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    • 1. 发明专利
    • 有機エレクトロルミネッセンス素子および電子機器
    • 有机电致发光元件和电子设备
    • JP2015053476A
    • 2015-03-19
    • JP2014153196
    • 2014-07-28
    • 出光興産株式会社Idemitsu Kosan Co Ltd
    • OGIWARA TOSHINARI
    • H01L51/50C09K11/06
    • 【課題】発光効率の低下を抑えつつ、駆動電圧を低下させることのできる有機エレクトロルミネッセンス素子を提供する。【解決手段】陽極3と、陰極4と、陽極および陰極の間に設けられている第一の有機層5と、陰極および第一の有機層の間に設けられ、第一の有機層と隣接している第二の有機層6と、を有し、第一の有機層は、第一の材料を含有し、第二の有機層は、熱活性遅延蛍光材料を12質量%以上の濃度で含有し、第一の材料のイオン化ポテンシャルIPBと熱活性遅延蛍光材料のイオン化ポテンシャルIPTとが、数式(数1)の関係を満たす有機エレクトロルミネッセンス素子1。IPB>IPT・・・(数1)【選択図】図1
    • 要解决的问题:提供能够降低驱动电压同时抑制发光效率降低的有机电致发光元件。解决方案:有机电致发光元件1包括:阳极3; 阴极4; 设置在阳极和阴极之间的第一有机层5; 以及设置在阴极和第一有机层之间并且与第一有机层相邻的第二有机层6。 第一有机层包含第一材料,第二有机层含有浓度为12质量%以上的热活化延迟荧光材料,第一材料的电离势IP和热活化延迟荧光体的电离势 材料满足数学表达式(公式1):IP> IP(公式1)
    • 3. 发明专利
    • Organic electroluminescent element
    • 有机电致发光元件
    • JP2012156499A
    • 2012-08-16
    • JP2011289822
    • 2011-12-28
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • OGIWARA TOSHINARINISHIMURA KAZUKI
    • H01L51/50
    • H01L51/5004H01L51/0072H01L51/0085H01L51/5016H01L2251/5384
    • PROBLEM TO BE SOLVED: To provide an organic electroluminescent element having high luminous efficiency.SOLUTION: The organic electroluminescent element has at least a hole transport layer and a luminous layer between a negative electrode and a positive electrode. The hole transport layer contains a hole transport material, the luminous layer is provided contiguously to the hole transport layer and contains a first host material, a second host material and a phosphorescent dopant material. The ionization potential IP(HT) of the hole transport material, the ionization potential IP(h1) of the first host material, and the ionization potential IP(h2) of the second host material satisfy the following relation of (formula 1). IP(h1)>IP(HT)>IP(h2) ... (formula 1).
    • 要解决的问题:提供具有高发光效率的有机电致发光元件。 解决方案:有机电致发光元件至少具有空穴传输层和在负极和正极之间的发光层。 空穴传输层包含空穴传输材料,发光层邻近空穴传输层提供,并且包含第一主体材料,第二主体材料和磷光掺杂剂材料。 空穴传输材料的电离电位IP(HT),第一主体材料的电离电位IP(h1)和第二主体材料的电离电位IP(h2)满足(式1)的关系。 IP(h1)> IP(HT)> IP(h2)...(公式1)。 版权所有(C)2012,JPO&INPIT
    • 4. 发明专利
    • Organic electroluminescent element
    • 有机电致发光元件
    • JP2013012505A
    • 2013-01-17
    • JP2009216051
    • 2009-09-17
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • OGIWARA TOSHINARIIWAKUMA TOSHIHIROITO MITSUNORI
    • H01L51/50C09K11/06
    • H01L51/0058C09K11/06C09K2211/1011H01L51/002H01L51/0059H01L51/0073H01L51/0085H01L51/5016H05B33/14
    • PROBLEM TO BE SOLVED: To provide a phosphorescent organic electroluminescent (EL) element having high efficiency and long life.SOLUTION: An organic electroluminescent element includes one or a plurality of organic thin film layers between a cathode and an anode, and the organic thin film layers contain an organic compound represented by the following formula (1) and a phosphorescent material. The triplet energy Eg(T) of the organic compound represented by the following formula (1) is larger than the triplet energy Eg(T) of the phosphorescent material. (In the formula, Arrepresents a condensed aromatic hydrocarbon ring selected from among a benzo phenanthrene ring, a dibenzo phenanthrene ring, a chrysene ring, a benzo chrysene ring, a dibenzo chrysene ring and the like, which may have a substituent, and the substituent is a halogen atom, an alkoxy group, an aryloxy group, a cyano group, an aryl silyl group, an alkyl silyl group, an alkyl(aryl)silyl group, a heterocyclic group or the like.)
