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1. 发明专利

JP2005150029A Proton conductor composition and proton conductor membrane 有权
标题翻译：原子导体组成和导体导体膜
公开(公告)号：JP2005150029A
公开(公告)日：2005-06-09
申请号：JP2003389478
申请日：2003-11-19
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： OTSUKI TOSHITAKA , KAWAI JUNJI , TSUNODA MAYUMI , GOTO KOHEI , KANEOKA NOBUYUKI , ASANO YOICHI , TAKAHASHI RYOICHIRO
IPC分类号： H01B1/06
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a proton conductor composition providing a proton conductor membrane having high proton conductivity without increasing the amount of introduced quantity of a sulfonic acid group, and also to provide a proton conductor membrane therefrom. SOLUTION: This proton conductor composition comprises 100 pts.wt. of poly arylene with the sulfonic acid group, and 0.01-60 pts.wt. of a hygroscopic inorganic porous compound. The hygroscopic inorganic porous compound is at least one kind of compounds selected from a group comprising particles of silica, synthetic zeolite, titania gel, alumina gel, zirconia gel, and yttria gel and a fibrous silica fiber. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种提供具有高质子传导性的质子导体膜的质子导体组合物，而不增加引入量的磺酸基团的量，并且还提供质子导体膜。解决方案：该质子导体组合物包含100重量份的聚亚芳基与磺酸基，和0.01-60重量份。的吸湿性无机多孔化合物。吸湿性无机多孔化合物是选自由二氧化硅颗粒，合成沸石，二氧化钛凝胶，氧化铝凝胶，氧化锆凝胶和氧化钇凝胶以及纤维状二氧化硅纤维组成的组中的至少一种化合物。版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2005050726A Method of manufacturing paste for electrodes and paste composite for electrodes 有权
标题翻译：电极用电极和电极复合材料的制造方法
公开(公告)号：JP2005050726A
公开(公告)日：2005-02-24
申请号：JP2003282712
申请日：2003-07-30
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： KAWAI JUNJI , HIGAMI MAKOTO , GOTO KOHEI , TAKAHASHI RYOICHIRO , ASANO YOICHI
IPC分类号： H01M4/86 , H01M4/88 , H01M4/92 , H01M8/10
CPC分类号： H01M4/8828 , H01M4/8605 , H01M4/8652 , H01M4/8663 , H01M4/8673 , H01M4/926
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing paste for electrodes and a paste composite for electrodes which are superior in storing stability and on which a catalyst layer provided with a pore volume sufficient for obtaining a good power generating function can be formed. SOLUTION: The paste for the electrode, in which particles provided with a specified average particle diameter is uniformly dispersed is obtained by agitating and mixing carbon black, by which catalyst metal is carried, polyelectrolyte, organic solvent and at least one component from carbon fiber and water with each of the component according to need. Thus the carbon black is made into minute particles. The agitation is continued until the average particle diameter of the dispersed particles in the mixed solvent becomes a specified value. Next, by adding dispersant to the mixed solvent and agitating and mixing it, the paste for electrodes is obtained, in which the particle provided with the specified average particle diameter is uniformly dispersed. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决的问题：提供一种电极用糊料的制造方法和电极用糊剂复合体，其存储稳定性优异，并且具有足以获得良好发电功能的孔体积的催化剂层可以是形成。解决方案：通过搅拌和混合载有催化剂金属的炭黑，聚电解质，有机溶剂和至少一种组分从而得到具有特定平均粒径的颗粒均匀分散的电极用糊料碳纤维和水，根据需要每个组分。因此，炭黑被制成微小的颗粒。继续搅拌，直到混合溶剂中分散颗粒的平均粒径成为规定值。接下来，通过向混合溶剂中加入分散剂并搅拌混合，得到具有特定平均粒径的粒子均匀分散的电极用糊料。版权所有（C）2005，JPO＆NCIPI

