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1. 发明专利

JP2014198807A ポリスチレン系樹脂押出発泡体の製造方法有权
标题翻译：生产聚苯乙烯树脂挤出泡沫的方法
公开(公告)号：JP2014198807A
公开(公告)日：2014-10-23
申请号：JP2013108167
申请日：2013-05-22
申请人：株式会社ジェイエスピー , Jsp Corp
发明人： KIKUZAWA MAKOTO , OKUDA AKIRA , KOGURE NAOCHIKA
IPC分类号： C08J9/14
摘要：【課題】押出発泡時に黒点が発生することを防ぎ、かつ基材樹脂であるポリスチレン系樹脂が分解して分子量の低下や黄変を抑制した難燃性に優れるポリスチレン系樹脂押出発泡体の製造方法を提供する。【解決手段】ポリスチレン系樹脂、難燃剤及び発泡剤を押出機に供給し、これらを押出機にて混練してなる発泡性溶融樹脂組成物を押出して押出発泡体を製造する方法において、難燃剤が、(1)ポリスチレン−臭素化ポリブタジエンブロック共重合体と(2)ビスフェノール型エポキシ化合物及び/又はノボラック型エポキシ化合物と(3)フェノール系酸化防止剤、ヒンダードアミン系酸化防止剤及びリン系酸化防止剤から選択される1又は2以上の酸化防止剤とを含む溶融混練物であることを特徴とする。【選択図】なし
摘要翻译：要解决的问题：提供一种具有优异的阻燃性的聚苯乙烯树脂挤出发泡体的制造方法，其防止在挤出发泡时产生黑斑，抑制由于聚苯乙烯树脂作为基质而导致的分子量的降低和变黄树脂。解决方案：在通过向挤出机中提供聚苯乙烯树脂，阻燃剂和发泡剂制备聚苯乙烯树脂挤出泡沫的方法中，挤出通过挤出机捏合得到的可发泡熔融树脂组合物，阻燃剂是熔融捏和混合物，其包含（1）聚苯乙烯 - 溴化聚丁二烯嵌段共聚物，（2）双酚型环氧化合物和/或酚醛清漆型环氧化合物，和（3）一种或两种以上抗氧化剂，其选自酚类抗氧化剂，受阻胺系抗氧化剂和磷系抗氧化剂。

