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    • 1. 发明专利
    • Vapor phase crystal creation apparatus
    • 蒸气相晶体创造装置
    • JP2006089811A
    • 2006-04-06
    • JP2004277270
    • 2004-09-24
    • Hokkaido UnivJapan Steel Works Ltd:The国立大学法人 北海道大学株式会社日本製鋼所
    • SHIMADA SHIROMIYAKI TAKAAKIGOTO TOSHIMITSUONISHI KEIZO
    • C23C16/448C23C16/34C30B29/38H01L21/205
    • PROBLEM TO BE SOLVED: To use a gas produced by the reduction reaction of raw material oxide with a reducing material as the gaseous starting material of the crystals of GaN or the like.
      SOLUTION: A vapor phase crystal creation apparatus is equipped with: a reduction reaction part where a gaseous starting material is produced by the reaction of an oxide raw material with a reducing material; a crystal growth reaction part where the gaseous starting material produced in the above and another gaseous starting raw material are reacted to produce and grow crystals; and a sealed reaction vessel 1 provided with the reduction reaction part and the crystal growth reaction part inside. In the reduction reaction part and the crystal growth reaction part, atmospheric temperature is independently controllable by heaters 2a, 2b or the like, respectively. In this way, a desired amount of gaseous starting material can be inexpensively and stably feed. In the crystal growth reaction part, desired crystals are efficiently produced/grown. Further, by controlling the amount of the gaseous starting material to be fed, the crystals in the desired forms of a needle shape, a feather shape, a planar shape and a film shape can be obtained.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:使用原料氧化物的还原反应产生的气体与还原材料作为GaN等晶体的气态原料。 解决方案:气相晶体生成装置配备有还原反应部分,其中通过氧化物原料与还原材料的反应产生气态原料; 使上述制造的气态原料和另一种气态起始原料反应的结晶生长反应部分生成和生长晶体; 以及内部具有还原反应部和晶体生长反应部的密闭反应容器1。 在还原反应部分和晶体生长反应部分中,大气温度分别由加热器2a,2b等独立控制。 以这种方式,可以廉价和稳定地进料所需量的气态原料。 在晶体生长反应部分中,有效地生产/生长所需的晶体。 此外,通过控制待进料的气态原料的量,可以获得所需形状的针状,羽状,平面形状和膜形状的晶体。 版权所有(C)2006,JPO&NCIPI
    • 2. 发明专利
    • Recovery of hydrogen from low pressure mixed gas containing hydrogen
    • 从低压混合气体中回收氢气
    • JPS61122103A
    • 1986-06-10
    • JP23939684
    • 1984-11-15
    • Japan Steel Works Ltd:The
    • ONISHI KEIZOOGAWA TAKATOSHIITO HIDEAKI
    • B01D53/14C01B3/56
    • PURPOSE: To recover hydrogen gas under low pressure or medium pressure from a low-pressure mixed gas containing hydrogen, by introducing the low- pressure mixed gas into a container filled with a hydrogen-occlusion alloy, occluding the hydrogen as a metal hydride, releasing the remaining mixed gas from the container, and repeating the above processes.
      CONSTITUTION: A mixed gas containing hydrogen is introduced into a container filled with a hydrogen-occlusion alloy having an equilibrium hydrogen-occlusion pressure of about several atm, while keeping the alloy to a temperature (about 20°C) to lower the equilibrium pressure below the atmospheric pressure. The mixed gas having lowered hydrogen concentration in the container is purged to a pressure near the equilibrium hydrogen occlusion pressure of the alloy. A fresh mixed gas is introduced into the container, and the occlusion of hydrogen and the purge of the remaining mixed gas are repeated. The introduction of the fresh mixed gas and the discharge of the mixed gas having decreased hydrogen concentration can be carried out simultaneously and continuously, by opening the gas outlet for purging in the introduction of the mixed gas into the container.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过将低压混合气体引入填充有吸氢合金的容器中,在低压或中压下从低压混合气体中回收氢气,将氢气作为金属氢化物封闭,释放 剩余的来自容器的混合气体,并重复上述过程。 构成:将含有氢气的混合气体引入填充有约几个大气压的平衡吸氢压力的吸氢合金的容器中,同时保持合金温度(约20℃)以降低平衡压力 低于大气压力。 将容器中氢浓度降低的混合气体吹扫至接近合金的平衡氢气封闭压力的压力。 将新的混合气体引入容器中,并重复氢气的封闭和剩余混合气体的吹扫。 通过在将混合气体引入容器中打开用于净化的气体出口,可以同时且连续地进行新鲜混合气的引入和具有降低的氢浓度的混合气体的排出。
    • 3. 发明专利
    • Overlay stainless clad steel having superior exfoliation resistance
    • 超级不锈钢,具有优异的耐腐蚀性
    • JPS6137951A
    • 1986-02-22
    • JP15556684
    • 1984-07-27
    • Japan Steel Works Ltd:The
    • ONISHI KEIZONOMURA TORUMURAKAMI YOSHIKUNIISHIGURO TORU
    • C22C38/00B32B15/01C22C38/28
    • PURPOSE: To manufacture an overlay stainless clad steel having superior resistance to exfoliation due to hydrogen embrittlement by incorporating specified amounts of V and Ti and/or Nb into a base metal for an overlay stainless clad steel used in environment contg. hydrogen at high temp. and pressure.