    • 要解决的问题:提供高效率和长寿命的磷光有机电致发光(EL)元件。 解决方案:有机电致发光元件包括在阴极和阳极之间的一个或多个有机薄膜层,有机薄膜层含有由下式(1)表示的有机化合物和磷光材料。 由下式(1)表示的有机化合物的三重态能量Eg(T)大于磷光材料的三重态能量Eg(T)。 (式中,Ar 1 表示选自苯并菲环,二苯并菲环,环,苯并环,二苯并噻吩的稠合芳香烃环 环等,其可以具有取代基,取代基是卤素原子,烷氧基,芳氧基,氰基,芳基甲硅烷基,烷基甲硅烷基,烷基(芳基)甲硅烷基, 杂环基等)。版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • Organic el device
    • 有机EL设备
    • JP2010171363A
    • 2010-08-05
    • JP2009090379
    • 2009-04-02
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • OGIWARA TOSHINARINISHIMURA KAZUKIIWAKUMA TOSHIHIRO
    • H01L51/50C09K11/06
    • H01L51/5016H01L51/0057H01L51/0072H01L51/5088H01L2251/552
    • PROBLEM TO BE SOLVED: To provide an organic EL device which utilizes phosphorescent emission having a high luminous efficiency and has a prolonged lifetime under a driving condition at high temperatures. SOLUTION: The organic EL device includes an emitting layer, an electron-injecting controlling layer and an electron-transporting layer between an anode and a cathode in sequential order from the anode, bonding one to another, the emitting layer including a host material and a dopant, the ionization potential (Ips) of the main material forming the electron-injecting controlling layer and the ionization potential (Iph) of the host material of the emitting layer satisfying relationship (i) 0.5eV>Ips-Iph≥0 eV, and the electron mobility of the electron-transporting material forming the electron-transporting layer being 10 -5 cm 2 /Vs or more at the electric field intensity of 400 to 500 (V/cm) 1/2 . COPYRIGHT: (C)2010,JPO&INPIT
    • 解决的问题:提供一种利用具有高发光效率并且在高温下的驱动条件下具有延长寿命的磷光发射的有机EL器件。 解决方案:有机EL器件从阳极依次顺序地包括发光层,电子注入控制层和阳极和阴极之间的电子传输层,彼此粘合,发光层包括主体 材料和掺杂剂,形成电子注入控制层的主要材料的电离电位(Ips)和发光层的主体材料的电离电位(Iph)满足关系式(i)0.5eV> Ips-Iph≥0 eV,并且形成电子传输层的电子传输材料的电子迁移率在电场强度为400〜200nm时为10〜30ps / Vs / Vs以上 500(V / cm) 1/2 。 版权所有(C)2010,JPO&INPIT
    • 8. 发明专利
    • Organic electroluminescent element
    • 有机电致发光元件
    • JP2014075249A
    • 2014-04-24
    • JP2012221625
    • 2012-10-03
    • Idemitsu Kosan Co Ltd出光興産株式会社
    • OGIWARA TOSHINARIJINDE YUKITOSHI
    • H05B33/12H01L51/50
    • H01L51/504H01L51/0052H01L51/0054H01L51/0056H01L51/0058H01L51/006H01L51/0061H01L51/0067H01L51/0068H01L51/0072H01L51/0073H01L51/0085H01L51/5012H01L51/5016H01L51/5044H01L2251/5376H01L2251/5384H01L2251/552
    • PROBLEM TO BE SOLVED: To provide an organic EL element which efficiently emits light in a practical high current density region.SOLUTION: An organic electroluminescent element of the present invention includes an organic compound layer between a pair of electrodes. The organic compound layer has a plurality of light emitting layers including at least a first light emitting layer and a second light emitting layer. The first light emitting layer includes a first host material and a fluorescent first light emitting material, and the second light emitting layer includes a second light emitting material that is different from the first light emitting material. The difference ΔST (H1) between the singlet energy EgS (H1) of the first host material and the energy gap Eg(H1) at 77 [K] of the first host material satisfies a specific relation. The main peak wavelength of the light emission of one of the first light emitting material and the second light emitting material is 400 nm or more and less than 500 nm, and the main peak wavelength of the light emission of the other is 500 nm or more and 700 nm or less.
    • 要解决的问题:提供一种在实际的高电流密度区域中有效发光的有机EL元件。解决方案:本发明的有机电致发光元件包括一对电极之间的有机化合物层。 有机化合物层具有包括至少第一发光层和第二发光层的多个发光层。 第一发光层包括第一主体材料和荧光第一发光材料,第二发光层包括不同于第一发光材料的第二发光材料。 第一主体材料的单线能量EgS(H1)与第一主体材料的77 [K]的能隙Eg(H1)之间的差Dgr(ST)(H1)满足特定关系。 第一发光材料和第二发光材料之一的发光的主峰波长为400nm以上且小于500nm,另一方的发光的主峰波长为500nm以上 700nm以下。