2. 发明专利

JP2012218364A Multilayer extruded polystyrene resin foam board, and method of manufacturing the same 有权
标题翻译：多层挤出聚苯乙烯树脂发泡板及其制造方法
公开(公告)号：JP2012218364A
公开(公告)日：2012-11-12
申请号：JP2011088353
申请日：2011-04-12
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： OKUDA AKIRA , ISHIKAWA TATSUYUKI , KOGURE NAOCHIKA
IPC分类号： B29C47/06 , B29K25/00 , B29K105/04 , B29L7/00 , B29L9/00 , B32B5/18 , B32B27/30 , C08J9/14
摘要： PROBLEM TO BE SOLVED: To provide a multilayer extruded polystyrene resin foam board small in thermal conductivity even when a physical foaming agent high in gas permeation speed to a polystyrene resin is used, and having high heat insulation performance over a long term, and to provide a method of manufacturing the same.SOLUTION: In this multilayer extruded polystyrene resin foam board formed by laminating a resin layer at least on one surface of a polystyrene resin foamed layer, a resin composing the resin layer contains at least one kind of resin (A) 1 (5-60 wt.%) selected from a polyester resin and a polyamide resin, and a polystyrene resin (B) 2 (95-40 wt.%) (where the total of the resin (A) and the polystyrene resin (B) is 100 wt.%); the resin (A) satisfies a specific condition; and, in the resin layer, the resin (A) and the polystyrene resin (B) form a dispersion phase and a continuous phase, respectively.
摘要翻译：要解决的问题：为了提供导热性小的多层挤出聚苯乙烯树脂发泡体，即使使用高聚苯乙烯树脂的透气速度高的物理发泡剂，并且长期具有高隔热性能，并提供其制造方法。解决方案：在通过在聚苯乙烯树脂发泡层的至少一个表面层压树脂层而形成的多层挤出聚苯乙烯树脂发泡体板中，构成树脂层的树脂含有至少一种树脂（A）1（5 -60重量％）和聚苯乙烯树脂（B）2（95-40重量％）（其中树脂（A）和聚苯乙烯树脂（B）的总量为 100重量％）; 树脂（A）满足特定条件; 在树脂层中，树脂（A）和聚苯乙烯树脂（B）分别形成分散相和连续相。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2013194101A Method for producing extruded polystyrene resin heat-insulating foam board 有权
标题翻译：生产挤出聚苯乙烯树脂绝热泡沫板的方法
公开(公告)号：JP2013194101A
公开(公告)日：2013-09-30
申请号：JP2012061093
申请日：2012-03-16
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： OKUDA AKIRA , ISHIKAWA TATSUYUKI , KOGURE NAOCHIKA
IPC分类号： C08J9/04
CPC分类号： C08J9/122 , C08J9/149 , C08J2201/03 , C08J2203/10 , C08J2203/14 , C08J2203/162 , C08J2203/202 , C08J2205/052 , C08J2325/06
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an extruded polystyrene resin heat-insulating foam board having small thermal conductivity, excellent long-term heat-insulating properties, a large thickness, a high expansion rate, good appearance and the like by using a physical blowing agent having zero or extremely small ozone depletion potential and small global warming potential when producing the extruded polystyrene resin heat-insulating foam board.SOLUTION: There is provided a method for producing an extruded heat-insulating foam board having a thickness of 10 to 150 mm, an apparent density of 20 to 50 kg/mand a closed cell content of at least 80% by extrusion foaming of a foamable resin melt containing a base resin composed primarily of a polystyrene resin, a physical blowing agent and a flame retardant, wherein a mixed physical blowing agent of 3 to 50 mol% of a hydrofluoroolefin, 30 to 70 mol% of a saturated hydrocarbon having 3 to 5 carbon atoms, and 5 to 50 mol% of water and/or carbon dioxide (where the sum of the contents of the hydrofluoroolefin, saturated hydrocarbon having 3 to 5 carbon atoms, water and/or carbon dioxide is 100 mol%) is used as the physical blowing agent.
摘要翻译：要解决的问题：提供一种通过使用具有导热性低，优异的长期绝热性，大厚度，高膨胀率，良好外观等的挤出聚苯乙烯树脂绝热泡沫板的制造方法一种在制造挤压聚苯乙烯树脂绝热泡沫板时具有零或极小的臭氧消耗潜能和小的全球变暖潜能的物理发泡剂。解决方案提供一种制造厚度为10的挤压绝热泡沫板的方法至150mm，表观密度为20〜50kg / cm2，通过挤出发泡含有主要由聚苯乙烯树脂，物理发泡剂和阻燃剂构成的基础树脂的可发泡树脂熔体，封闭的细胞含量至少为80％其中，将3〜50摩尔％的氢氟烯烃，30〜70摩尔％的碳原子数3〜5的饱和烃和5〜50摩尔％的w的混合物理发泡剂惰性和/或二氧化碳（其中氢氟烯烃，碳原子数3〜5的饱和烃，水和/或二氧化碳的含量之和为100摩尔％）的总和用作物理发泡剂。

