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    • 2. 发明专利
    • NON-ALKALI DECORATING TYPE LUBRICATING RESIN TREATED STEEL PLATE AND MANUFACTURE THEREOF
    • JPH10109376A
    • 1998-04-28
    • JP26743196
    • 1996-10-08
    • KAWASAKI STEEL CO
    • OGATA HIROYUKIHIGAI KAZUHIKOOGISHI HIDEO
    • B05D3/02B05D7/24B32B15/08
    • PROBLEM TO BE SOLVED: To realize the possession of an excellent primary rust-proofness without the application of a rust resisting oil and of an excellent press-workability without the application of a press oil, excellent weldability, and the possession of an enough adhesion of overcoating film even without zinc phosphate film and of a water-resistant secondary adhesion. SOLUTION: This steel plate has a film, which consists of an urethane-based resin having Tg of 40-100 deg.C and the acid value of 10-50, and a polyethylene wax having Ts of 90-130 deg.C, the coating build-up of which is 0.5-3g/m , the solid ratio of urethane/ polyethylene of which is 97/3-80/20 and the film-forming percentage defined by the following formula of which is 70-100%. The formula: the film-forming percentage (%) of a lubricating treated film = [(the number of particles in an air drived film -the number of particles in an baked film)/the number of particles in the air dried film] ×100, in the formula, the number of particles is the number per 1μm×1μm of urethane-based resin particles and of polyethylene wax particles, which respectively are clearly confirmed when the rupture cross-section of the lubricating film on the surface of a steel plate under the state that the resin-treated steel plate is cooled in liquid nitrogen and then brittly fractured by abruptly apply a force is observed with an electron microscope at 10,000 power.
    • 3. 发明专利
    • GALVANIZED STEEL SHEET WITH ORGANIC COATING, EXCELLENT IN LUBRICITY
    • JPH08174758A
    • 1996-07-09
    • JP32611994
    • 1994-12-27
    • KAWASAKI STEEL CO
    • HIGAI KAZUHIKOOGATA HIROYUKINARUSE YOSHIHIRO
    • B32B15/082B32B15/08B32B15/085C23C28/00C25D11/38
    • PURPOSE: To obtain a galvanized steel sheet with an organic coating, which displays excellent lubricity even under severe press molding conditions, by forming a specific chromate coating on one of faces of a zinc- or zinc alloy-galvanized steel sheet and forming a specific hydrophilic resin composition coating on the chromate coating. CONSTITUTION: A chromate layer having a deposited quantity of 2-150mg/m in terms of metal chrome is formed on one of faces of a zincor zinc alloy-galvanized steel sheet. A hydrophilic resin composition coating is formed on the chromate layer. In the case of forming this coating, 10-100 pts.wt. of an aqueous-dispersible polyolefin resin, or of an aqueous-dispersible fluororesin, each having a melting point of at least 50 deg.C, in terms of solid content are contained in the coating with respect to 100 pts.wt. of the solid content of the hydrophilic resin. The aqueous-dispersible polyolefin resin, or the aqueous-dispersible fluororesin, in the hydrophilic resin composition coating is segregated on the surface of the hydrophilic resin coating, and the aqueous-dispersible polyolefin resin, or the aqueous-dispersible fluororesin, is made to be present as particles on the surface of the hydrophilic resin coating in the protortion of 2-30 particles/μm .