3. 发明专利

JP2005246800A Proton conductive composite film and its production method 审中-公开
标题翻译：原子导电复合膜及其生产方法
公开(公告)号：JP2005246800A
公开(公告)日：2005-09-15
申请号：JP2004061049
申请日：2004-03-04
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： ONOE KOICHI , OTSUKI TOSHITAKA , MASAKA FUSAZUMI , NAITO YUJI , IGUCHI MASARU , KANEOKA NOBUYUKI , ASANO YOICHI , MITSUDA NAOKI , SOMA HIROSHI
IPC分类号： C08J5/22 , B32B27/00 , C08G61/12 , C08L65/00 , H01B1/06 , H01B13/00 , H01M6/22 , H01M8/02
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a proton conductive composite film of a polyarylene having sulfonic acid groups which can improve the strength, toughness and hot water resistance without spoiling proton conductivity, and a method for producing the film.
SOLUTION: In the proton conductive composite film, at least two proton conductive films of the polyarylene having sulfonic acid groups are laminated. At least two proton conductive layers are made of the polyarylene having sulfonic acid groups having different ion exchange capacities. In the method for producing the proton conductive composite film, in the production of the proton conductive film described in Claim 1 by laminating the proton conductive film of the polyarylene having at least two sulfonic acid groups, the proton conductive film is made to adhere by using a solution prepared by dissolving the polyarylene having the sulfonic acid groups in an alcoholic solvent or an aprotic solvent.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供具有磺酸基的聚亚芳基的质子传导性复合膜，其可以提高强度，韧性和耐热水性而不破坏质子传导性，以及制备该膜的方法。解决方案：在质子传导性复合膜中，层叠具有磺酸基的聚亚芳基的至少两个质子传导膜。至少两个质子传导层由具有不同离子交换容量的磺酸基的聚亚芳基制成。在质子传导性复合膜的制造方法中，在权利要求1所述的质子传导膜的制造中，通过层叠具有至少两个磺酸基的聚亚芳基的质子传导膜，使质子传导膜通过使用通过将具有磺酸基的聚亚芳基溶解在醇溶剂或非质子溶剂中制备的溶液。版权所有（C）2005，JPO＆NCIPI

4. 发明专利

JP2003317749A Varnish composition, manufacturing method of film- electrode conjugate 有权
标题翻译：电极组合物，电极连接的制造方法
公开(公告)号：JP2003317749A
公开(公告)日：2003-11-07
申请号：JP2002122822
申请日：2002-04-24
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： HIGAMI MAKOTO , GOTO KOHEI , KANEOKA NOBUYUKI , TAKAHASHI RYOICHIRO , ASANO YOICHI , SUMIYA OSAMU , OKIYAMA GEN
IPC分类号： H01M8/02 , H01M8/10
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide an electrolyte varnish composition capable of being applied on an electrode without shedding and allowing an obtained electrode/electrolyte structure to maintain the high power generating characteristic. SOLUTION: The varnish composition is produced by dissolving sulfonated polymer into solvent containing organic solvent A, organic solvent B, and water. The organic solvent A is a good solvent of the sulfonated polymer, and its boiling point is higher than that of the other solvent component. The organic solvent B has a boiling point of 50°C or higher, and does not become a good solvent of the sulfonated polymer by itself, but produces a dissolving region of the sulfonated polymer by being mixed with the organic solvent A and/or water. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供能够在不脱落的情况下施加在电极上并使得所得电极/电解质结构保持高发电特性的电解液清漆组合物。解决方案：通过将磺化聚合物溶解在含有机溶剂A，有机溶剂B和水的溶剂中来制备清漆组合物。有机溶剂A是磺化聚合物的良溶剂，其沸点高于其它溶剂组分的沸点。有机溶剂B的沸点为50℃以上，本身不会成为磺化聚合物的良溶剂，而是通过与有机溶剂A和/或水混合而产生磺化聚合物的溶解区域。版权所有（C）2004，JPO

