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1. 发明专利

JP2005116519A Electrode for nonaqueous secondary battery and nonaqueous secondary battery 有权
标题翻译：非电源二次电池和非电池二次电池电极
公开(公告)号：JP2005116519A
公开(公告)日：2005-04-28
申请号：JP2004266149
申请日：2004-09-14
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： SUGIYAMA HIROSHI , ISHIZAWA KIYOMI , UEDA TOKUJI , AOYAMA SHIGEO
IPC分类号： C22C9/02 , C22C24/00 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/66 , H01M10/05 , H01M4/02 , H01M4/04 , H01M10/40
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide an electrode containing an intermetallic compound capable of storing and desorbing Li repeatedly and composing a nonaqueous secondary battery which has high charge/discharge efficiency, a large discharge capacity and superior properties of a load and a cycle.
SOLUTION: An alloy material containing an intermetallic compound of a metal alloying with Li and an element not alloying with Li, capable of repeatedly adsorbing and desorbing Li, is formed as a plurality of protrusions 2 mutually separated through gaps, on a current collector 1 made of a material not alloying with the Li. The area of the protrusions 2 occupying on the collector 1 is set to 60-95% of the area of the collector 1.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种含有能够重复地储存和解吸Li的金属间化合物的电极，并且构成具有高充电/放电效率的非水二次电池，具有大的放电容量和优异的负载和循环性能。解决方案：将具有与Li的金属合金化的金属间化合物和不能与Li反应吸附和解吸的元素的合金材料形成为通过间隙相互分离的多个突起2，以电流收集器1由不与李合金化的材料制成。占据收集器1的突起2的面积被设定为收集器1的面积的60-95％。版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2005050681A Electrode for lithium ion battery, its manufacturing method, and lithium ion battery 审中-公开
标题翻译：锂离子电池用电极，其制造方法和锂离子电池
公开(公告)号：JP2005050681A
公开(公告)日：2005-02-24
申请号：JP2003281515
申请日：2003-07-29
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： AOYAMA SHIGEO , UEDA TOKUJI , SUGIYAMA HIROSHI , KAWAI TETSUO
IPC分类号： H01M4/70 , H01M4/134 , H01M4/1395 , H01M10/05 , H01M4/02 , H01M10/40
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide an electrode for a lithium ion battery suppressing the volume expansion in the longitudinal direction of an active material during charge, preventing collapse of the active material or peeling off of it from a current collector, preventing a swelling deformation of the whole electrode caused by volume change of the active material, increasing energy density, and enhancing cycle characteristics, and to provide a lithium ion battery using the electrode as a negative electrode.
SOLUTION: The active material 2 is placed on the surface of a sheet-like current collector 1. The active material 2 is formed by disspersing a metal capable of alloying with Li or a lithium alloy in a dot shape. Regulating projections 4 ensuring the expansion spaces in the longitudinal direction of the active material 2 are installed on the sheet surface of the current collector 1. The regulating projections 4 are formed by interspersing a material not alloying with Li in a dot shape.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种锂离子电池用电极，其在充电时抑制活性物质的长度方向的体积膨胀，防止活性物质的塌陷或者使其从集电体剥离，由于活性物质的体积变化引起的整个电极的膨胀变形，增加了能量密度，提高了循环特性，并提供了使用该电极作为负极的锂离子电池。解决方案：将活性物质2放置在片状集电器1的表面上。活性物质2是通过使与Li或锂合金的点状合金化的金属分散而形成的。将确保活性物质2的长度方向的膨胀空间的调节突起4安装在集电体1的片材表面上。调节突起4通过将不与Li合金化的材料分散成点状而形成。版权所有（C）2005，JPO＆NCIPI

3. 发明专利

JP2005032632A Manufacturing method of non-aqueous secondary battery 审中-公开
标题翻译：非水性二次电池的制造方法
公开(公告)号：JP2005032632A
公开(公告)日：2005-02-03
申请号：JP2003272019
申请日：2003-07-08
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： KOJIMA AKIMICHI , UEDA TOKUJI , AOYAMA SHIGEO
IPC分类号： H01M10/05 , H01M4/38 , H01M4/485 , H01M4/62 , H01M10/052 , H01M10/058 , H01M10/40 , H01M4/02 , H01M4/58
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a non-aqueous secondary battery in which the deterioration of cycle characteristics is suppressed.
SOLUTION: The manufacturing method of the non-aqueous secondary battery which comprises a negative electrode containing an element capable of alloying with lithium and a positive electrode includes a process of a first charging. The first charging is carried out by a process of the initial stage charging, a middle stage charging, and a last stage charging in this order. In the above process, the negative electrode is pressurized in the thickness direction of the negative electrode, and the initial stage charging and the last stage charging are carried out with a current density of 1.0 mA/cm
2 or less.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决的问题：提供抑制循环特性劣化的非水二次电池。解决方案：包括含有能够与锂合金化的元素的负极和正极的非水二次电池的制造方法包括第一次充电的过程。通过初期充电，中间阶段充电和最后阶段充电的处理来进行第一次充电。在上述过程中，负极在负极的厚度方向上被加压，并且以1.0mA / cm 2的电流密度进行初始阶段充电和最后阶段充电，或减。版权所有（C）2005，JPO＆NCIPI

