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1. 发明专利

JP2006188682A Catalyst for synthesizing high trans-structured polymer 审中-公开
标题翻译：用于合成高转移结构聚合物的催化剂
公开(公告)号：JP2006188682A
公开(公告)日：2006-07-20
申请号：JP2005367502
申请日：2005-12-21
申请人： Goodyear Tire & Rubber Co:The , ザ・グッドイヤー・タイヤ・アンド・ラバー・カンパニーThe Goodyear Tire & Rubber Company
发明人： HALASA ADEL FARHAN , HSU WEN-LIANG , JASIUNAS CHAD A , AUSTIN LAURIE E
IPC分类号： C08F4/54 , C08F236/10
CPC分类号： C08F36/06 , C08F4/484 , C08F4/52 , C08F4/48 , C08F4/50
摘要： PROBLEM TO BE SOLVED: To provide a homopolymer or a copolymer of a conjugated diene monomer and an aromatic vinyl monomer useful in a tire tread and a side wall rubber, which have an excellent abrasion resistance, tear property and bending property.
SOLUTION: A copolymer of a conjugated diene monomer and an aromatic vinyl monomer having a high styrene content, a high trans-structure content and a high molecular weight can be obtained by using a catalyst system, which comprises (a) an organoaluminum compound, (b) an organolithium compound, and (c) a barium compound selected from (i) a barium salt of di(ehylene glycol) ethyl ether, (ii) a barium salt of di(ethylene glycol) propyl ether, (iii) a barium salt of di(ethylene glycol) hexyl ether, (iv) a barium salt of di(N,N-dimethylamino glycol) ethyl ether and (v) a barium salt of menthol in the presence of a polar modification agent comprising water, an alcohol, an amine, a thiol, a phosphate and a phosphite.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有优异的耐磨性，撕裂性和弯曲性的共轭二烯单体和可用于轮胎胎面的芳族乙烯基单体的均聚物或共聚物和侧壁橡胶。解决方案：通过使用催化剂体系，可以获得具有高苯乙烯含量，高反式结构含量和高分子量的共轭二烯单体和芳族乙烯基单体的共聚物，其包含（a）有机铝化合物，（b）有机锂化合物和（c）选自（i）二（乙二醇）乙醚的钡盐，（ii）二（乙二醇）丙醚的钡盐，（iii））二（乙二醇）己基醚的钡盐，（iv）二（N，N-二甲基氨基乙二醇）乙醚的钡盐和（v）薄荷醇的钡盐，在极性改性剂存在下，包含水，醇，胺，硫醇，磷酸酯和亚磷酸酯。版权所有（C）2006，JPO＆NCIPI

2. 发明专利

JP2008069347A Amine-containing catalyst system and method for using the same 审中-公开
标题翻译：含胺催化剂体系及其使用方法
公开(公告)号：JP2008069347A
公开(公告)日：2008-03-27
申请号：JP2007218249
申请日：2007-08-24
申请人： Goodyear Tire & Rubber Co:The , ザ・グッドイヤー・タイヤ・アンド・ラバー・カンパニーThe Goodyear Tire & Rubber Company
发明人： HALASA ADEL FARHAN , HSU WEN-LIANG , JASIUNAS CHAD A , ZUPPO III JOHN ROBERT , AUSTIN LAURIE E
IPC分类号： C08F4/54 , B60C1/00 , C08F36/04 , C08K3/04 , C08K3/36 , C08L9/00
CPC分类号： C08F36/04 , B60C1/0016 , C08F4/52 , C08F4/50
摘要： PROBLEM TO BE SOLVED: To provide an amine-containing catalyst system for synthesizing a rubbery polymer having a high trans microstructure. SOLUTION: The amine containing catalyst system is used for synthesizing a rubbery polymer, such as a polybutadiene rubber and a styrene-butadiene rubber, having a high trans microstructure. The catalyst system, in one embodiment, comprises (a) an organolithium compound, (b) a group IIa metal salt, (c) an organoaluminum compound and (d) an amine compound wherein the amine compound (d) can be selected from the group consisting of (1) a heterocyclic aromatic compound which includes a ring structure having one or more nitrogen atoms as a part of the ring, (2) a heterocyclic non-aromatic compound which includes a ring structure having two or more nitrogen atoms as a part of the ring, (3) an aromatic compound which includes a ring structure substituted with at least one amine and at least one polar functionality-containing group selected from a carboxy group or a hydroxy group, (4) a bicyclic chelating diamine compound and (5) an aliphatic amine which includes a 5-20C alkyl group. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种用于合成具有高反相微观结构的橡胶状聚合物的含胺催化剂体系。解决方案：含胺催化剂体系用于合成具有高反相微观结构的橡胶状聚合物，如聚丁二烯橡胶和苯乙烯 - 丁二烯橡胶。在一个实施方案中，催化剂体系包含（a）有机锂化合物，（b）IIa族金属盐，（c）有机铝化合物和（d）胺化合物，其中胺化合物（d）可以选自包括（1）包含具有一个或多个氮原子作为环的一部分的环结构的杂环芳族化合物的组，（2）包含具有两个或更多个氮原子的环结构的杂环非芳族化合物作为部分环，（3）芳族化合物，其包括被至少一个胺取代的环结构和至少一个选自羧基或羟基的极性官能团基团，（4）双环螯合二胺化合物和（5）包含5-20C烷基的脂族胺。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2008163336A Catalyst system for synthesizing amine functionalized rubbery polymer having high trans microstructure 审中-公开
标题翻译：用于合成具有高转移微结构的胺官能化橡胶聚合物的催化剂体系
公开(公告)号：JP2008163336A
公开(公告)日：2008-07-17
申请号：JP2007335875
申请日：2007-12-27
申请人： Goodyear Tire & Rubber Co:The , ザ・グッドイヤー・タイヤ・アンド・ラバー・カンパニーThe Goodyear Tire & Rubber Company
发明人： HALASA ADEL FARHAN , HSU WEN-LIANG , AUSTIN LAURIE E , JASIUNAS CHAD A , HENNING STEVEN KRISTOPER
IPC分类号： C08F4/48 , B60C1/00 , C08F36/04
CPC分类号： C08F36/04 , C08F4/48 , C08F4/54
摘要： PROBLEM TO BE SOLVED: To obtain a catalyst system for synthesizing a rubbery polymer such as a polybutadiene rubber, a styrene-butadiene rubber, an isoprene-butadiene rubber or a styrene-isoprene-butadiene rubber, etc., which is amine functionalized and has a high trans microstructure.
SOLUTION: The catalyst system comprises (a) an organolithium amine compound, (b) a group IIa metal salt of an amino glycol or a glycol ether, (c) an organoaluminum compound and optionally (d) an amine compound. The amine functionalized rubbery polymer is used for a rubber for a tire tread and the rubbery polymer provides a desirable wear resistance without substantially sacrificing one or more performance characteristics such as traction properties.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：为了获得聚合二烯橡胶，苯乙烯 - 丁二烯橡胶，异戊二烯 - 丁二烯橡胶或苯乙烯 - 异戊二烯 - 丁二烯橡胶等橡胶状聚合物的合成催化剂体系，其为胺功能化并具有高反向显微组织。解决方案：催化剂体系包括（a）有机锂胺化合物，（b）氨基二醇或二醇醚的IIa族金属盐，（c）有机铝化合物和任选的（d）胺化合物。胺官能化的橡胶状聚合物用于轮胎胎面的橡胶，并且橡胶状聚合物提供期望的耐磨性，而基本上不会牺牲一种或多种性能特征，例如牵引性能。版权所有（C）2008，JPO＆INPIT

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