5. 发明专利

JP2005213325A Polyarylene polymer composition and its use 有权
标题翻译：聚异戊烯聚合物组合物及其用途
公开(公告)号：JP2005213325A
公开(公告)日：2005-08-11
申请号：JP2004020139
申请日：2004-01-28
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： KADOTA TOSHIAKI , OTSUKI TOSHITAKA , OKADA TAKASHI , YAMAKAWA YOSHITAKA , KANEOKA NOBUYUKI , ASANO YOICHI , IGUCHI MASARU , MITSUDA NAOKI , SOMA HIROSHI
IPC分类号： C08J5/22 , C08K5/00 , C08L65/00 , H01B1/06 , H01M8/02
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a polymer electrolyte composition which has high oxidation resistance, proton conductivity, strength, and elasticity, and can easily be processed into a thin film. SOLUTION: The polyarylene polymer composition is characterized by comprising a sulfonic group-having polyarylene obtained by hydrolyzing a sulfonate group-having polyarylene obtained by polymerizing a monomer represented by the general formula (A) [X is a halogen atom excluding fluorine atom, OSO 3 CH 3 or OSO 3 CF 3 ; A is a divalent electron-attracting group; B is a divalent electron-donating group or a direct bond; (m) is 0 to 10; (n) is 0 to 10; (k) is 1 to 4; Ar is an aromatic group having SO 3 R b ; R a and R b are each a 4 to 20C hydrocarbon group], and at least one additive selected from the group consisting of hindered phenolic compounds, hindered amine-based compounds, organic phosphrous compounds and organic sulfur compounds. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供具有高抗氧化性，质子传导性，强度和弹性的高分子电解质组合物，并且可以容易地加工成薄膜。聚亚芳基聚合物组合物的特征在于包含通过水解通过使由通式（A）表示的单体聚合而获得的具有磺酸酯基的聚亚芳基获得的磺酸基聚亚芳基[X是除氟原子以外的卤素原子，OSO <3> 3 或OSO 3 3 ; A是二价吸电子基团; B是二价给电子基团或直接键; （m）为0〜10; （n）为0〜10; （k）为1〜4; Ar是具有SO 3 S R b 的芳族基团。 R a 和R b 各自为4〜20C烃基]，并且至少一种选自受阻酚类化合物，受阻胺类化合物，有机磷化合物和有机硫化合物。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2005146189A Proton conductor composition and proton conducting membrane 有权
标题翻译：原子导体组成和原子导电膜
公开(公告)号：JP2005146189A
公开(公告)日：2005-06-09
申请号：JP2003388776
申请日：2003-11-19
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： KAWAI JUNJI , OTSUKI TOSHITAKA , KANEOKA NOBUYUKI , ASANO YOICHI , TAKAHASHI RYOICHIRO
IPC分类号： C08L71/10 , C08K3/00 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a proton conductor composition that gives a proton conducting membrane having a sufficiently high proton conductivity even in a high temperature range of not less than 100°C and to provide a proton conducting membrane formed from the composition. SOLUTION: The proton conductor composition comprises (a) at least one kind of compound selected from the group consisting of a metal oxide hydrate and a phyllosilicate and (b) a polyarylene having a sulfonic acid group wherein the component (a) is preferably contained in an amount of 0.5-80 pts.wt. based on 100 pts.wt. of the component (b). COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决的问题：为了提供即使在不低于100℃的高温范围内也能产生具有足够高质子传导性的质子传导膜的质子导体组合物，并且提供由组合物形成的质子传导膜。＆lt; P＆gt;解决方案：质子导体组合物包含（a）至少一种选自金属氧化物水合物和页硅酸盐的化合物和（b）具有磺酸基的聚亚芳基，其中组分（a）优选含有0.5-80重量份的量基于100重量的组分（b）。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2004075895A Proton-conductive resin composition, its preparation process and proton-conductive film 审中-公开
公开(公告)号：JP2004075895A
公开(公告)日：2004-03-11
申请号：JP2002239447
申请日：2002-08-20
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： GOTO KOHEI , TSUNODA MAYUMI , ASANO YOICHI , KANEOKA NOBUYUKI
IPC分类号： C08J5/22 , B01D69/14 , B01D71/52 , B01D71/66 , B01D71/68 , B01D71/70 , B01D71/82 , C08G65/48 , C08K3/36 , C08L71/00 , C08L71/08 , C08L81/06 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： B01D71/66 , B01D69/141 , B01D71/52 , B01D71/68 , B01D71/82 , C08G65/48 , C08G2650/02 , C08J5/2256 , C08J2365/00 , C08J2381/06 , C08K3/36 , C08L71/00 , C08L81/06 , H01M8/1004 , H01M8/1023 , H01M8/1051
摘要： PROBLEM TO BE SOLVED: To provide a proton-conductive resin composition which yields a proton-conductive film showing a high proton conductivity without increasing its acid concentration, its preparation process and the proton-conductive film formed from the composition.
SOLUTION: The composition comprises silica and a proton-conductive sulfonated polyarylene. In the process for preparing the composition, a powdery silica whose primary aggregate has an average particle size of ≤50nm is mixed with the sulfonated polyarylene.
COPYRIGHT: (C)2004,JPO