4. 发明专利

JP2012012610A Method for producing polystyrene-based resin extrusion foamed plate 有权
标题翻译：生产聚苯乙烯树脂挤出泡沫板的方法
公开(公告)号：JP2012012610A
公开(公告)日：2012-01-19
申请号：JP2011181704
申请日：2011-08-23
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： NAITO MASATO , KOGURE NAOCHIKA , AKIYAMA TERUYUKI , OKUDA AKIRA
IPC分类号： C08J9/14 , C08K3/34 , C08K5/13 , C08K5/521 , C08L25/06
摘要： PROBLEM TO BE SOLVED: To provide a polystyrene-based resin extrusion foamed plate that simultaneously has high flame retardancy and recyclability, and a method for producing a polystyrene-based resin extrusion foamed plate that enables stable production of the extrusion foamed plate.SOLUTION: In the method for producing a foamed plate having apparent density of 20-60 kg/mand a thickness of 10-150 mm by performing extrusion foaming of a foamable molten resin composition which is obtained by kneading of a polystyrene-based resin, a cell regulator, a flame retardant, and a foaming agent, a certain rate of inorganic substances are blended as the cell regulator, a brominated bisphenol ether derivative having special structure and a phosphoric ester are included as the flame retardant, and the brominated bisphenol ether derivative and the phosphoric ester are each blended in a certain rate.
摘要翻译：解决的问题：提供同时具有高阻燃性和可回收性的聚苯乙烯类树脂挤出发泡板，以及能够稳定生产挤出发泡板的聚苯乙烯类树脂挤出发泡板的制造方法。解决方案：在通过进行挤出发泡的生产具有20-60kg / m 2的表观密度的泡沫板的方法中，具有特定结构的溴化双酚醚衍生物作为细胞调节剂，配合通过将聚苯乙烯类树脂，电池调节剂，阻燃剂，发泡剂混合而得到的发泡性熔融树脂组合物并且包括磷酸酯作为阻燃剂，并且溴化双酚醚衍生物和磷酸酯各自以一定的速率混合。版权所有（C）2012，JPO＆INPIT

5. 发明专利

JP2012007094A Thermoplastic resin extrusion foamed heat insulating plate 有权
标题翻译：热塑性树脂挤出发泡热绝缘板
公开(公告)号：JP2012007094A
公开(公告)日：2012-01-12
申请号：JP2010144995
申请日：2010-06-25
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： OKUDA AKIRA , ISHIKAWA TATSUYUKI , KOGURE NAOCHIKA , SATO KAZUMASA
IPC分类号： C08J9/12 , B29C47/00 , B29K25/00 , B29K105/04 , B29L7/00 , C08L25/04 , C08L67/02
摘要： PROBLEM TO BE SOLVED: To provide a thermoplastic resin extrusion foamed heat insulating plate having a low thermal conductivity and excellent in heat insulation over a long period.SOLUTION: The thermoplastic resin extrusion foamed heat insulating plate is prepared by using: as a base material a mixture in which a relatively large amount of an amorphous or a low-crystalline polyester resin is blended in a polystyrene resin, wherein the polyester resin exhibits an endothermic peak heat quantity of
摘要翻译：要解决的问题：提供一种具有低导热性和优异的隔热性的热塑性树脂挤出发泡隔热板。解决方案：热塑性树脂挤出发泡绝热板通过使用在聚苯乙烯树脂中共混有相对大量的无定形或低结晶性聚酯树脂的混合物作为基料，其中聚酯树脂显示基于由热通量差示扫描量热计以10℃/ min的加热速率获得的DSC曲线从聚酯树脂熔化而产生的<5J / g（包括0）的吸热峰热量根据“ 在JIS K7122（1987）中记载的“在固定热处理后测定熔融热的情况”（试验片的调节条件下的加热速度和冷却速度分别为10℃/ min）; 以及对聚苯乙烯树脂具有高渗透速度的物理发泡剂。热塑性树脂挤出发泡隔热板在挤出发泡时的生产稳定性优异，在泡沫表面上没有不规则的波纹，具有足够的厚度，高发泡率和高闭孔比，导热性低，优异在长时间的隔热中，辐射隔热特别优异，并具有耐热性。版权所有（C）2012，JPO＆INPIT

