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    • 1. 发明专利
    • Analysis device
    • 分析装置
    • JP2009209833A
    • 2009-09-17
    • JP2008055028
    • 2008-03-05
    • Horiba LtdRitsumeikan学校法人立命館株式会社堀場製作所
    • IIDA SACHIHIROKO TOSHINORINAKANISHI YASUFUMIYOSHIHARA FUKUZENASANO ICHIROINOUE KO
    • F01N3/02B01D39/14B01D46/42B01D53/86B01D53/94F01N3/08F01N9/00
    • Y02T10/47
    • PROBLEM TO BE SOLVED: To provide a self-regenerating type gas purification device capable of efficient reproduction and using an electrochemical method.
      SOLUTION: The electrochemical-type gas purification device 100 using a purification member 1 composed of solid electrolyte is provided with an impedance measuring circuit 4 for measuring an impedance related value which is a value related to impedance in the width direction of the purification member 1, and a control circuit 5 which starts reproduction treatment of the purification member 1 by turning on a current impression circuit 3 when the impedance related value measured by the impedance measuring circuit 4 exceeds the upper limit set beforehand, and terminates the reproduction treatment of the purification member 1 by turning off the current impression circuit 3 when the measured impedance falls below the lower limit set beforehand.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供能够有效再现并使用电化学方法的自再生型气体净化装置。 解决方案:使用由固体电解质构成的净化部件1的电化学型气体净化装置100设置有阻抗测定电路4,该阻抗测定电路4测定与净化宽度方向的阻抗有关的阻抗相关值 以及控制电路5,当由阻抗测量电路4测量的阻抗相关值超过预先设定的上限时,通过打开电流压印电路3开始对净化部件1进行再生处理,并终止再生处理 净化部件1通过当测量的阻抗下降到预先设定的下限以下时关闭当前压印电路3。 版权所有(C)2009,JPO&INPIT
    • 2. 发明专利
    • GAS ANALYZER
    • JP2001159587A
    • 2001-06-12
    • JP34213999
    • 1999-12-01
    • HORIBA LTD
    • INOUE KOADACHI MASAYUKI
    • G01N1/00G01N1/22
    • PROBLEM TO BE SOLVED: To provide a gas analyzer capable of accurately providing in real time a component concentration before dilution by continuously monitoring a dilution ratio during actual measurement. SOLUTION: In this gas analyzer, a part of gas G flowing in a duct 2 continuous with a gas generating source 1 is sampled, this sampled gas S is diluted in a diluting device, and then it is analyzed at a gas analyzing part 5. In such a case, trace gas T of a constant flow rate is continuously introduced during the gas dilution, the trace gas T and the diluted gas are analyzed by the gas analyzing part 5, a component gas concentration and a concentration of the trace gas in the diluted gas are determined, and the component concentration in the gas S (G) before dilution is determined by using the component gas concentration, the trace gas concentration, and a flow rate value of the trace gas concentration.
    • 4. 发明专利
    • QUANTITATIVE ANALYSIS USING FTIR
    • JPH04268439A
    • 1992-09-24
    • JP5085091
    • 1991-02-23
    • HORIBA LTD
    • INOUE KOYAMAGISHI YUTAKAADACHI MASAYUKI
    • G01N21/3504G01N21/35
    • PURPOSE:To obtain a quantitative analysis using FTIR which allows highly accurate and highly reliable continuous analysis even for a measuring sample that could change sharply in the density of a component. CONSTITUTION:A group of wave number points for monitoring density is assigned together with a group of wave number points for calculating density beforehand corresponding to a density range of a component to be measured. In analysis, a proper density range is selected based on absorbance of the wave number points for monitoring density and the density of the component to be measured is calculated using the group of wave number points for monitoring density to be outputted. When it is judged based on the absorbance of the wave number points for monitoring density that no proper range exist for a measuring sample to be analyzed in one density range or among a plurality of density ranges which are prepared for components to be measured, a density output of the object to be measured is fixed at a certain vaue.