8. 发明专利

JP2005310643A Porous proton conducting film, its manufacturing method, and manufacturing method of film-electrode assembly 审中-公开
标题翻译：多孔导电膜，其制造方法和制造方法的电极组件
公开(公告)号：JP2005310643A
公开(公告)日：2005-11-04
申请号：JP2004128245
申请日：2004-04-23
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： KAWAI JUNJI , GOTO KOHEI , KANEOKA NOBUYUKI , ASANO YOICHI , TAKAHASHI RYOICHIRO , IGUCHI MASARU
IPC分类号： H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a porous proton conducting film capable of sufficiently retaining moisture in its ion conducting component, and excellent in mechanical characteristics and proton conductivity, its manufacturing method, and a film-electrode assembly. SOLUTION: This porous proton conducting film comprises an ion conducting component contained aromatic polymer, and its porosity is 1-60%. The ion conducting component contained aromatic polymer is dissolved in a cast solvent to prepare uniform coating liquid, the coating liquid is applied on a substrate, and a thin film containing 10-95 wt.% of the cast solvent is formed. After that, the thin film is brought into contact with and treated by a poor solvent compatible with the cast solvent. Thereby, this porous proton conducting film can be manufactured. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供能够充分保持其离子传导性成分中的水分，机械特性和质子传导性优异的多孔质子传导膜，其制造方法和膜 - 电极组件。解决方案：该多孔质子传导膜包含离子传导组分含有芳族聚合物，其孔隙率为1-60％。将含有芳族聚合物的离子导电组分溶解在浇铸溶剂中以制备均匀的涂布液，将涂布液涂布在基材上，形成含有10-95重量％铸塑溶剂的薄膜。之后，使薄膜与与浇铸溶剂相容的不良溶剂接触并进行处理。由此，可以制造该多孔质子传导膜。版权所有（C）2006，JPO＆NCIPI

