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1. 发明专利

JPS5721369A N-acyl-n-methyl-4- 3-pyridyl -3-butene-1-amine and its preparation 失效
标题翻译： N-乙酰基-N-甲基-4-三氟甲基-3-丁烯-1-胺及其制备方法
公开(公告)号：JPS5721369A
公开(公告)日：1982-02-04
申请号：JP9445380
申请日：1980-07-10
申请人： Japan Tobacco Inc , Yuki Gosei Yakuhin Kogyo Kk
发明人： KISAKI TAKUROU , SUNAKAWA KENJI , SHIGEMATSU HITOSHI , SHINKAI TAKAYA , NAOI YOSHITAKA , KAKIZAWA TAKAO , KIGAMI AKIHIRO , NAKANO MITSUO , NAKAO TSUTOMU
IPC分类号： A24B3/12 , A24B15/38 , C07D213/38 , C07D213/40
摘要： NEW MATERIAL:An N-acyl-N-methyl-4-(3-pyridyl)-3-butene-1-amine expressed by the formula (R is propionyl, butyryl, valeryl, cinnamoyl, isobutyryl, isovaleryl, octanoyl, palmitoyl or cyclohexylcarbonyl).
EXAMPLE: N-Propionyl-N-methyl-4-(3-pyridyl)-3-butene-1-amine.
USE: A flavor and taste improver for tobacco.
PROCESS: N-Methyl-4-(3-pyridyl)-3-butene-1-amine is reacted with an acyl halogenide expressed by the formula RX (X is halogen) in the presence of an alkali hydroxide to give the compound expressed by the formula. The raw material compound is readily obtained by reacting nicotine or nicotine sulfate with benzoyl chloride, and hydrolyzing the resultant N-benzoylmetanicotine with hydrochloric acid, etc.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：新材料：由式（R是丙酰基，丁酰基，戊酰基，肉桂酰基，异丁酰基，异戊酰基，辛酰基，棕榈酰基或异戊酰基）表示的N-酰基-N-甲基-4-（3-吡啶基）-3-丁烯-1-胺环己基羰基）。实施例：N-丙酰基-N-甲基-4-（3-吡啶基）-3-丁烯-1-胺。用途：用于烟草的风味和味道改良剂。方法：将N-甲基-4-（3-吡啶基）-3-丁烯-1-胺与碱式氢氧化物存在下由式RX（X为卤素）表示的酰基卤化物反应，得到由公式。原料化合物易于通过使尼古丁或硫酸烟碱与苯甲酰氯反应，并用盐酸等水解所得的N-苯甲酰基甲脒。

2. 发明专利

JPS5721370A N-acyl-n-methyl-4- 3-pyridyl -butylamine and its preparation 失效
标题翻译： N-乙酰-N-甲基-4-三吡啶基 - 丁基胺及其制备方法
公开(公告)号：JPS5721370A
公开(公告)日：1982-02-04
申请号：JP9445480
申请日：1980-07-10
申请人： Japan Tobacco Inc , Yuki Gosei Yakuhin Kogyo Kk
发明人： KISAKI TAKUROU , SUNAKAWA KENJI , SHIGEMATSU HITOSHI , SHINKAI TAKAYA , NAOI YOSHITAKA , KAKIZAWA TAKAO , KIGAMI AKIHIRO , NAKANO MITSUO , NAKAO TSUTOMU
IPC分类号： A24B3/12 , A24B15/38 , C07D213/38 , C07D213/40
摘要： NEW MATERIAL:An N-acyl-N-methyl-4-(3-pyridyl)-butylamine expressed by formula I (R is propionyl, butyryl, valeryl, cinnamoyl or benzoyl).
EXAMPLE: N-Propionyldihydrometanicotine.
USE: A flavor and taste improver for tabacco.
PROCESS: An N-methyl-4-(3-pyridyl)-3-butene-1-amine is reacted with an acyl halogenide expressed by the formula RX (X is halogen) in the presence of an alkali hydroxide, e.g. NaOH, at 0W40°C for 1W3hr to give an N-acyl-N-methyl-4-(3- pyridyl)-3-butene-1-amine expressed by formula II, which is then catalytically hydrogenated with hydrogen at low, medium or high pressure in a solvent in the presence of a transition metallic catalyst at ordinary temperature to afford the compound expressed by formula I.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：新材料：由式I表示的N-酰基-N-甲基-4-（3-吡啶基） - 丁胺（R是丙酰基，丁酰基，戊酰基，肉桂酰基或苯甲酰基）。实施例：N-丙酰基二氢氨基烟碱。用途：味觉和口味改良剂，用于烟草。方法：将N-甲基-4-（3-吡啶基）-3-丁烯-1-胺与式RX（X为卤素）表示的酰基卤化物在碱金属氢氧化物的存在下反应。 NaOH，在0-40℃下反应1-3小时，得到由式II表示的N-酰基-N-甲基-4-（3-吡啶基）-3-丁烯-1-胺，然后用式在常温下在过渡金属催化剂存在下，在溶剂中在低，中或高压下进行氢气处理，得到由式I表示的化合物。