4. 发明专利

JP2004146104A Nonaqueous electrolyte secondary battery 有权
公开(公告)号：JP2004146104A
公开(公告)日：2004-05-20
申请号：JP2002306980
申请日：2002-10-22
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： YAMADA MASAYUKI , MORIMOTO HIDEYUKI , UEDA TOKUJI , AOYAMA SHIGEO
IPC分类号： H01M4/13 , H01M4/134 , H01M4/36 , H01M4/38 , H01M4/40 , H01M4/62 , H01M10/05 , H01M4/02 , H01M10/40
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a high-energy-density nonaqueous electrolyte secondary battery that prevents an electrode from being expanded or shrunk even if a charging/discharging cycle is repeated, prevents a conductive network inside the electrode from being destroyed, and prevents battery capacity from decreasing or internal resistance from increasing.
SOLUTION: In the nonaqueous electrolyte secondary battery containing a positive electrode, a negative electrode, and a nonaqueous electrolyte; the negative electrode contains a collector 12 and a negative electrode active material particle 11, the negative electrode active material particle is deposited on the collector 12, the thickness of the negative electrode active material layer deposited on the collector 12 is set to the two times or less of the average particle diameter of the negative electrode active material particle 11, and the average particle diameter of the negative electrode active material particle 11 is preferably set to 2-100 μm.
COPYRIGHT: (C)2004,JPO

5. 发明专利

JP2008270086A Nonaqueous electrolyte secondary battery 有权
标题翻译：非电解电解质二次电池
公开(公告)号：JP2008270086A
公开(公告)日：2008-11-06
申请号：JP2007114521
申请日：2007-04-24
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： UEDA TOKUJI , EDAMOTO TOSHIYUKI , CHIYOU KANEYASU
IPC分类号： H01M4/131 , H01M4/133 , H01M4/36 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/0525 , H01M10/0567
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte secondary battery excelling in a cycle characteristic and a storage characteristic while achieving increase of capacity by high-voltage charging.
SOLUTION: A positive electrode of this nonaqueous electrolyte secondary battery contains a first positive electrode active material Li
(1+a) Mn
x Ni
y Co
(1-x-y-z) M
z O
2 or/and a second positive electrode active material Li
(1-s-b) Mg
s Co
(1-t-u) Al
t M'
u O
2 ; a compound having a bond represented by -SO
n - (1≤n≤4) is present on a surface of the positive electrode; the content of sulfur present on the surface of the positive electrode as the bond represented by the -SO
n - (1≤n≤4) is 0.2-1.5 atomic% when analyzed by an X-ray photoelectron spectroscopic method.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种具有循环特性和存储特性的非水电解质二次电池，同时通过高压充电实现容量的增加。解决方案：该非水电解质二次电池的正极包含第一正极活性物质Li（SB）（1 + a） SB> Co （1-xyz）/ / SB> 2 或/和第二正极活性物质Li（SB））镁取值钴（1-TU）铝吨 M'û 0 2 ; 在正极的表面上存在具有由-SO 3表示的键的化合物（1≤n≤4）。当通过X射线光电子分析时，作为由-SO n - （1≤n≤4）表示的键，存在于正极表面的硫的含量为0.2-1.5原子％光谱法。版权所有（C）2009，JPO＆INPIT