      CONSTITUTION: 0.10W0.35% V and 0.015W0.040% Ti and/or Nb are incorporated into JIS.SCMV5 Cr-Mo steel as a base metal for an overlay stainless clad steel for a pressure vessel used in environment contg. hydrogen at high temp. and pressure for petrochemistry, oil refining or coal liquefaction. SUS347 stainless steel is welded to the resulting base metal to manufacture an overlay stainless clad steel. This clad steel does not cause an exfoliation phenomenon due to hydrogen embrittlement in environment contg. hydrogen at high temp. and pressure.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:制造覆盖不锈钢复合钢,通过在环境条件中使用的覆盖不锈钢复合钢的基础金属中加入规定量的V和Ti和/或Nb,因氢脆而具有优异的抗剥离性。 高温氢 和压力。 构成:将0.10-0.35%V和0.015-0.040%Ti和/或Nb掺入JIS.SCMV5Cr-Mo钢中,作为用于环境条件下使用的压力容器的覆盖不锈钢复合钢的贱金属。 高温氢 石油炼制或煤炭液化的压力。 将SUS347不锈钢焊接到所得的基底金属上以制造覆盖不锈钢复合钢。 该复合钢不会由于环境中的氢脆而引起剥离现象。 高温氢 和压力。
    • 4. 发明专利
    • Cooling system for car
    • 汽车冷却系统
    • JPS61113513A
    • 1986-05-31
    • JP23334884
    • 1984-11-07
    • Japan Steel Works Ltd:The
    • ONISHI KEIZOOGAWA TAKATOSHIITO HIDEAKI
    • F25B27/02B60H1/32F25B17/12
    • F25B17/12B60H1/3201
    • PURPOSE:To improve output and fuel consumption at the time of cooling by utilizing the waste heat of engine cooling water by connecting a pair of two types of heat exchangers filled with hydrogenated metals having a different hydrogen-gas balanced-pressure characteristics, to engine cooling water piping, an outside-car-room radiator, and an inside-car room-cooling unit. CONSTITUTION:When the hydrogen gas pressures of both of a first hydrogenated-metal heat exchanger 18 and a second hydrogenated-metal heat exchanger 20, attained a balanced condition, selector valves 32a, 32b, 40a, 40b, 44a, 44b, 50a, 50b are shifted, to feed water from an outside-car-room radiator 16 into the heat exchanger 18, causing the first hydrogenated metal to be cooled and absorb hydrogen to generate heat. And, since the second hydrogenated metal in the heat exchanger 20 discharges hydrogen and absorbs heat, cooling water is fed into an inside-car-room cooling unit 14, cooling the inside of a car by means of rotation of a fan 14a. Then, as said selector valves are shifted when the hydrogen gas pressure is balanced, an engine cooling water is fed to the heat exchanger 18 from a radiator 60, to equally carry out cooling with the pair of heat exchangers.
    • 目的:通过连接一对装有氢气平衡压力特性不同的氢化金属的两种热交换器,通过利用发动机冷却水的废热来提高冷却时的输出和燃料消耗,以发动机冷却 水管,室外散热器和室内冷气机组。 构成:当第一氢化金属热交换器18和第二氢化金属换热器20两者的氢气压力达到平衡状态时,选择阀32a,32b,40a,40b,44a,44b,50a,50b 移动,将水从外车厢散热器16供给到热交换器18中,使第一氢化金属冷却并吸收氢气产生热量。 并且,由于热交换器20中的第二氢化金属排出氢气并吸收热量,所以将冷却水供给到室内冷却单元14内,通过风扇14a的旋转来冷却汽车内部。 然后,当氢气压力平衡时,当所述选择阀被移动时,发动机冷却水从散热器60供给到热交换器18,以同样地用一对热交换器进行冷却。
    • 6. 发明专利
    • Recovery of gaseous hydrogen
    • 回收氢气
    • JPS6186401A
    • 1986-05-01
    • JP20641284
    • 1984-10-03
    • Japan Steel Works Ltd:The
    • ONISHI KEIZOOGAWA TAKATOSHIITO HIDEAKI
    • C03B3/00B01D53/14B01D53/34B01D53/46C01B3/00
    • Y02E60/327
    • PURPOSE: To recover gaseous hydrogen efficiently, to prevent danger of explosion, etc., and to facilitate storage, transportation, and reutilization by introducing gas contg. H
      2 into a vessel packed with hydrogen storage alloy.
