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    • 2. 发明专利
    • Method for disposing of radioactive waste and solidified waste
    • 处理放射性废物和固化废物的方法
    • JP2007127545A
    • 2007-05-24
    • JP2005321069
    • 2005-11-04
    • Hitachi Ltd株式会社日立製作所
    • HINO YUKONOSHITA KENJISASAHIRA AKIRA
    • G21F9/30G21F9/02G21F9/36
    • PROBLEM TO BE SOLVED: To provide a method for disposing of radioactive waste which makes it possible to effectively suppress the rise in the pressure in a cask caused by a hydrogen gas evolved through radiolysis without making any major changes or modifications to cemented waste and the cask.
      SOLUTION: The radioactive waste 10 is stowed in the cask 1A and is solidified into solidified waste 12 with a hydraulic inorganic solidifier 11 like mortal. When an opening 1a of the cask 1A is sealed with a lid member 1B and the like to store the cask 1A, thereafter, a specific filler 13 such as water and mortal which dissolves the hydrogen generated through radiolysis and accelerates recombination reaction is filled into the cask 1A so that the volume of the cavity in the cask 1A can be ≤10%, preferably ≤6%, of the inside volume of the cask 1A.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种处理放射性废物的方法,其可以有效地抑制由通过放射分解放出的氢气引起的桶中的压力升高,而不会对胶结废料进行任何重大变化或改变 和酒桶。

      解决方案:放射性废物10放在桶1A中,用水力无机固化剂11固化成固体废物12,如凡士林。 当用盖构件1B等密封容器1A的开口1a以存储储物盒1A时,将填充有溶解通过放射分解产生的氢并促进重组反应的水和致死物等的特殊填充剂13填充到 桶1A,使得桶1A中的空腔体积可以低于桶1A的内部容积的10%,优选≤6%。 版权所有(C)2007,JPO&INPIT

    • 3. 发明专利
    • Radioactive waste solidification method and solidification device
    • 放射性废物固化方法和固化装置
    • JP2006258716A
    • 2006-09-28
    • JP2005079278
    • 2005-03-18
    • Hitachi LtdKansai Electric Power Co Inc:The株式会社日立製作所関西電力株式会社
    • KAWASAKI TORUKONDO YOSHIKAZUYAMAZAKI HIROTOASANO TAKASHINOSHITA KENJIHORIKAWA YOSHIHIKOHATSUOKA YOSHIMASAYASUDA TAKASHIHIGUCHI NATSUKO
    • G21F9/16G21F9/10
    • PROBLEM TO BE SOLVED: To efficiently solidify radioactive waste liquid containing sodium sulfate without allowing unreacting sulfate ions to remain therein, thereby obtaining a solidified body having high water resistance and extremely little affecting a buried artificial barrier.
      SOLUTION: In this radioactive waste liquid solidification method for solidifying radioactive waste liquid containing sodium sulfate, solidification procedure is divided into an insolubilization process for insolubilizing sulfate ions in the waste liquid while heating the waste liquid and a solidification process for solidifying the insolubilized waste liquid. Temperature variation is measured accompanying endothermic reaction of the waste liquid in the insolubilization process. Completion of the solidification process is determined based on the transition of temperature. After the completion of insolubilization, heating electric power is reduced and switching takes place to the solidification process (turning into water glass → polymerization solidification).