6. 发明专利

JP2013082805A Thermoplastic resin extrusion foamed heat insulating plate 有权
标题翻译：热塑性树脂挤出发泡热绝缘板
公开(公告)号：JP2013082805A
公开(公告)日：2013-05-09
申请号：JP2011223418
申请日：2011-10-07
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： OKUDA AKIRA , ISHIKAWA TATSUYUKI , KOGURE NAOCHIKA
IPC分类号： C08J9/14
摘要： PROBLEM TO BE SOLVED: To provide a thermoplastic resin extrusion foamed heat insulating plate which is an extrusion foam having as a base material resin a mixture of a polystyrene resin and an amorphous or low-crystalline polyester resin, and which maintains stable heat insulation for a long period and has a large thickness and good appearance.SOLUTION: The thermoplastic resin extrusion foamed heat insulating plate is obtained by extrusion-foaming a foamable resin melt containing a foaming agent composed of at least a hydrofluoroolefin, and has an apparent density of 20 to 50 kg/mand a thickness of 10 to 150 mm, wherein the base material resin constituting the foamed heat insulating plate is composed of a polystyrene resin and a polyester resin satisfying the following condition, and the ratio of the polystyrene resin and the polyester resin is 95:5 to 50:50. The condition: the endothermic peak heat quantity is
摘要翻译：要解决的问题：提供作为基材的热塑性树脂挤出发泡绝热板，其是聚苯乙烯树脂和无定形或低结晶性聚酯树脂的混合物，并且保持稳定的热量保温期长，厚度大，外形美观。解决方案：热塑性树脂挤出发泡绝热板通过挤出发泡含有至少由氢氟烯烃组成的发泡剂的可发泡树脂熔体而获得，其表观密度为20至50kg / m 2 SP SP = “POST”> 3 ，厚度为10〜150mm，其中构成发泡绝热板的基材树脂由聚苯乙烯树脂和满足以下条件的聚酯树脂构成，聚苯乙烯树脂和聚酯树脂为95:5至50:50。条件：根据以10℃/分钟的加热速度获得的DSC曲线，涉及聚酯树脂熔化的吸热峰热量为“5J / g（包括0）在JIS K7122（1987）中描述的使用热通量差示扫描量热计进行一定热处理后的熔融。版权所有（C）2013，JPO＆INPIT

7. 发明专利

JP2012255078A Method for manufacturing thermoplastic resin extrusion foam 有权
标题翻译：制造热塑性树脂挤出泡沫的方法
公开(公告)号：JP2012255078A
公开(公告)日：2012-12-27
申请号：JP2011128587
申请日：2011-06-08
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： OKUDA AKIRA , ISHIKAWA TATSUYUKI , KOGURE NAOCHIKA
IPC分类号： C08J9/12
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a thermoplastic resin extrusion foam, which can manufacture an extrusion foam having a small thermal conductivity and capable of maintaining thermal insulation and good in the surface state even if a foaming agent is used which has a zero or very low ozone depletion potential and a low global warming potential.SOLUTION: The method for manufacturing thermoplastic resin extrusion foam includes melting and kneading a specific saturated hydrocarbon (a), carbon dioxide (b), water (c) and a thermoplastic resin to obtain a foaming thermoplastic resin melted material, and extrusion foaming the foaming thermoplastic resin melted material, wherein the thermoplastic resin is composed of a specific polyester copolymer (B) and a polystyrene resin (A); the blend amount of the polyester copolymer (B) is 5 to 150 pts.wt. to 100 pts.wt. of the polystyrene resin (A); the blend amount of water (c) is ≥0.01 mol and
摘要翻译：解决的问题：提供一种制造热塑性树脂挤出泡沫的方法，即使使用发泡剂也能制造热导率小且能够保持隔热性和表面状态良好的挤出泡沫的方法臭氧消耗潜力零或极低，全球变暖潜能低。解决方案：制造热塑性树脂挤出泡沫的方法包括熔融和捏合特定的饱和烃（a），二氧化碳（b），水（c）和热塑性树脂，以获得发泡热塑性树脂熔融材料，并挤出发泡热塑性树脂熔融材料发泡，其中热塑性树脂由特定的聚酯共聚物（B）和聚苯乙烯树脂（A）组成; 聚酯共聚物（B）的混合量为5〜150重量份。到100磅的聚苯乙烯树脂（A）; 水（c）的混合量≥0.01mol，热塑性树脂1kg〜1kg。版权所有（C）2013，JPO＆INPIT