    • 6. 发明专利
    • QUANTITATIVE ANALYSIS METHOD FOR MULTIPLE COMPONENTS IN SPECTROCHEMICAL ANALYSIS
    • JPH04262240A
    • 1992-09-17
    • JP4444491
    • 1991-02-15
    • HORIBA LTD
    • YAMAGISHI YUTAKAADACHI MASAYUKIINOUE KO
    • G01N21/35G01N21/3504
    • PURPOSE:To perform highly accurate quantitative analysis in a short time by forming an assumed concentration operation matrix obtained by the combination of reference spectra in a plurality of components of known concentrations, and using the matrix. CONSTITUTION:A comparing sample or a sample to be measured is contained in a cell 12. Infrared rays are emitted from an infrared-ray source 7 on the cell 12, and the interferogram of the comparing sample or the sample to be measured is measured. In a data processing part 2, the interferograms are added and averaged. The added and averaged output undergoes Fourier transformationa at a high speed. The spectrum with respect to the component to be measured is operated based on the detected output of the Fourier transformation. A memory part 4 specifies the group of wave- number points of predicted arbitray gas out of a reference spectrum group 5 having the known concentrations. After the spectrum of the component is obtained, an assumed concentration operation matrix is stored by using a calibrating matrix. Therefore, it is not necessary to store the reference spectra of a plurality of components in, e.g. an analyzer. It is not necessary to form a concentration operation matrix within an apparatus. Therefore, the quantitative analysis can be performed highly accurately in a short time.
    • 7. 发明专利
    • CHEMILUMINESCENCE ANALYSER
    • JPH01277742A
    • 1989-11-08
    • JP10868188
    • 1988-04-30
    • HORIBA LTD
    • KADA MICHIOAOKI TAKESHIINOUE KO
    • G01N21/76
    • PURPOSE:To stably perform measurement with high sensitivity, by providing an apparatus for removing the impurity generated when ozone is generated between an ozone generator due to discharge and an analytical part into which ozone is introduced. CONSTITUTION:Moisture is removed from air K being a raw material in a dehumidifier 1 and the dried air K' is introduced into an ozone generator 5. Whereupon, a gas O' wherein a slight amount of impurity gas F is contained in ozone O is generated in the ozone generator 5 by silent discharge. When this gas O' is guided to one trap chamber 7B of a water trap 7 filled with water W, the impurity gas F larger in solubility than ozone O is almost dissolved in the water W to become HNO3 and, since ozone O is not almost dissolved in the water W, the gas reaches an ozone flow passage 12 without lowering the concon. of ozone and ozone O almost containing no impurity gas F is supplied to an NO analytical part 11.
    • 8. 发明专利
    • JPH05296924A
    • 1993-11-12
    • JP12574192
    • 1992-04-18
    • HORIBA LTD
    • INOUE KOADACHI MASAYUKIYAMAGISHI YUTAKA
    • G01J3/28G01N21/35
    • PURPOSE:To continuously analyze samples without receiving any influence from the drift of an absorption spectrum by preparing a base line spectrum on a computer by simplifying the drift of a base line and using the prepared spectrum as part of a reference spectrum at the time of generating a concentration calculating matrix. CONSTITUTION:A base line drift itself can be regarded as a kind of interference component which makes a whole spectrum to float or sink. In addition, since a base line itself makes no absorption and has no noise, a base line spectrum is prepared on a computer and used as part of a reference spectrum at the time of generating a concentration calculating matrix. Therefore, the influence of a drift can be eliminated from a concentration-calculated value. In addition, when the base line spectrum is applied to continuous analyses; a highly accurate determinated result can be obtained. When, for example, the base line has a possibility of making absorbancy floating or sinking by +0.05, five kinds of data files respectively having floating or sinking values of =0.10, +0.05, 0, -0.5, and -0.10 are prepared.
    • 9. 发明专利
    • QUANTITATIVE ANALYSIS METHOD USING FTIR
    • JPH04262239A
    • 1992-09-17
    • JP4416791
    • 1991-02-16
    • HORIBA LTD
    • INOUE KOYAMAGISHI YUTAKAADACHI MASAYUKI
    • G01N21/3504G01N21/35
    • PURPOSE:To analyze even a component to be measured having high concentration with the minimum detecting sensitivity being maintained at a constant level and to make it possible to perform continuous analysis even for a samples to be measured whose concentration change is large by automatically switching the groups of wave-number points used for the concentration computation of the component in response to the magnitude of the concentration of the component to be measured. CONSTITUTION:The group of wave-number points used for concentration computation corresponding to the concentration range based on the spectrum data obtained from a Fourier- transformation infrared spectrophotometer is used, and operation is performed. Whether the computed value can be outputted or not is compared with a threshold value. When the concentration range which is set by the computed value is judged as adequate, the computed value is outputted as the computed value of the concentration. When the range is not adequate, the concentration range is changed and set at the adequate value. The operation is performed again based on the absorbance of the group of the wave-number points for the corresponding concentration computation. These computation, judgment and change of range are all performed with computers automatically. Only the result of the concentration computation based on the group of the wave-number points for the most adequate concentration computation is always outputted in this way.