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    • 1. 发明专利
    • Method of separating phosphorus
    • 分离磷的方法
    • JP2013147382A
    • 2013-08-01
    • JP2012009174
    • 2012-01-19
    • Jfe Steel CorpJfeスチール株式会社Kurita Water Ind Ltd栗田工業株式会社
    • TAKAHASHI KATSUNORIWATANABE KEIJIKUWAYAMA MICHIHIROYAO YASUKOSUMITA ICHIROSEKIMOTO TOMOHIRO
    • C01B25/01C21C1/02F27D15/00
    • PROBLEM TO BE SOLVED: To provide a method capable of efficiently and economically separating phosphorus from a composite oxide which contains the phosphorus and contains iron and calcium at a relatively high concentration.SOLUTION: A composite oxide containing 10 mass% or more of CaO, 10 mass% or more of total Fe, and 10 mass% or more of POis brought into contact with 1-normal or more alkali metal hydroxide aqueous solution, and phosphorus in the composite oxide is extracted into the alkali metal hydroxide aqueous solution. Alternatively, a composite oxide containing 30 mass% or more of CaO, 10 mass% or more of total Fe, and 1-5 mass% of POwith CaO/SiO(mass ratio) being 2 or greater is brought into contact with 5-normal or more alkali metal hydroxide aqueous solution, and phosphorus in the composite oxide is extracted into the alkali metal hydroxide aqueous solution. From the alkali metal hydroxide aqueous solution in which the phosphorus is extracted, phosphate ions are separated and the phosphorus is recovered.
    • 要解决的问题:提供一种能够高效且经济地从含有磷并且含有较高浓度的铁和钙的复合氧化物中分离出磷的方法。溶液:含有10质量%以上的CaO,10 质量%以上的Fe,10质量%以上的POis与1价以上的碱金属氢氧化物水溶液接触,复合氧化物中的磷被提取到碱金属氢氧化物水溶液中。 或者,将含有30质量%以上的CaO,10质量%以上的Fe和1-5质量%的PO与CaO / SiO(质量比)为2以上的复合氧化物与5正常 或更多的碱金属氢氧化物水溶液,并且复合氧化物中的磷被提取到碱金属氢氧化物水溶液中。 从其中提取磷的碱金属氢氧化物水溶液中分离磷酸根离子并回收磷。
    • 3. 发明专利
    • Treatment method of fluorine-containing wastewater
    • 含氟废水处理方法
    • JP2007190517A
    • 2007-08-02
    • JP2006012782
    • 2006-01-20
    • Kurita Water Ind Ltd栗田工業株式会社
    • KATO ISAMUSEKIMOTO TOMOHIRO
    • C02F1/58
    • PROBLEM TO BE SOLVED: To obtain treated water, from which fluorine is sufficiently removed, by stably and efficiently treating fluorine-containing wastewater with aluminum coexistence using a calcium fluoride method.
      SOLUTION: A calcium compound is added to the fluorine-containing wastewater with aluminum coexistence while phosphoric ions are further added so that P/Al (molar ratio) becomes 1 or above and trivalent iron ions are further added so that an Fe/P (molar ratio) becomes 1 or more to subject insoluble matter to solid-liquid separation under a pH condition of 3.5-5.5. It is preferable to return the sludge subjected to solid-liquid separation to a reaction process. At this time, it is preferable that the calcium compound to be added to raw water is preliminarily mixed with the return sludge and the modified sludge is added to the raw water.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:通过使用氟化钙方法通过铝共存稳定有效地处理含氟废水来获得充分除去氟的处理水。 解决方案:将铝化合物与铝共存加入到含氟废水中,同时进一步添加磷酸离子,使得P / Al(摩尔比)为1以上,进一步添加3价铁离子,使Fe / 在3.5-5.5的pH条件下,P(摩尔比)为1以上,使不溶物进行固液分离。 优选将进行固液分离的污泥返回到反应过程。 此时,优选将添加到原水中的钙化合物与返回污泥预先混合,并将改性污泥加入原水中。 版权所有(C)2007,JPO&INPIT
    • 4. 发明专利
    • Starting-up method of water treatment apparatus
    • 水处理设备启动方法
    • JP2006272121A
    • 2006-10-12
    • JP2005094002
    • 2005-03-29
    • Kurita Water Ind Ltd栗田工業株式会社
    • SEKIMOTO TOMOHIROSHIBATA KATSUMIHAYASHI KAZUKI
    • C02F1/58
    • PROBLEM TO BE SOLVED: To quickly start up a water treatment apparatus in which raw water containing inorganic contaminant ions is reacted with an insolubilizing agent insolubilizing the inorganic contaminant ions to form insoluble matter, and to obtain sludge containing the insoluble matter and separated water by solid/liquid separation of the insoluble matter.
      SOLUTION: In this starting-up method of the water treatment apparatus, prior to supply of the raw water to a reactor, the water treatment apparatus is filled with water, a compound containing inorganic contaminant ion sources is added to the reactor, and the insolubilizing agent is added to a mixing tank and water in the water treatment apparatus is circulated by operating a sludge returning means, and when the insoluble matter in a solid/liquid separating tank has reached a given amount, the addition of the compound is stopped, and supply of the raw water to the reactor is started.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:为了快速启动一种水处理设备,其中含有无机污染物离子的原水与不溶解剂不溶解无机污染物离子形成不溶物质,并获得含有不溶物质的污泥并分离 水通过固/液分离不溶物。 解决方案:在水处理装置的这种启动方法中,在将原水供应到反应器之前,水处理装置充满水,将含有无机污染物离子源的化合物加入到反应器中, 并且将不溶解剂加入到混合槽中,通过操作污泥返回装置使水处理装置中的水循环,并且当固/液分离罐中的不溶物达到给定量时,化合物的添加为 停止,并开始向反应器供应原水。 版权所有(C)2007,JPO&INPIT