜0.010%Mg和0.0005〜0.010%稀土金属。 (2)关于耐腐蚀性高的钢,从钢的最外表面到深度为500μm的区域设置Cu + Ni浓缩层,其中Cu +含量为Ni的含量≥1.2倍 钢中的含量为Cu +,Ni的含量也为≥1.0质量%,浓缩层的厚度为1μm以上。 (3)在高耐蚀性钢中,钢板表面层部分的特定区域的平均铁素体晶粒尺寸≤5μm。 版权所有(C)2006,JPO&NCIPI
    • 9. 发明专利
    • Surface treatment method for aluminum
    • 铝表面处理方法
    • JP2005113182A
    • 2005-04-28
    • JP2003346773
    • 2003-10-06
    • Iwatani Internatl CorpKobe Steel Ltd岩谷産業株式会社株式会社神戸製鋼所
    • KOIKE KUNIHIKOINOUE GOICHIHISAMOTO ATSUSHIWADA KOJITANAKA TOSHIYUKI
    • C23C8/12
    • PROBLEM TO BE SOLVED: To provide a method of efficiently forming an oxide film on the surface of aluminum or an aluminum alloy.
      SOLUTION: The method of forming an oxide film on the surface of aluminum or an aluminum alloy with gaseous ozone is characterized in that the surface of aluminum or an aluminum alloy held from ordinary temperature to 450°C is brought into contact with an ozone-containing gas having an ozone concentration of 5 to 100 vol% to form an oxide film. In the case of a CVD (Chemical Vapor Deposition) system, the ozone-containing gas is fed in a state where the inside of the system is decompressed and heated, by which the oxide film is formed on the surface of the aluminum or aluminum alloy in the system. The concentration of the gaseous ozone is preferably controlled to ≥20%.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种在铝或铝合金的表面上有效地形成氧化膜的方法。 解决方案:在具有气态臭氧的铝或铝合金表面上形成氧化膜的方法的特征在于,将常温保持在450℃的铝或铝合金的表面与 臭氧浓度为5〜100体积%的含臭氧气体,形成氧化膜。 在CVD(化学气相沉积)系统的情况下,在系统内部减压加热的状态下进料含臭氧气体,通过该气体在铝或铝合金的表面上形成氧化膜 在系统中。 气态臭氧的浓度优选控制在≥20%。 版权所有(C)2005,JPO&NCIPI
    • 10. 发明专利
    • Aluminum alloy member having excellent low staining property
    • 具有优异的低污染性能的铝合金构件
    • JP2010209367A
    • 2010-09-24
    • JP2009053390
    • 2009-03-06
    • Kobe Steel Ltd株式会社神戸製鋼所
    • HOSOKAWA MAMORUTSUBOTA TAKAYUKIWADA KOJIHISAMOTO ATSUSHI
    • C25D11/04C23C16/44
    • PROBLEM TO BE SOLVED: To provide an aluminum alloy member having low staining property and coping with low staining need recently growing regardless of a component composition of the aluminum alloy used for a base material even when an aluminum alloy having special component composition requiring time and labor in the manufacture is not adopted.
      SOLUTION: The aluminum alloy member has an anodized film formed on the surface of a base material comprising the aluminum alloy. The anodized film has a porous layer in which barrier thickness between pores is ≤30 nm, in the depth of ≥1 μm from the surface side of the film. The barrier thickness between the pores is >30 nm and the barrier layer thickness is ≥5 μm in the region of the base material side except for the porous layer of the surface side.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:即使当具有特殊组分组成要求的铝合金,即使是具有特殊组成成分的铝合金,即使是用于基材的铝合金的组分组成,也可以提供一种低染色性的铝合金构件, 制造时间和劳动力不被采用。 解决方案:铝合金构件具有在包含铝合金的基材的表面上形成的阳极氧化膜。 阳极氧化膜具有多孔层,其中孔之间的阻挡层厚度≤30nm,距膜的表面侧的深度≥1μm。 除了表面侧的多孔层之外,在基材侧的区域中,孔之间的阻挡层厚度> 30nm,阻挡层厚度≥5μm。 版权所有(C)2010,JPO&INPIT