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了有效地固化含有硫酸钠的放射性废液,而不会残留硫酸根离子,从而获得具有高耐水性并且极少影响埋置的人造屏障的凝固体。 解决方案:在用于固化含有硫酸钠的放射性废液的放射性废液固化方法中,将固化步骤分为不溶解废液中的硫酸根离子同时加热废液的不溶化方法和固化不溶化的固化方法 废液。 随着不溶解过程中废液的吸热反应测量温度变化。 基于温度的转变来确定凝固过程的完成。 完成不溶化后,加热电力降低,凝固过程转化(变成水玻璃→聚合凝固)。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Underground environment assessment device and method
    • 地下环境评估装置及方法
    • JP2005315607A
    • 2005-11-10
    • JP2004130946
    • 2004-04-27
    • Hitachi Ltd株式会社日立製作所
    • OKUYAMA KEITANOSHITA KENJISASAHIRA AKIRA
    • G01V5/08C02F1/00G01N33/24
    • G01N33/24
    • PROBLEM TO BE SOLVED: To measure the distribution coefficient and the like of stratum in underground environment by using a boring hole and others. SOLUTION: In a boring hole underground, a stratum environment assessment device loading a stratum assessment sensor 20, a pump 14, a measuring system 7, a PC 8 and a data transmitter is provided. The stratum evaluation sensor 20 is constituted of a thin layer on a ground surface. Underground water mixed by a tracer 14 is sent to the sensor 20, the concentration variation of the tracer in underground water before and after contact to the ground 3 is measured with an analyzer 7. The PC 8 calculates a breakthrough curve from the concentration variation, and measures the distribution coefficient (Kd) of the ground 3 and underground water and an effective diffusion coefficient. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:通过使用钻孔等测量地下环境中地层的分布系数等。 解决方案:在地下的钻孔中,提供装载层评估传感器20的层状环境评估装置,泵14,测量系统7,PC 8和数据发送器。 地层评价传感器20由地面上的薄层构成。 由示踪剂14混合的地下水被传送到传感器20,用分析仪7测量与地面3接触之前和之后的地下水中的示踪剂的浓度变化.PC 8从浓度变化计算穿透曲线, 并测量地面3和地下水的分布系数(Kd)和有效扩散系数。 版权所有(C)2006,JPO&NCIPI
    • 5. 发明专利
    • Processing method for radioactive waste and its processing device
    • 放射性废物处理方法及其处理装置
    • JP2000075087A
    • 2000-03-14
    • JP24928298
    • 1998-09-03
    • Hitachi Ltd株式会社日立製作所
    • SASAHIRA AKIRAYOKOI HIROTOFUKAZAWA TETSUONISHI TAKASHIKAMOSHITA MAMORUNOSHITA KENJI
    • G21C19/46G21F9/06
    • Y02W30/883
    • PROBLEM TO BE SOLVED: To provide a processing method for radioactive waste using electrolyte containing Ag2+ which can reduce the amount of spent ion exchanger material. SOLUTION: By contacting nitric acid solution containing Ag2+ with U, Pu and Np having adhered to a filter in a reaction tank 1, these elements are solved in the nitric acid solution by the Ag2+ effects. In a cathode chamber 7 wherein a cathode 9 of the main electrolysis tank 2 is placed, the Ag2+ in nitric acid solution containing the solved elements is reduced to Ag+. These elements are removed from the nitric acid solution exhausted from the cathode chamber 7 by the ion exchanger material in an ion exchanger tower 3. In an anode chamber 6 wherein an anode 8 of the main electrolysis tank 2 is placed, the Ag+ contained in the nitric acid solution is oxidized to Ag2+. As removal amount of Ag2+ by the ion exchanger material can be drastically reduced, the life of ion exchanger material is extended and thus the generation amount of spent ion exchanger material is drastically reduced.
    • 要解决的问题:提供使用含有Ag2 +的电解质的放射性废物的处理方法,其可以减少废离子交换剂材料的量。 解决方案:通过将含有Ag2 +的硝酸溶液与附着在反应槽1中的过滤器的U,Pu和Np接触,这些元素通过Ag2 +效应溶解在硝酸溶液中。 在其中放置主电解槽2的阴极9的阴极室7中,将含有溶解元素的硝酸溶液中的Ag 2 +还原为Ag +。 这些元素从离子交换塔3中的离子交换剂材料从阴极室7排出的硝酸溶液中除去。在其中放置主电解槽2的阳极8的阳极室6中,包含在 硝酸溶液被氧化成Ag2 +。 由于离子交换剂材料的Ag 2+的去除量可以大大降低,离子交换剂材料的寿命延长,因此废离子交换剂材料的产生量急剧降低。
    • 7. 发明专利
    • Solidification disposal method for radioactive waste
    • 放射性废物固化处理方法
    • JP2007003393A
    • 2007-01-11
    • JP2005184863
    • 2005-06-24
    • Hitachi LtdKansai Electric Power Co Inc:The株式会社日立製作所関西電力株式会社
    • ASANO TAKASHINOSHITA KENJIKAWASAKI TORUKONDO YOSHIKAZUYAMAZAKI HIROTOHORIKAWA YOSHIHIKOHATSUOKA YOSHIMASAYASUDA TAKASHIHIGUCHI NATSUKO
    • G21F9/16G21F9/06
    • PROBLEM TO BE SOLVED: To provide a solidification disposal method for a radioactive waste provided with a procedure for determining within a proper range an amount of an alkaline earth metal compound and a material/compounding of a curing agent added to a radioactive waste liquid containing sulfate ion or the radioactive waste containing a soluble sulfate compound to bring a pH of water contacting with a solidified body into 12 or less and to bring a sulfate ion concentration into 200ppm or less.