      CONSTITUTION: A gaseous mixture from a generating source 10 is fed through a three way valve 12 and a valve 14 to one of a vessel 16 packed with a hydrogen storage alloy, and the hydrogen storage alloy in the vessel is held at a fixed temp. where the equilibrium pressure at the temp. is below the pressure of hydrogen to be recovered. In this stage, neither gaseous mixture nor cooling water are supplied to another vessel packed with hydrogen storage alloy. The gaseous H
      2 in the gaseous mixture is absorbed by the hydrogen storage alloy in the form of metal hydride. After a specified amt. of gaseous mixture is fed to the vessel, the valve 14 is closed, and the three-way valve 12 is changed over, and a valve 20 is opened to introduce the gaseous mixture into the other vessel 22 packed with hydrogen storage alloy. Further, the three-way valve 28 is changed over to a three-way valve 30, and cooling water is fed to the vessel 22. By these series of changing over operations, gaseous H
      2 can be recovered continuously. When the concn. of H
      2 reaches a specified value, the valve 18 is closed, and the vessel 16 is detached as it is combined with the valve 14 and 18 in one body, and a fresh vessel 16 is installed to replace the detached vessel.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:有效回收氢气,防止爆炸危险等,并通过引入气体来促进储存,运输和再利用。 H2置于装有储氢合金的容器中。 构成:来自发生源10的气体混合物通过三通阀12和阀14进料到装有储氢合金的容器16中的一个,容器中的储氢合金保持在固定温度。 其中平衡压力在温度 低于要回收的氢的压力。 在这个阶段,气体混合物和冷却水都不会供应到另外装有储氢合金的容器。 气态混合物中的气态H 2被金属氢化物形式的储氢合金吸收。 经过指定的amt。 的气体混合物被供给到容器中,阀14关闭,并且三通阀12被切换,阀20打开以将气体混合物引入到装有储氢合金的另一个容器22中。 此外,三通阀28切换到三通阀30,并且冷却水被供给到容器22.通过这些一系列的更换操作,可以连续地回收气态H 2。 当时 的H2达到指定值时,阀18关闭,并且容器16在与阀14和18组合在一个体中时被分离,并且安装新鲜容器16以更换分离的容器。
    • 7. 发明专利
    • Power generating method by means of metallic hydride
    • 通过金属液体的发电方法
    • JPS61108831A
    • 1986-05-27
    • JP22897184
    • 1984-11-01
    • Japan Steel Works Ltd:The
    • ONISHI KEIZOINOUE SAKIOOGAWA TAKATOSHI
    • F02C1/04F02C1/02
    • F02C1/02
    • PURPOSE:To enable small-scale power generation by means of small-size equipment by turning a gas turbine by using a hydrogen gas flow, which is obtained by utilizing hydrogen pressure difference that is produced by heating or cooling metallic hydride through switching a high temperature heat source and a low temperature heat source at a constant cycle. CONSTITUTION:When change-over valves 22, 24, 26, and 28 are set as shown in the figure, both a high temperature thermal medium from the high temperature heat source 18 and a low temperature thermal medium from a low temperature heat source 20 are supplied to heat exchangers 14 and 16 for metallic hydride, respectively. Accordingly, in the heat exchanger 14, the metallic hydride releases hydrogen gas, and the hydrogen gas pressure rises. On the other hand, in the heat exchanger 16, the metallic hydride absorbs hydrogen gas, and the hydrogen gas pressure lowers. If valves 34 and 44 are kept open while valves 36 and 42 are kept closed under this circumstance, hydrogen gas flow, which passes through pipes 30 and 40, is formed owing to the difference in hydrogen gas pressure. This hydrogen gas flow drives a gas turbine 12, and the electric power is generated by a power generator 10.
    • 目的:通过使用氢气流转动燃气轮机,通过小型设备实现小规模发电,这是通过利用通过切换高温加热或冷却金属氢化物而产生的氢压差而获得的 热源和低温热源。 构成:如图所示设置转换阀22,24,26,28时,来自高温热源18的高温热介质和来自低温热源20的低温热介质均为 分别供应到用于金属氢化物的热交换器14和16。 因此,在热交换器14中,金属氢化物释放氢气,氢气压力上升。 另一方面,在热交换器16中,金属氢化物吸收氢气,氢气压降低。 如果在这种情况下阀36和42保持关闭的情况下阀34和44保持打开,则由于氢气压力的差异而形成通过管道30和40的氢气流。 该氢气流驱动燃气轮机12,电力由发电机10产生。