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    • 5. 发明专利
    • New phosphonium salt ionic liquid and reaction solvent using the same
    • 新型磷酸盐锂离子液体和反应溶剂
    • JP2008222592A
    • 2008-09-25
    • JP2007060207
    • 2007-03-09
    • Nippon Chem Ind Co Ltd日本化学工業株式会社
    • TSUNASHIMA KATSUHIKO
    • C07F9/54C07C45/45C07C47/54C07C311/48
    • C07C303/38C07F9/5304Y02P20/542C07C311/48
    • PROBLEM TO BE SOLVED: To provide a phosphonium salt ionic liquid which has low viscosity, does not inhibit the diffusion or convection of reactive substrates, has extremely low reactivity with the reaction substrates, has an extremely low water content and can be utilized as a solvent for various organic synthetic reactions.
      SOLUTION: The ionic liquid comprises a quaternary phosphonium salt expressed by general formula (1) [wherein R
      1 to R
      4 are each a 1-6C linear alkyl, branched alkyl, alicyclic alkyl or an alkoxyalkyl expressed by -(CH
      2 )
      n O-R
      5 (wherein, n is an integer of 1 to 6; and R
      5 is methyl or ethyl) or the like, and at least one of the R
      1 to R
      4 is an alkoxyalkyl; and X is an anion], and the reaction solvent comprising the ionic liquid is also provided.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供具有低粘度,不抑制反应性底物的扩散或对流的鏻盐离子液体,与反应底物的反应性极低,具有极低的含水量并且可以被利用 作为各种有机合成反应的溶剂。 解决方案:离子液体包含由通式(1)表示的季鏻盐[其中R SB 1至R SB 4各自为1-6C直链烷基, 支链烷基,脂环族烷基或由 - (CH 2 )表示的烷氧基烷基,其中n为1〜6的整数。 ; R SB 5是甲基或乙基)等,并且R SB 1至R SB 4中的至少一个是烷氧基烷基; 并且X是阴离子],并且还提供包含离子液体的反应溶剂。 版权所有(C)2008,JPO&INPIT