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1. 发明专利

JPS59211617A Flame-retardant acrylic synthetic fiber 失效
标题翻译：阻燃丙烯酸合成纤维
公开(公告)号：JPS59211617A
公开(公告)日：1984-11-30
申请号：JP8229883
申请日：1983-05-10
申请人： Kanegafuchi Chem Ind Co Ltd
发明人： KONISHI AKIO , FUJIWARA KAZUAKI , ICHIBORI TAKAHARU , HATANO TAKASHI
IPC分类号： C08L27/00 , C08K5/57 , C08K5/58 , C08L1/00 , C08L27/04 , C08L33/00 , C08L33/02 , C08L33/20 , D01F1/07 , D01F1/10 , D01F6/40 , D01F6/48 , D01F6/54
摘要： PURPOSE: The titled fiber that is obtained by combining a tin compound containing a phenyl group with a polymer composed of acrylonitrile, a halogen-containing monomer and an olefin and subjecting the mixture to spinning thus being suitable for use as curtains, because it retains gloss even after dyeing.
CONSTITUTION: A polymer which is composed of 30W70wt% of acrylonitrile, 70W30wt% of a halogen-containing monomer such as vinyl chloride and 0W 10wt% of an olefin copolymerizable with them such as acrylamide is combined with a tin compound bearing a phenyl group represented by the formula (X is Cl, Br; R is 1W8C alkyl, cyclohexyl; a is integer of 0W4; b is integer of 0W4; c is integer of 0W3; d is 0W3 integer; m is 0W3 integer, where a+b+c+d=4, a+b≥1) such as monobutyltin triphenyl by 0.2W3.0wt%, then they are subjected to spinning to obtain the objective synthetic fiber.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过将含有苯基的锡化合物与由丙烯腈，含卤素的单体和烯烃组成的聚合物组合而得到的标题纤维，并使混合物纺丝适于用作窗帘，因为它保持光泽即使染色后。构成：由30-70重量％的丙烯腈，70-30重量％的含卤素单体如氯乙烯和0-10重量％的与它们共聚的烯烃如丙烯酰胺组成的聚合物与锡化合物轴承由式（X为Cl，Br; R为1-8C烷基，环己基; a为0-4的整数; b为0-4的整数; c为0-3的整数; d为0 -3整数; m为0-3整数，其中a + b + c + d = 4，a + b> = 1），例如0.2-3.0重量％的单丁基锡三苯基，然后进行纺丝以获得目标合成纤维。

2. 发明专利

JPS6112911A Manufacture of acrylonitrile synthetic fiber having high shrinkage 失效
标题翻译：具有高收缩率的丙烯腈合成纤维的制备
公开(公告)号：JPS6112911A
公开(公告)日：1986-01-21
申请号：JP13145784
申请日：1984-06-26
申请人： Kanegafuchi Chem Ind Co Ltd
发明人： KONISHI AKIO , KUBO YUUJI , INOUE MASAHARU
IPC分类号： D01F6/38 , D01D1/02 , D01D5/06 , D02J1/22
摘要： PURPOSE: To obtain a high-shrinkage acrylonitrile fiber free from the loss of clarity, by adding water to a solution of a copolymer having a specific composition, and carrying out the wet spinning of the dope.
CONSTITUTION: A copolymer having an acrylonitrile content of 80W92wt% is dissolved in dimethylformamide, dimethylacetamide or dimethyl sulfoxide, and 1.0W 6.0wt% water is added to the dope. The fiber obtained by the wet spinning of the above dope is subjected to the primary drawing at a draw ratio of ≤3.0, dried, and finally subjected to the secondary drawing in hot air of 100W140°C at a draw ratio of 1.5W3.0. A fiber free from the loss of clarity can be produced even by a wet spinning process, and the low-temperature drying process after the secondary drawing can be eliminated. The titled fiber produced by the above process has a shrinkage of ≥30%, preferably ≥35%.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：为了获得不含透明度的高收缩率丙烯腈纤维，通过向具有特定组成的共聚物的溶液中加入水，并进行纺丝的湿纺丝。构成：将丙烯腈含量为80-92wt％的共聚物溶解在二甲基甲酰胺，二甲基乙酰胺或二甲基亚砜中，并将1.0〜6.0wt％的水加入到涂料中。将通过上述纺丝液的湿法纺丝得到的纤维以拉伸比<= 3.0进行一次拉伸，干燥，最后在100-140℃的热风中以拉伸比进行二次拉伸 1.5-3.0。即使通过湿法纺丝法也能够得到不含透明性的纤维，可以消除二次拉伸后的低温干燥处理。通过上述方法制备的标题纤维的收缩率> 30％，优选> = 35％。