9. 发明专利

JP2005222736A Polymeric electrolyte composite film, and manufacturing method thereof 审中-公开
标题翻译：聚合物电解质复合膜及其制造方法
公开(公告)号：JP2005222736A
公开(公告)日：2005-08-18
申请号：JP2004027089
申请日：2004-02-03
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： HIGAMI MAKOTO , OTSUKI TOSHITAKA , KANEOKA NOBUYUKI , ASANO YOICHI , TAKAHASHI RYOICHIRO
IPC分类号： C08G85/00 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a polymeric electrolyte composite film, having low electrical resistance and high mechanical strength, and to provide a method for manufacturing the polymeric electrolyte composite film. SOLUTION: The polymeric electrolyte composite film contains polyarylene having a sulfonic acid group, having a repetitive constitutional unit expressed by a general expression (A) and a repetitive constitutional unit expressed by a general expression (B) (i), and a fibrous substance, such as a sheet-like fibrous substance and short fibrous filler (ii). However, in the general expression (A), A, B, Ar, m, n, and k indicate a divalent electron-attracting group, a divalent electron donative group or direct coupling, an aromatic series group having -SO 3 H, an integer of 0-10, an integer of 0-10, and an integer of 1-4, respectively. And R 1 -R 8 in the general expression (B) are at least one type selected from a hydrogen atom, a fluorine atom, an alkyl group, a fluorine substitution alkyl group, an allyl group, an aryl group, and the like; W is a divalent electron-attracting group or single coupling; T is a single bond or a divalent organic group; and p is an integer of 2 or higher. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供具有低电阻和高机械强度的高分子电解质复合膜，并提供制造聚合物电解质复合膜的方法。解决方案：聚合物电解质复合膜包含具有磺酸基的聚亚芳基，具有由通式（A）表示的重复结构单元和由通式（B）（i）表示的重复结构单元，和纤维状物质，如片状纤维状物质和短纤维状填料（ii）。然而，在一般表达式（A）中，A，B，Ar，m，n和k表示二价吸电子基团，二价电子给体基团或直接键合，具有-SO 3 SB H，0〜10的整数，0〜10的整数，1-4的整数。通式（B）中的R SB 1〜SB 8是选自氢原子，氟原子，烷基，氟取代烷基中的至少一种基团，烯丙基，芳基等; W是二价吸电子基团或单键耦合; T是单键或二价有机基团; p为2以上的整数。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2005212213A Proton conductive composite film and its manufacturing method 审中-公开
标题翻译：原子导电复合膜及其制造方法
公开(公告)号：JP2005212213A
公开(公告)日：2005-08-11
申请号：JP2004020140
申请日：2004-01-28
申请人： Honda Motor Co Ltd , Jsr Corp , Jsr株式会社 , 本田技研工業株式会社
发明人： TAKASUGI SHINGO , OTSUKI TOSHITAKA , MASAKA FUSAZUMI , NAITO YUJI , GOTO KOHEI , KANEOKA NOBUYUKI , ASANO YOICHI , IGUCHI MASARU , MITSUDA NAOKI , SOMA HIROSHI
IPC分类号： B05D5/12 , B01J47/12 , B05D7/24 , B32B27/00 , B32B27/30 , C08G61/12 , C08G85/00 , C08J5/22 , H01B1/06 , H01B13/00 , H01M8/02
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a proton conductive composite film having excellent proton conductivity and excellent in dimensional stability and elastic modulus, and its manufacturing method.
SOLUTION: The polyarylene composite film is obtained by laminating a film comprising polyarylene having a sulfonic acid group, which has a repeating constituent unit represented by the general formula (A) (wherein A is a divalent electron-withdrawing group; B is a divalent electron-donating group or a direct bond; Ar is an aromatic group having a substituent represented by-SO
3 H; m is an integer of 0-10; n is an integer of 0-10; and k is an integer of 1-4), and a tetrafluoroethylene copolymer having proton conductivity.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供具有优异的质子传导性和优异的尺寸稳定性和弹性模量的质子传导复合膜及其制造方法。解决方案：聚亚芳基复合膜通过层压含有具有磺酸基的聚亚芳基的膜而获得，该膜具有由通式（A）表示的重复结构单元（其中A是二价吸电子基团; B是二价给电子基团或直接键合; Ar为具有-SO-S 3表示的取代基的芳香族基团; m为0〜10的整数，n为0〜10的整数 ; k为1-4的整数）和具有质子传导性的四氟乙烯共聚物。版权所有（C）2005，JPO＆NCIPI

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