8. 发明专利

JP2012051971A Process for producing polycarbonate resin extruded foam, and polycarbonate resin extruded foam 有权
标题翻译：生产聚碳酸酯树脂挤出泡沫的方法和聚碳酸酯树脂挤出泡沫
公开(公告)号：JP2012051971A
公开(公告)日：2012-03-15
申请号：JP2010193696
申请日：2010-08-31
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： ISHIKAWA TATSUYUKI , OKUDA AKIRA , KOGURE NAOCHIKA
IPC分类号： C08J9/04
CPC分类号： C08G63/672 , C08J9/0061 , C08J2201/03 , C08J2369/00 , C08J2467/02 , C08L67/02 , C08L69/00 , C08L2666/18
摘要： PROBLEM TO BE SOLVED: To provide a process for producing a polycarbonate resin extruded foam having small thermal conductivity and excellent heat insulation properties, capable of sustaining the excellent heat insulation properties for a long period, and having a high mechanical strength, and to provide the polycarbonate resin extruded foam.SOLUTION: The process for producing the polycarbonate resin extruded foam includes a process of kneading a polycarbonate resin and a polyester resin together with a blowing agent to afford a foamable melted resin, and extruding and foaming the foamable melted resin, wherein the polyester resin is a polyester copolymer including diol component units which contain therein glycol component units having a cyclic ether structure in an amount of 25 to 50 mol% of the diol component units and dicarboxylic acid component units, and the blended proportion of the polyester resin is 5-100 pts.wt. based on 100 pts.wt. of the polycarbonate resin.
摘要翻译：待解决的问题：提供一种能够长时间保持优异的绝热性能并且具有高机械强度的具有导热性低和隔热性能优异的聚碳酸酯树脂挤出泡沫的制造方法，以及以提供聚碳酸酯树脂挤出的泡沫。解决方案：聚碳酸酯树脂挤出泡沫的制造方法包括将聚碳酸酯树脂和聚酯树脂与发泡剂一起捏合以提供可发泡的熔融树脂，并将可发泡的熔融树脂挤出和发泡的方法，其中聚酯树脂是包含二醇成分单元的聚酯共聚物，其中含有二醇成分单元和二羧酸成分单元的25〜50摩尔％的环状醚结构的二醇成分单元，聚酯树脂的配合比例为5 -100 pts.wt 基于100重量的聚碳酸酯树脂。版权所有（C）2012，JPO＆INPIT

9. 发明专利

JP2011219631A Heat insulation plate of extruded thermoplastic resin foam 有权
标题翻译：超热塑性树脂泡沫的热绝缘板
公开(公告)号：JP2011219631A
公开(公告)日：2011-11-04
申请号：JP2010090555
申请日：2010-04-09
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： OKUDA AKIRA , ISHIKAWA TATSUYUKI , KOGURE NAOCHIKA , SATO KAZUMASA
IPC分类号： C08J9/14
CPC分类号： C08J9/14 , B29C44/505 , B29K2025/00 , B29K2067/00 , B29K2105/046 , B29K2995/0015 , B29L2031/10 , C08J9/0061 , C08J2201/03 , C08J2205/052 , C08J2325/06 , C08J2367/02 , C08J2425/00 , C08J2467/00
摘要： PROBLEM TO BE SOLVED: To provide a heat insulation plate of extruded thermoplastic resin foam, capable of suppressing dissipation of a foaming agent from a foam even when using a physical foaming agent such as HC whose ozone depletion potential is zero or extremely low and whose global warming potential is small, and having a small heat conductivity and excellent heat insulating property for a long period.SOLUTION: In this heat insulation plate of extruded thermoplastic resin foam, having an apparent density of 20-50 kg/m, a closed cell ratio of 85% or more and a thickness of 10-150 mm, and containing a non-halogen-based organic physical blowing agent, the thermoplastic resin is a mixture of a polystyrene resin and a polyester resin satisfying such a condition that an endothermic peak calorific value following fusion is less than 5 J/g (including 0), which is based on a DSC curve obtained when adopting "a case for measuring the heat of fusion after performing a fixed heat treatment" (both heating speed and cooling speed are 10°C/min respectively) which is described in JIS K7122 (1987).
摘要翻译：要解决的问题：为了提供一种挤出的热塑性树脂发泡体的隔热板，即使使用臭氧消耗电位为零或极低的HC等物理发泡剂，也能够抑制发泡剂从泡沫中的耗散其全球变暖潜力小，长时间导热性好，隔热性优异。解决方案：在该挤出热塑性树脂泡沫隔热板中，其表观密度为20-50kg / m 3 / SP，闭孔率为85％以上厚度为10-150mm，并且含有非卤素类有机物理发泡剂，热塑性树脂是聚苯乙烯树脂和聚酯树脂的混合物，其满足融合后的吸热峰值发热值较小的条件基于采用“进行固定热处理后的熔融热的情况”（加热速度和冷却速度分别为10℃/分钟）时获得的DSC曲线的5J / g（包括0）），其在JIS K7122（1987）中描述。版权所有（C）2012，JPO＆INPIT