6. 发明专利

JP2007005148A Positive electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery 有权
标题翻译：非电解电解质二次电池和非电解电解质二次电池的正极
公开(公告)号：JP2007005148A
公开(公告)日：2007-01-11
申请号：JP2005184294
申请日：2005-06-24
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： HASHIMOTO HIROSHI , UEDA TOKUJI
IPC分类号： H01M4/02 , H01M4/131 , H01M4/505 , H01M4/525 , H01M4/62 , H01M10/05
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a positive electrode for a nonaqueous electrolyte secondary battery having high capacity and high safety in high temperature storage, and to provide the nonaqueous electrolyte secondary battery having the positive electrode.
SOLUTION: The positive electrode for the nonaqueous electrolyte secondary battery has a positive mix layer made of a positive mix containing a positive active material, a conductive auxiliary, and a binder, the positive mix contains a lithium transition metal composite oxide represented by general formula Li
(1+δ) Mn
x Ni
y Co
(1-x-y) O
2 (0≤δ≤0.05; 0.1 2 /g is contained as the conductive auxiliary, and the neutralization amount (A) obtained by neutralization titration of supernatant liquid obtained by immersing 2.5 g of the positive mix in 50 g of neutral water with a sulfuric acid solution having a concentration of 0.01 mol/l is 4.5 ml or less. The nonaqueous electrolyte secondary battery includes the positive electrode.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决的问题：提供一种高容量，高安全性的非水电解质二次电池用正极，并且提供具有正极的非水电解质二次电池。解决方案：非水电解质二次电池用正极具有由正极活性物质，导电性助剂和粘合剂构成的正极混合物构成的正极混合层，正极混合物含有以下的锂过渡金属复合氧化物通式Li＆lt; SB＆gt;（1 +δ）＆lt; SB＆gt; x＆lt; SB＆gt;＆lt; SB＆gt;（1-xy） 2 （0≤δ≤0.05; 0.1 / g，中和量（A）通过中和滴定上清液而得到的中和量（A），所述中和量通过将浓度为2.5g的正极混合物在50g中性水中浸渍， 0.01mol / l为4.5ml以下。非水电解质二次电池包括正极。版权所有（C）2007，JPO＆INPIT

7. 发明专利

JP2005135925A Electrode material and its manufacturing method, and nonaqueous secondary battery and its manufacturing method 有权
标题翻译：电极材料及其制造方法和非等级二次电池及其制造方法
公开(公告)号：JP2005135925A
公开(公告)日：2005-05-26
申请号：JP2004374141
申请日：2004-12-24
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： YAMADA MASAYUKI , AOYAMA SHIGEO , KA EIYO , UEDA TOKUJI
IPC分类号： C22C24/00 , C22C28/00 , H01M4/02 , H01M4/04 , H01M4/36 , H01M4/38 , H01M4/48 , H01M4/62 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M10/0569 , H01M10/058 , H01M10/40
CPC分类号： Y02T10/7011
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous secondary battery with large capacity and excellent cycling characteristics.
SOLUTION: In electrical material consisting of a complex particle including material containing lithium and an alloying element and a conductive material, the ratio of the material containing lithium and the alloying element to total mass of the complex particle is 30 mass% and less than or equal to 80 mass%, the composite particles have cavities in it, and when the bulk density of the composite particles is D1 (g/cm3), the true density of the composite particles is D2 (g/cm3) and a volumetric population (%) of the cavities of the composite particles is Vs =(1-1.35×D1/D2)×100, Vs is at least 35% and less than or equal to 70%.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供具有大容量和优异的循环特性的非水二次电池。解决方案：在由包含锂和合金元素的材料的复合颗粒和导电材料组成的电气材料中，包含锂和合金元素的材料与复合颗粒的总质量的比例为30质量％以下复合粒子的密度为D1（g / cm 3）时，复合粒子的真密度为D2（g / cm 3），体积复合颗粒的空洞的群体（％）为Vs =（1-1.35×D1 / D2）×100，Vs为至少35％且小于或等于70％。版权所有（C）2005，JPO＆NCIPI

