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    • 3. 发明专利
    • Production method of adamantane derivative
    • 衍生物衍生物的生产方法
    • JP2013014552A
    • 2013-01-24
    • JP2011149647
    • 2011-07-06
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • ITO KATSUKIKOJIMA AKIOONO HIDETOSHIKONO NAOYA
    • C07D303/27
    • PROBLEM TO BE SOLVED: To provide a production method with a high yield of an adamantane derivative, which is a stable compound having high symmetry property and is useful as a raw material of pharmaceutical products, a raw material of high-functional industrial materials, or the like.SOLUTION: A production method of a glycidyloxy group-containing adamantane derivative represented by formula is provided by which the adamantane derivative is produced by allowing a compound such as 4,6-bis(1-adamantyl)-1,3-dihydroxybenzene to react with epichlorohydrin in a molar amount 8 to 20 times as the above compound in a solvent having a relative dielectric constant of 14 to 37 represented by secondary alcohol.
    • 待解决的问题:为了提供高对称性的稳定化合物金刚烷衍生物的高产率的制造方法,可用作药物原料,高功能工业用原料 材料等。 解决方案:提供由式表示的含缩水甘油氧基的金刚烷衍生物的制备方法,通过其制备金刚烷衍生物,通过使化合物如4,6-双(1-金刚烷基)-1,3-二羟基苯 在上述化合物的摩尔量为8〜20倍的表氯醇与由仲醇表示的相对介电常数为14〜37的溶剂中反应。 版权所有(C)2013,JPO&INPIT
    • 5. 发明专利
    • Photosensitive composition containing adamantane derivative
    • 含有ADAMANTANE衍生物的光敏组合物
    • JP2011102921A
    • 2011-05-26
    • JP2009258252
    • 2009-11-11
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • ITO KATSUKIONO HIDETOSHI
    • G03F7/027C07C69/02C07C69/608C07C69/612G02B5/20G03F7/004G03F7/075H01L21/027
    • PROBLEM TO BE SOLVED: To provide a photosensitive composition and a photosensitive laminate, containing an adamantane derivative, providing a cured object which excels in developability and adhesiveness.
      SOLUTION: The composition contains the adamantine derivative (A), obtained by reaction of formula (II) which is a material and a polycarboxylic acid and/or a polycarboxylic acid anhydride, a polymerization initiator (B), a diluent (C), a colorant (D) and a binder resin (E), where in the formula (II), R
      1 represents a carbon hydride having 1 to 20 carbon atoms; R
      2 and R
      3 respectively represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms or a methyl halide; R
      4 represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a hydroxyl group or a methyl halide; j is an integer of 1 to 4; k is an integer of 1 to 4; and m is an integer of 2 to 9. s is an integer of 0 to 10; and r is 1 or 0. When j, k, m or s is 2 or greater, a plurality of groups may be identical or different. An asterisk indicates a binding position.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供含有金刚烷衍生物的感光性组合物和光敏层叠体,提供显影性和粘合性优异的固化物。 解决方案:该组合物含有金属衍生物(A),其通过反应式(II),其为材料和多元羧酸和/或多元羧酸酐,聚合引发剂(B),稀释剂(C ),着色剂(D)和粘合剂树脂(E),其中在式(II)中,R“1”表示碳原子数1〜20的碳氢化合物, 分别表示氢原子,卤素原子,碳原子数1〜10的烃基或甲基卤化物; R 2,R 3, R 4表示氢原子,卤素原子,碳原子数1〜10的烃基,羟基或甲基卤化物; j为1〜4的整数, k为1〜4的整数, m为2〜9的整数。s为0〜10的整数。 并且r为1或0.当j,k,m或s为2以上时,多个组可以相同或不同。 星号表示绑定位置。 版权所有(C)2011,JPO&INPIT
    • 10. 发明专利
    • Method for isolating and refining adamantane derivative formed and method for recovering raw material
    • 用于分离和精制ADAMANTANE衍生物的方法和用于回收原料的方法
    • JP2005089363A
    • 2005-04-07
    • JP2003324211
    • 2003-09-17
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • ONO HIDETOSHITANAKA SHINJIKODOI KOICHIHATAKEYAMA NAOYOSHI
    • C07C67/58C07C29/86C07C35/52C07C69/54
    • PROBLEM TO BE SOLVED: To provide a method for versatilely and industrially separating a raw material and the objective product from a reaction mixture formed by the reaction of producing the objective adamantane derivative by converting at least one acidic hydroxy group using a compound having an adamantyl group and one or more such acidic hydroxy groups as the raw material.
      SOLUTION: In the reaction producing the objective adamantane derivative by converting at least one acidic hydroxy group using the compound having an adamantyl group and one or more such acidic hydroxy groups as the raw material, the method for isolating and refining the adamantane derivative formed is provided, comprising dissolving the reaction mixture comprising the adamantane derivative formed and the raw material in an organic solvent not substantially fully miscible with water and extracting the raw material with an alkaline aqueous solution.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:提供一种通过将工业上原料和目标产物与通过使用具有至少一个酸性羟基的化合物形成的反应混合物形成的反应混合物的方法,该化合物具有 金刚烷基和一个或多个这样的酸性羟基作为原料。 解决方案:在使用具有金刚烷基和一个或多个这样的酸性羟基作为原料的化合物转化至少一种酸性羟基的反应生成目标金刚烷衍生物中,分离和精制金刚烷衍生物的方法 包括将包含形成的金刚烷衍生物和原料的反应混合物溶解在与水完全不混溶的有机溶剂中并用碱性水溶液萃取原料。 版权所有(C)2005,JPO&NCIPI