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    • 2. 发明专利
    • ELECTRON BEAM RESIST
    • JPH0451244A
    • 1992-02-19
    • JP15979190
    • 1990-06-20
    • HITACHI LTDHITACHI VLSI ENG
    • MORI SHIGEKINITTA KYOYAMORITA MASAYUKITONOKAWA HIROSHI
    • G03F7/075H01L21/027
    • PURPOSE:To eliminate the need for an intermediate layer with a lower layer resist for flattening steps and to decrease the number of processes of resist processing by using a silanol compd. and an acid precursor as essential components. CONSTITUTION:The lower layer resist 3 for flattening steps consisting of a novolak resin and the electron beam resist 4 are successively applied on a silicon oxide film 2 of the main surface of a semiconductor wafer 1 consisting of a silicon single crystal. The electron beam resist is formed by dissolving the silanol compd. and the acid precursor in an org. solvent. The acid precursor is compounded at a ratio of 1 to 50wt.% with 50 to 99wt.% silanol compd. The acid liberated from the acid precursor of the exposed part changes to a catalyst and generate the condensation reaction of the silanol compd. if this electron beam resist is irradiated with radiations. Alkaline-insoluble polysiloxane is then formed. Only the unexposed part is then dissolved and the prescribed resist patterns are obtd. if the alkaline developing soln. is acted thereon.
    • 6. 发明专利
    • RESIST PROCESSING
    • JPH03253019A
    • 1991-11-12
    • JP4938290
    • 1990-03-02
    • HITACHI LTDHITACHI VLSI ENG
    • NITTA KYOYASHIRAI SEIICHIROHAYAKAWA HAJIME
    • G03F7/11G03F7/26H01L21/027H01L21/768
    • PURPOSE:To avoid the cracking in pattern corner parts even if polyvinylcarbazole is used and the first and second layers are dryetched by a method wherein heating or ultraviolet irradiation process or both of them are performed after the formation of the first layer. CONSTITUTION:In order to form a resist, firstly, the first layer (bottom layer) 4 containing polyvinylcarbazole is formed on a substrate 3 by spincoating process. Next, the layer 4 is baked for specific time and dried up simultaneously after irradiating it with ultraviolet ray (UV) for specific time, the second layer (intermediate layer) 5 is formed on the surface of the layer 4 also by spin- coating process. Next, after baking the layer 5, the third layer (topmost layer) 6 is formed on the layer 5 and then the layer 6 is baked. Finally, a pattern is formed to be tranferred (dryetched) to the underneath layer (bottom layer) 4. Through these procedures, the practice of surface oxidation, acceleration of resist bridging, enhancement of bond properties, relief of inner stress, etc., are made feasible. Resultantly, the cracking in the pattern corner parts of the layer 5 during the dryetching process of the layers 5, 6 can be avoided, thereby enabling the yield to be augmented.
    • 8. 发明专利
    • ELECTRONIC BEAM EXPOSURE SYSTEM
    • JPH01105534A
    • 1989-04-24
    • JP26154887
    • 1987-10-19
    • HITACHI LTDHITACHI VLSI ENG
    • AONO TAKESHIMORI SHIGEKINITTA KYOYA
    • G03F7/20H01L21/027H01L21/30
    • PURPOSE:To improve the dimensional accuracy of a figure by controlling the shape and rotation angle of the photoelectric surface of electronic beams or the strength of an astigmatic correction lens according to the change of area of the photoelectric surface of electronic beams to correct the astigmatism of electronic beams. CONSTITUTION:An astigmatism correction part 20 reads correction data from a correction data storing part 21 according to the information on the area of the photoelectric surface of an electronic beam 6 in the control information of the electro-optical system sent out from a pattern generation part 17. The correction part 20 accordingly increases or decreases the length of each side of the photoelectric surface of an electronic beam 6 via a shaping deflector control part 18. This correction and the correction of the rotation angle of the electronic beam 6 via a beam rotation lens control part 19 are combined with each other. The control such that the astigmatism in the electronic beam 6 irradiated to an exposed object 2 becomes the minimum is performed. This enables the dimensional accuracy of the figure to be improved.