3. 发明专利

JPS5696677A ISOLATION AND PURIFICATION OF PHYLLODULCIN 失效
公开(公告)号：JPS5696677A
公开(公告)日：1981-08-04
申请号：JP17046179
申请日：1979-12-28
申请人： YUKI GOSEI YAKUHIN KOGYO KK
发明人： NAKANO MITSUO , HIRAI TAKAMASA , YOKOZAWA KUNIO , OZAKI EIICHI , KAKIZAWA TAKAO
IPC分类号： A23L27/00 , C07D311/76 , C07H1/08
摘要： PURPOSE:To isolate and purify phyllodulcin, by converting hydrangenol into its alkai salt with a (water-containing) lower alcohol extracted solution of leaves of hydrangea in a pH not less than 8, extracting a colored component, etc. with a weakly polar organic solvent in a pH not less than 11, removing it, followed by extracting phyllodulcin with a wealky polar organic solvent in a pH not more than 10. CONSTITUTION:In extracting and purifying phyllodulcin useful as a sweetener, perfume for tabacco, etc. from leaves of hydrangea, first the leaves of hydrangea is extracted with a lower alcohol, e.g., methanol, etc. or a water-containing lower alcohol to give an extracted solution, which is adjusted to a pH not less than 8 with an alkali aqueous solution and stirred at from normal temperature to about 50 deg.C for 30min to 6hr so that hydrangenol is converted into its alkali salt. The prepared solution is adjusted to a pH not less than 11 and extracted with a weakly polar organic solvent, e.g., chloroform, so that colored components and impurities are removed by the extraction. The prepared water-alcohol solution is adjusted to a pH not more than 10 and extracted with an organic solvent, e.g., chloroform, to give high-purity phyllodulcin in high yield. This substance is recrystallized from a lower alcohol to give an almost purified product.

4. 发明专利

JPS53137941A IMPROVED METHOD FOR PRODUCTION OF 77HYDROXYINDANONE 失效
公开(公告)号：JPS53137941A
公开(公告)日：1978-12-01
申请号：JP5205777
申请日：1977-05-09
申请人： YUKI GOSEI YAKUHIN KOGYO KK
发明人： AZUMA SHIGERU , HIGUCHI SHIGEKI , NAOI YOSHITAKA , ITOU HIDEKI , NAKANO MITSUO , SAKAI KOUJI , FUJII KIYOMI
IPC分类号： C07C49/747 , B01J21/00 , B01J21/02 , C07B61/00 , C07C45/00 , C07C67/00

5. 发明专利

JPS5356657A PREPARATION METHOD OF 55BENZYLL22CARBOXYY33FURFURYL ALCOHOL 失效
公开(公告)号：JPS5356657A
公开(公告)日：1978-05-23
申请号：JP13121476
申请日：1976-11-02
申请人： YUKI GOSEI YAKUHIN KOGYO KK
发明人： NAKANO MITSUO , NAOI YOSHITAKA , SAKAI KOUJI , FUJII KIYOMI
IPC分类号： C07D307/44 , C07D307/68

6. 发明专利

JPS5217474A PROCESS FOR PREPARATION OF 44CARBOXYY3* 44DIHYDROISOCOUMARIN 失效
公开(公告)号：JPS5217474A
公开(公告)日：1977-02-09
申请号：JP6097076
申请日：1976-05-26
申请人： YUKI GOSEI YAKUHIN KOGYO KK
发明人： HIGUCHI SHIGEKI , SAKAI KOUSHI , AZUMA SHIGERU , MATSUI TAKAAKI , NISHI AKIRA , SANO SEIICHI , NAKANO MITSUO , TAKAHASHI YOSHINORI , ITOU HIDEKI , NAOI YOSHITAKA
IPC分类号： C07D311/76
摘要： PURPOSE:The title compound, useful as intermediate of dihydroisocoumarin using as sweetening agents, antiseptics, fluorescent agents, laxatives. etc., is prepared by the cyclization of a particular compound.

7. 发明专利

JPS53124234A PROCESS FOR PREPARING 33HYDROXYHOMOPHTHALATE 失效
公开(公告)号：JPS53124234A
公开(公告)日：1978-10-30
申请号：JP3835377
申请日：1977-04-04
申请人： YUKI GOSEI YAKUHIN KOGYO KK
发明人： MIYOSHI MASAMITSU , HONDA SHIYUNICHI , YOKOZAWA KUNIO , NAKAO TSUTOMU , NAKANO MITSUO , NAOI YOSHITAKA , HIGUCHI SHIGEKI , SAKAI KOUJI , FUJII KIYOMI
IPC分类号： C07C65/03 , C07C51/00 , C07C67/00

8. 发明专利

JPS5356655A 55BENZYLL22CARBOXYY33FURFURYL ALCOHOL AND PREPARATION METHOD 失效
公开(公告)号：JPS5356655A
公开(公告)日：1978-05-23
申请号：JP13121276
申请日：1976-11-02
申请人： YUKI GOSEI YAKUHIN KOGYO KK
发明人： NAOI YOSHITAKA , NAKANO MITSUO , SAKAI KOUJI , FUJII KIYOMI
IPC分类号： C07D307/68

9. 发明专利

JPS57141283A IMPROVEMENT OF TOBACCO AROMA AND TASTE 失效
公开(公告)号：JPS57141283A
公开(公告)日：1982-09-01
申请号：JP2598781
申请日：1981-02-24
申请人： JAPAN TOBACCO & SALT PUBLIC , FUJI FLAVOR CO , YUKI GOSEI YAKUHIN KOGYO KK
发明人： TAKAHARA HIROYASU , TANAKA SUMIO , FUKUZUMI TETSUO , MORISHITA ISAO , NAKANO MITSUO , HIRAI TAKAMASA , KAKIZAWA TAKAO
IPC分类号： A24B3/12

10. 发明专利

JPS5356656A PREPARATION METHOD OF 55BENZYLL33FURFURYL ALCOHOL 失效
公开(公告)号：JPS5356656A
公开(公告)日：1978-05-23
申请号：JP13121376
申请日：1976-11-02
申请人： YUKI GOSEI YAKUHIN KOGYO KK
发明人： NAOI YOSHITAKA , NAKANO MITSUO , SAKAI KOUJI , FUJII KIYOMI
IPC分类号： C07D307/42 , C07D307/44

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