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    • 9. 发明专利
    • BRASS ALLOYING METHOD BY THERMAL DIFFUSION
    • JPS60141865A
    • 1985-07-26
    • JP25030783
    • 1983-12-29
    • KAWASAKI STEEL COKAWATETSU KOSEN KOGYO KK
    • ARAI KAZUOKATAOKA KUNIHIKO
    • C23C10/28C23C26/00C25D21/12
    • PURPOSE:To correct the characteristic of a plating liquid, plating current and diffusion voltage to the set values with respect to the prescribed beta bruss rate with high accuracy by measuring on-line and continuously the characteristic of the plating liquid, the coating weight of copper and zinc and the beta brass rate after the thermal diffusion treatment and controlling on-line and automatically the characteristic of the plating liquid, plating current and diffusion voltage. CONSTITUTION:A steel wire 1 is passed successively through a copper plating cell 6 and a zinc plating cell 7 and is thus plated with copper and zinc. The plated wire is passed through a diffusion soaking cell 10 and is subjected to brass alloying by the thermal diffusion treatment. The pH, temp., specific gravity, concn., etc. of the plating liquid are continuously measured by a fluorescent X-ray analysis device 15 and a measuring device 16 for the characteristic of the plating liquid in this stage and the coating weight of the copper and zinc on the steel wire 1 and the beta brass rate after the thermal diffusion treatment are on- line measured by an X-ray diffraction device 18. The characteristic of the plating liquid, plating current and diffusion voltage are thus on-line and automatically controlled and are corrected to the set values with respect to the prescribed beta brass rate with high accuracy.
    • 10. 发明专利
    • METHOD OF QUANTITATIVE ANALYSIS OF MULTI-ELEMENT ALLOY PLATING LAYER BY X-RAY MEASUREMENT
    • JPS58150845A
    • 1983-09-07
    • JP3306482
    • 1982-03-04
    • KAWATETSU KOSEN KOGYO KKKAWASAKI STEEL CO
    • ARAI KAZUOKATAOKA KUNIHIKO
    • G01N23/223
    • PURPOSE:To perform the quantitative analysis of component elements precisely and simply without necessitating the preparation of a working curve, by conducting calculations based on theoretical formulas from the integral strength value of fluorescent X-rays of each component element of the multi-element alloy plating layer of a body to be inspected and from the integral strength of each component element of a standard sample. CONSTITUTION:The integral strength In of the flrorometric X-ray of each component element of a multi-element alloy plating layer is measured, and the quantitative analysis of the plating layer is performed from this integral strength In and the integral strength I0 of each component element of a standard sample consisting of the same component elements as the plating layer on the basis of theoretical formulas comprising a formulaI and Formula II wherein Pn is the ratio in weight of each component element of a body to be inspected; Qn, kio the ratio in weight of n of two elements n and ki in the standard sample: i=1,... (m-1) in an m-element alloy: Rn, ki Formula III wherein Rn=In/Ino; Rki=Iki/Ikio: M the ratio in sticking quantity of plating: Pno the ratio in weight of n element of the standard sample: and Mo the ratio in sticking quantity of plating of the standard sample . This method enables highly-precise quantification in a short time, while unnecessitating the preparation of a working curve which requires considerable processes and time.