3. 发明专利

JPS5759944A Halogen-containing polymer composition 失效
标题翻译：含氢聚合物组合物
公开(公告)号：JPS5759944A
公开(公告)日：1982-04-10
申请号：JP13617080
申请日：1980-09-29
申请人： Kanegafuchi Chem Ind Co Ltd
发明人： KONISHI AKIO , KURIOKA SHIYUNICHIROU
IPC分类号： C08L27/00 , C08G59/00 , C08G59/18 , C08K5/13 , C08K5/29 , C08K5/34 , C08K5/45 , C08K5/46 , C08K5/51 , C08L1/00 , C08L33/00 , C08L33/02 , C08L63/00
摘要： PURPOSE: To prepare the titled composition giving a textile product having remarkably improved light resistance and weather resistance, by compounding a specific UV-absorber in combination with an epoxy-containing polymer.
CONSTITUTION: A halogen-containing polymer such as vinyl chloride polymer, a compolymer of vinyl chloride and acrylonitrile monomer, etc., is compounded with a compound selected from benzotriazole compounds, cyanoacrylate compounds, and nickel complex salt compounds, together with an epoxy-containing polymer. The epoxy-containing polymer is e.g. glycidyl methacrylate polymer, epoxidized buta- diene polymer, etc., and pref. has a low epoxy number. It is possible to incorporate metallic soaps, antioxidants, etc. for the thermal stabilization, however, the additive should be selected cautiously because the combined use with some organotin compound causes the lowering of the effect.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：通过将特定的紫外线吸收剂与含环氧基的聚合物组合，制备给出具有显着改善的耐光性和耐候性的纺织品的标题组合物。构成：将氯乙烯聚合物，氯乙烯和丙烯腈单体的共聚物等含卤素聚合物与选自苯并三唑化合物，氰基丙烯酸酯化合物和镍络盐化合物的化合物与含环氧基的化合物聚合物。含环氧基的聚合物是例如。甲基丙烯酸缩水甘油酯聚合物，环氧化丁二烯聚合物等。具有低环氧数。可以将金属皂，抗氧化剂等掺入到热稳定化中，但是由于与一些有机锡化合物的组合使用导致效果的降低，因此应谨慎选择添加剂。

4. 发明专利

JPS6112910A Manufacture of acrylonitrile synthetic fiber having high shrinkage 失效
标题翻译：具有高收缩率的丙烯腈合成纤维的制备
公开(公告)号：JPS6112910A
公开(公告)日：1986-01-21
申请号：JP13145684
申请日：1984-06-26
申请人： Kanegafuchi Chem Ind Co Ltd
发明人： KONISHI AKIO , KUBO YUUJI , INOUE MASAHARU
IPC分类号： D01F6/38 , D01D5/06 , D02J1/22
摘要： PURPOSE: To obtain the titled fiber in high efficiency, without using a low- temperature drying after the secondary drawing, by carrying out the wet spinning of a copolymer composed mainly of acrylonitrile and containing a specific amount of acid group, and subjecting the obtained filament successively to the primary drawing, drying, and the secondary drawing in hot air.
CONSTITUTION: A high-shrinkage fiber is produced by the following process using a copolymer having an acrylonitrile content of 80W92wt%. Acrylonitrile is copolymerized with a monomer containing acid group (e.g. sodium methallylsulfonate) to obtain an acrylonitrile copolymer containing ≥60m-equivalent of the acid group per 1kg of the copolymer. The obtained copolymer is dissolved in DMF, etc. and the dope is extruded through a spinning nozzle into a coagulation bath. The filament obtained by the above wet-spinning process is subjected to the primary drawing at a draw ratio of ≤3.0, dried, and finally subjected to the secondary drawing in hot air of 100W140°C at a draw ratio of 1.5W3.0.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：为了高效率地获得标准纤维，在二次拉伸后不使用低温干燥，通过进行主要由丙烯腈组成并含有特定量的酸基的共聚物的湿法纺丝，并将所得到的长丝先后在热风中进行一次拉制，干燥和二次拉拔。构成：使用丙烯腈含量为80-92wt％的共聚物，通过以下方法制造高收缩纤维。丙烯腈与含有酸基团的单体（例如甲代烯丙基磺酸钠）共聚，得到每1kg共聚物含有> = 60m当量酸性基团的丙烯腈共聚物。将得到的共聚物溶解在DMF等中，通过纺丝喷嘴将涂料挤出成凝固浴。通过上述湿法纺丝工艺获得的长丝以拉伸比<= 3.0进行初步拉伸，干燥，最后在100-140℃的热空气中以1.5的拉伸比进行二次拉伸 -3.0。

5. 发明专利

JPS5782516A Acrylonitrile synthetic fiber and preparation 失效
标题翻译：丙烯腈合成纤维和制备
公开(公告)号：JPS5782516A
公开(公告)日：1982-05-24
申请号：JP15629580
申请日：1980-11-05
申请人： Kanegafuchi Chem Ind Co Ltd
发明人： KONISHI AKIO , FUJIWARA KAZUAKI
IPC分类号： D01F6/38 , C08K5/57 , C08K5/58 , C08L27/08 , C08L27/10 , D01F6/54 , D01F6/68
摘要： PURPOSE: To obtain the titled synthetic fibers having improved luster, transparancy and flame retardancy, by spinning a solution containing a polymer consisting of acrylonitrile, a monomer containing a halogen and a copolymerizable monomer in a specific composition, an organotin compound and an organic solvent.
CONSTITUTION: A solution containing (A) a polymer consisting of (a) 30W70wt% acrylonitrile, (b) 70W30wt% monomer containing a halogen, e.g. vinyl chloride, and (c) 0W10wt% one or more olefinic monomers copolymerizable therewith, e.g. acrylamide, (B) an organotin compound, e.g. dibutyltin ethylmaleate, and (C) an organic solvent, e.g. dimethylformamide, as a spinning solution is spun to give the aimed fibers having improved luster and transparancy. The amount of the component (B) is preferably 0.2W10wt% based on the component (A).
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了获得具有改善的光泽，透明性和阻燃性的标题合成纤维，通过纺丝含有丙烯腈的聚合物，含有卤素的单体和具有特定组成的可共聚单体的溶液，有机锡化合物和有机溶剂。构成：含有（A）由（a）30-70重量％丙烯腈，（b）70-30重量％含卤素单体组成的聚合物的溶液，氯乙烯，和（c）0-10重量％的一种或多种可与其共聚的烯属单体。丙烯酰胺，（B）有机锡化合物，例如二丁基锡马来酸乙酯，和（C）有机溶剂，例如将纺丝溶液纺丝，得到具有改善的光泽和透明度的目标纤维。基于组分（A），组分（B）的量优选为0.2-10重量％。

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