8. 发明专利

JP2005135872A Electrode material for nonaqueous secondary battery, its manufacturing method, and nonaqueous secondary battery using it 有权
标题翻译：非电源二次电池用电极材料及其制造方法及使用其的非标次级电池
公开(公告)号：JP2005135872A
公开(公告)日：2005-05-26
申请号：JP2003373582
申请日：2003-10-31
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： YAMADA MASAYUKI , SHIRASAWA KO , UEDA TOKUJI , AOYAMA SHIGEO
IPC分类号： H01M10/05 , H01M4/02 , H01M4/36 , H01M4/48 , H01M4/485 , H01M4/62 , H01M4/58 , H01M10/40
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide an electrode material capable of realizing a nonaqueous secondary battery having high cycle characteristics, high heavy-load characteristics, and high capacity.
SOLUTION: The electrode material of the nonaqueous secondary battery has oxide particles of at least one element selected from the group comprising Ti, Zr, V, Nb, Cr, Mo, and W and a covering layer for covering the particles and containing a carbon material having conductivity, and the covering layer is contained in a ratio to the total weight of 5 wt% or less. When the intensity of a peak present in the frequency region of 1550 cm
-1 to 1650 cm
-1 on a Raman spectrum measured by using argon laser having a wavelength of 514.5 nm is represented by I
1 and when the intensity of a peak present in the frequency region of 1300 cm
-1 to 1400 cm
-1 on the Raman spectrum is represented by I
2 , ratio (L
2 /L
1 ) is 0.4-1.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供能够实现具有高循环特性，高重负荷特性和高容量的非水二次电池的电极材料。解决方案：非水二次电池的电极材料具有选自Ti，Zr，V，Nb，Cr，Mo和W中的至少一种元素的氧化物颗粒和用于覆盖颗粒并包含具有导电性的碳材料，并且包覆层的总重量为5重量％以下。当通过使用波长为514.5nm的氩激光器测量的拉曼光谱在1550cm -1 / 16min的频率区域中的峰值强度达到1650cm -1时，由I 1 表示，并且当存在于1300cm×SP -1的频率区域中的峰值强度至1400cm -1时，拉曼光谱由I 2 表示，比率（L 2 / L 1 ）为0.4-1。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2005108523A Thin film electrode, manufacturing method of the same, and lithium secondary battery using that thin film electrode 审中-公开
标题翻译：薄膜电极，其制造方法和使用薄膜电极的锂二次电池
公开(公告)号：JP2005108523A
公开(公告)日：2005-04-21
申请号：JP2003337895
申请日：2003-09-29
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： SUGIYAMA HIROSHI , UEDA TOKUJI , AOYAMA SHIGEO
IPC分类号： H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M10/05 , H01M4/02 , H01M4/04 , H01M10/40
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a thin film electrode having high elasticity, hardly generating swelling of an electrode, wrinkling of a current collector and a crack in an activator thin film, and manufacturing method of the same, and to provide a lithium secondary battery using the thin film electrode with high capacity, cycle property and rate property.
SOLUTION: The thin film electrode 1 comprises a current collector 2 made of metal not alloying with lithium, and a thin film 3 formed on the current collector 2, containing an element alloying with lithium, having porosity of not less than 1% and not more than 40%. The manufacturing method of the thin film electrode comprises a process of forming the thin film 3 containing an element alloying with lithium and a blowing agent on the surface of the current collector 2 made of metal not alloying with lithium, by an electroplating method, and a process of forming the thin film 3 so as to have a porosity of not less than 1% and not more than 40% by removing the blowing agent in the thin film 3.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种具有高弹性，几乎不产生电极膨胀，集电器起皱和活化剂薄膜中的裂纹的薄膜电极及其制造方法，并且提供一种锂二次电池使用具有高容量，循环性能和速率特性的薄膜电极。解决方案：薄膜电极1包括由与锂合金化的金属制成的集电体2和形成在集电体2上的含有与锂合金的元素，具有不小于1％的孔隙率的薄膜3，不超过40％。薄膜电极的制造方法包括以下步骤：通过电镀法形成含有与锂合金化的元素的薄膜3和由与金属非合金化的金属制成的集电体2的表面上的发泡剂，以及通过除去薄膜3中的发泡剂，形成薄膜3以具有不小于1％且不大于40％的孔隙率的工艺。（C）2005，JPO＆NCIPI

10. 发明专利

JP2004319457A Anode for nonaqueous secondary battery, its manufacturing method, and nonaqueous secondary battery using above anode 有权
公开(公告)号：JP2004319457A
公开(公告)日：2004-11-11
申请号：JP2004090631
申请日：2004-03-25
申请人： Hitachi Maxell Ltd , 日立マクセル株式会社
发明人： KOJIMA AKIMICHI , SUGIYAMA HIROSHI , MORIMOTO HIDEYUKI , UEDA TOKUJI , AOYAMA SHIGEO
IPC分类号： H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M10/05 , H01M4/02 , H01M4/04 , H01M10/40
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To improve charge/discharge efficiency and cycle characteristics of a thin-film electrode used for an anode of a nonaqueous secondary battery.
SOLUTION: The nonaqueous secondary battery is constituted by the use of the anode having an active material layer capable of storing and releasing lithium on a current collector having an intermetallic compound composed of at least a kind of element A selected from Sn, In, Ge, Ga, Pb, Al, and Si, and an element X substantially not reacting with Li, with a ratio Ib/Ia between respective strongest peak intensities I
a and I
b of X-ray diffraction peaks derived from the intermetallic compound and the above element A of 0.1 or less.
COPYRIGHT: (C)2005,JPO&NCIPI

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