      SOLUTION: The alkaline earth metal compound 7 is added to the radioactive waste in a drum can 4 to bring a molar amount of alkaline earth metal into 1.0 or more with respect to a molar amount of the sulfate ion contained in the radioactive waste, so as to prepare a mixture of a sulfate of a solidlike alkaline earth metal and a solution containing an alkali metal ion, and a silicon oxide compound 8 and blast furnace water granulation slag and/or fly ash 9 are added as the curing agent to the mixture to bring a molar amount into 1.2 or more with respect to a molar amount of the alkali metal contained in the radioactive waste, and is stirred by a stirrer 5 to be solidified.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:为了提供放射性废物的固化处理方法,其具有在适当范围内确定碱土金属化合物的量和添加到放射性废物中的固化剂的材料/配混的程序 含有硫酸根离子的液体或含有可溶性硫酸盐化合物的放射性废物使与固化体接触的水的pH达到12以下,并使硫酸根离子浓度达到200ppm以下。 解决方案:将碱土金属化合物7添加到鼓罐4中的放射性废物中,使碱土金属的摩尔量相对于放射性废物中所含的硫酸根离子的摩尔量为1.0以上 ,以制备固体状碱土金属的硫酸盐和含有碱金属离子的溶液和氧化硅化合物8和高炉水造粒渣和/或飞灰9的混合物作为固化剂加入到 所述混合物相对于放射性废物中所含的碱金属的摩尔量使摩尔量为1.2以上,并通过搅拌器5搅拌而固化。 版权所有(C)2007,JPO&INPIT
    • 8. 发明专利
    • Underground environment assessment device and method
    • 地下环境评估装置及方法
    • JP2009103724A
    • 2009-05-14
    • JP2009032463
    • 2009-02-16
    • Hitachi Ltd株式会社日立製作所
    • OKUYAMA KEITANOSHITA KENJISASAHIRA AKIRA
    • G01V5/08
    • PROBLEM TO BE SOLVED: To measure the distribution coefficient and the like of a stratum in underground environment by using a boring hole and others.
      SOLUTION: In a boring hole underground, a stratum environment assessment device loading a stratum assessment sensor 20, a pump 14, a measuring system 7, a PC 8 and a data transmitter is provided. The stratum evaluation sensor 20 is constituted of a thin layer on a ground surface. Underground water mixed by a tracer 14 is sent to the sensor 20, the concentration variation of the tracer in underground water before and after contact to the ground 3 is measured with an analyzer 7. The PC 8 calculates a breakthrough curve from the concentration variation, and measures the distribution coefficient (Kd) of the ground 3 and underground water and an effective diffusion coefficient.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:通过使用钻孔等来测量地下环境中的层的分布系数等。 解决方案:在地下的钻孔中,提供装载层评估传感器20的层状环境评估装置,泵14,测量系统7,PC 8和数据发送器。 地层评价传感器20由地面上的薄层构成。 由示踪剂14混合的地下水被传送到传感器20,用分析仪7测量与地面3接触之前和之后的地下水中的示踪剂的浓度变化.PC 8从浓度变化计算穿透曲线, 并测量地面3和地下水的分布系数(Kd)和有效扩散系数。 版权所有(C)2009,JPO&INPIT
    • 10. 发明专利
    • Underground environment evaluating method and underground environment evaluating device
    • 地下环境评估方法和地下环境评估装置
    • JP2007327762A
    • 2007-12-20
    • JP2006156903
    • 2006-06-06
    • Hitachi Ltd株式会社日立製作所
    • OKUYAMA KEITANOSHITA KENJISASAHIRA AKIRA
    • G01V9/02G01V5/08
    • PROBLEM TO BE SOLVED: To provide an underground environment evaluating device capable of correctly evaluating shutting-up capacity of a nuclide possessed by an underground environment in a short time.
      SOLUTION: This underground environment evaluating device A1 is characterized by having a thin layer flow passage 4 formed along a surface of underground base rock 3, a first liquid supply part of supplying a first liquid including a tracer to the thin layer flow passage 4, a second liquid supply part of supplying a second liquid without including the tracer to the thin layer flow passage 4, and a concentration measuring means 7 measuring the concentration of the tracer in an outlet of the thin layer flow passage 4.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种能够在短时间内正确评估地下环境所具有的核素的关闭能力的地下环境评估装置。 解决方案:该地下环境评估装置A1的特征在于,具有沿着地下基础岩石3的表面形成的薄层流路4,第一液体供给部,将包含示踪剂的第一液体供给到薄层流路 如图4所示,第二液体供给部分将不含示踪剂的第二液体供应到薄层流动通道4;以及浓度测量装置7,其测量薄层流动通道4的出口中示踪剂的浓度。 版权所有(C)2008,JPO&INPIT