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    • 4. 发明专利
    • SENSOR FOR WATER QUALITY
    • JPH06265514A
    • 1994-09-22
    • JP5537393
    • 1993-03-16
    • HITACHI LTD
    • ISHIZUKA KEIKOTAKAHASHI MASANORIWATANABE ATSUSHIIBE HIDEFUMI
    • G01N27/406G21C17/02
    • PURPOSE:To directly measure the concentration of oxygen, hydrogen peroxide in a reactor water under the radiation of radioactive rays by using an oxygen sensor which employs an ion conductive substance sufficiently capable of responding at temperatures in a reactor. CONSTITUTION:An ion conductive substance 1 is a metallic oxide using a solid electrolyte which sufficiently scatters in the temperature range from room temperatures to not higher than 300 deg.C, for example, Sc, Ti, V, Cr or the like. Electrodes 2 of thin films of Pt, Ag, etc., are attached at both sides of the ion conductive substance 1. A reference gas is housed at one side of the ion conductive substance 1 by an insulating body 3 and a material 4 having resistances to high temperatures and radioactive rays, e.g. stainless steel, an alloy of Ni base. The reference gas is communicated with a gas tank 6 from a piping 5 through, for instance, a capillary. The partial pressure of oxygen is kept to be constant at all times. The electrodes 2 are connected to a voltmeter 8 thereby to measure the electromotive force generated by the movement of ions.
    • 6. 发明专利
    • ANALYSIS APPARATUS FOR RADIOACTIVE GAS
    • JPH03262955A
    • 1991-11-22
    • JP6102090
    • 1990-03-14
    • HITACHI LTD
    • KURIYAMA OSAMUIBE HIDEFUMISUZUKI SADAJI
    • G01N27/62H01J49/00
    • PURPOSE:To remove a steam component from the inside of an analysis gas and to allow the discriminated analysis of ammonia and OH molecules by providing an absolute lower alcohol layer in the front stage of a mass spectrograph and passing the analysis gas through the absolute alcohol layer. CONSTITUTION:While the pressure in the system is checked by a pressure gage, the analysis gas is filled into the system and the inside of a gas sampling tube 8 is evacuated by a vacuum pump 7. Valves 9, 10, 11 are closed and after the vacuum degree is checked, the valve 9 is opened again and a micro-flow rate control valve 12 is gradually opened to introduce the analysis gas into the sampling tube 8 until the pressure gage 13 registers a prescribed value. While the analysis gas bubbles in a chemical trap 18 filled with the absolute alcohol cooled down to -20 deg.C by a cooler 17, the moisture is absorbed in the absolute alcohol. The moisture in the analysis gas is decreased in such a manner and the NH3 and the OH molecule are discriminated. The moisture is, therefore, removed by such simple apparatus and the inexpensive absorbent.
    • 7. 发明专利
    • MAIN STEAM SYSTEM RADIOACTIVE NITROGEN MEASUREMENT DEVICE AND ITS MEASURING METHOD
    • JPH02198394A
    • 1990-08-06
    • JP1616689
    • 1989-01-27
    • HITACHI LTD
    • IBE HIDEFUMI
    • G01T1/167G21C17/00
    • PURPOSE:To control the exact assessment of the concentration and the chemical form of radioactive nitrogen by grab-sampling a constant quantity of steam to measure after the steam is condensed in inactive gas at one to several atmospheres at the position as near as it can reach a pressure vessel of a main steam tube. CONSTITUTION:At first, a conventional sampling system is operated to form a steady steam/water flow in a system of a condenser 3 to a sampling rack. A device 23 is connected through the upper branch 5 of the condenser 3 and a condenser 4 is filled with a gas of normal to several atmospheres beforehand. At the time when purging of a sampling tube 2 is finished, a valve 6 is closed to prevent the reverse flow of downstream water of the condenser 3 from being produced to open a valve 7 so as to take the steam in the condenser 4. The inner pressure is monitored by a pressure gauge 10 to close the valve 7 at the time when it becomes specified pressure so as to open the valve 6. A time is measured from the time when the valve 7 is opened or closed to perform exact time assessment.
    • 8. 发明专利
    • OPERATION OF NUCLEAR REACTOR AND ITS DEVICE
    • JPH02179499A
    • 1990-07-12
    • JP33476788
    • 1988-12-28
    • HITACHI LTD
    • IBE HIDEFUMIASAKURA YAMATOBABA TSUTOMU
    • G21C17/02G21D3/08
    • PURPOSE:To contrive an improvement of a working efficiency of a nuclear reactor by detecting a leakage of an ion exchange resin into a reactor water and by reducing an oxygen generated in the reactor water from the leaked ion exchange resin with a reduction means to convert to an oxidized gas. CONSTITUTION:In case that leakage of an ion exchange resin in a reactor water purification system 1 provided to a pressure vessel 2 of a nuclear reactor occurs, a conductivity rises or a pH value decreases by a thermal decomposition of the resin at a downstream portion of a heat exchanger. The conductivity rise is detected by a conductivity monitor 13 to notify an in-leakage of the resin and a reducing agent is injected from an injecting device 10 of the reducing agent. Also, a catalyst is injected from an injecting device 14 of the catalyst, if required. Regarding to injection points, both injection points of the reducing agent and the catalyst are not necessary to be the same one but may be provided at a feed water system, the reactor water purification system 1, a cooling system for a control rod drive mechanism 6, a high/low pressure core injection system 7 and so on. A gas generated by an injection of the reducing agent is converted into a form of a safe gas and is discharged outside a system, accompanied with a steam.
    • 10. 发明专利
    • DIRECT CYCLE NUCLEAR POWER PLANT
    • JPH0213895A
    • 1990-01-18
    • JP16253288
    • 1988-07-01
    • HITACHI LTD
    • TAGAWA HISATOIBE HIDEFUMI
    • G21C19/307G21C19/30G21D1/00G21D3/08
    • PURPOSE:To prevent a generation of N in a nuclear reactor by adding a metal reacting quickly with a hydrogen to a reactor water and therewith decreasing concentration of hydrogen atoms in the reactor water. CONSTITUTION:Metal rods 3 made of metals such as a silver, a chromium, a ruthenium and the like which react quickly with a hydrogen are inserted into a fuel assembly 2 in place of fuel rods so as to make those metallic ions dissolve into the reactor water. The N is discharged to a main steam in the chemical form of NO and when a concentration of hydrogen atoms increases, a discharged amount of the NO increases also. With the reason that the N in a main steam system can be diminished by decreasing the concentration of hydrogen atoms and by suppressing a reaction of NO2+H NO+OH, the concentration of hydrogen atoms in the reactor water decreases and the above-mentioned reaction is suppressed by adding the metallic ions which react quickly with hydrogen atoms as explained above, and as the result, the N decreases.