10. 发明专利

JP2006137862A Polystyrene-base resin extruded foam plate and method for producing the same 有权
标题翻译：聚苯乙烯树脂树脂挤出泡沫板及其生产方法
公开(公告)号：JP2006137862A
公开(公告)日：2006-06-01
申请号：JP2004329106
申请日：2004-11-12
申请人： Jsp Corp , 株式会社ジェイエスピー
发明人： NAITO MASATO , KOGURE NAOCHIKA , AKIYAMA TERUYUKI , OKUDA AKIRA
IPC分类号： C08J9/12 , C08K5/06 , C08K5/521 , C08L25/04
CPC分类号： C08J9/149 , C08J9/0019 , C08J9/0057 , C08J9/127 , C08J2201/03 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2203/142 , C08J2325/06
摘要： PROBLEM TO BE SOLVED: To provide a polystyrene-base resin extruded foam plate which is high in flame-retardance and recyclability; and a method which can produce stably the polystyrene-base resin extruded foam plate.
SOLUTION: The method is a method for extruding and foaming a foamable molten resin composition made by blending a polystyrene-base resin, a flame retardant, and a foaming agent to produce a foam plate having an apparent density of 20-60 kg/m
3 and a thickness of 10-150 mm, wherein the flame retardant comprises a brominated bisphenol ether derivative represented by formula (1) and a phosphate ester, and the brominated bisphenol ether derivative has a rate of 0.5-5 pts.wt, and the phosphate ester has a rate of 0.1-6 pts.wt. relative to 100 pts.wt. of the polystyrene-base resin, respectively. In the formula, R is a 1-3C alkyl group, and A is -C(CH
3 )
2 -, -SO
2 -, -S- or -CH
2 -.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种阻燃性和可回收性高的聚苯乙烯基树脂挤出泡沫板; 以及可以稳定地生产聚苯乙烯基树脂挤出泡沫板的方法。解决方案：该方法是将通过混合聚苯乙烯基树脂，阻燃剂和发泡剂制成的可发泡熔融树脂组合物挤出和发泡的方法，以制造表观密度为20-60kg的泡沫板 / m 3＆lt; 3＆gt;和10〜150mm的厚度，其中阻燃剂包含由式（1）表示的溴化双酚醚衍生物和磷酸酯，溴化双酚醚衍生物的比例为 0.5-5重量％，磷酸酯的比例为0.1-6重量份。相对于100 pts.wt 的聚苯乙烯基树脂。在该式中，R为1-3C烷基，A为-C（CH 3）SO 2 - ， - SB 2 - ，-S-或-CH 2 SB 2 - 。版权所有（C）2006，JPO＆NCIPI

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