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1. 发明专利

JP2012232926A Oligo(phenyleneoxy) group-containing cyclic phosphazene compound modified with unsaturated carbonyl group, and production method of the same 有权
标题翻译：具有不饱和碳原子团的OLIGO（苯乙烯）基团的环状磷酸酯化合物及其制备方法
公开(公告)号：JP2012232926A
公开(公告)日：2012-11-29
申请号：JP2011102548
申请日：2011-04-29
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： MORIYA NARIMASA , KAGAWA MASAMI , FUSHIMI TOSHITAKE , UTSUMI KEIICHIRO , IKEDA NORIAKI , ASANUMA KOTA , TADA YUJI
IPC分类号： C07F9/6581 , C07B61/00 , C07F9/6593 , C08F290/00 , C08G65/48 , C08L63/00 , C08L71/12 , C08L101/00 , C09K21/14
摘要： PROBLEM TO BE SOLVED: To provide a cyclic phosphazene compound that increases flame retardancy of a resin molded body without decreasing electric characteristics and high-temperature reliability.SOLUTION: An oligo(phenyleneoxy) group-containing cyclic phosphazene compound modified with an unsaturated carbonyl group is expressed by formula (1). In the formula, n represents an integer of 1 to 6; in a plurality of A, at least one A represents an oligo(phenyleneoxy) group-substituted phenyloxy group modified with an unsaturated carbonyl group and others represent an aryloxy group.
摘要翻译：解决的问题：提供在不降低电特性和高温可靠性的情况下提高树脂成型体的阻燃性的环状磷腈化合物。解决方案：用不饱和羰基改性的含低级（亚苯基氧基）的环状磷腈化合物由式（1）表示。在该式中，n表示1〜6的整数，在多个A中，至少一个A表示用不饱和羰基改性的低聚（苯撑氧基）基取代的苯氧基，其它代表芳氧基。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2010053086A Reactive group-bearing cyclic phosphazene compound and method for producing the same 有权
标题翻译：反应性组合式环状磷酸酯化合物及其制造方法
公开(公告)号：JP2010053086A
公开(公告)日：2010-03-11
申请号：JP2008220583
申请日：2008-08-28
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： TADA YUJI , MORIYA NARIMASA , IKEDA NORIAKI , KANAZAWA MAKOTO , UTSUMI KEIICHIRO
IPC分类号： C07F9/6581 , C07F9/6593 , C08K5/5399 , C08L101/00 , C09K21/12
摘要： PROBLEM TO BE SOLVED: To achieve a phosphazene compound that effectively enhances flame retardancy of a resin molded item without detriment to mechanical properties thereof and yet hardly injures high-temperature reliability and dielectric properties of the resin molded item. SOLUTION: The reactive group-bearing cyclic phosphazene compound is represented by formula (1) [in formula (1), n is an integer of 3-15; one example of A is a group selected from the group consisting of an acryloyloxy group-substituted phenyl group and a methacryloyloxy group-substituted phenyl group represented by formula (2); in formula (2), E 1 -E 5 are each independent; at least one of them is an acryloyloxy group or a methacryloyloxy group; at least one of them is at least one group selected from among 1-6C alkyl and alkenyl groups and an aryl group; and the rest are each a hydrogen atom]. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了获得有效地提高树脂模塑制品的阻燃性而不损害其机械性能的磷腈化合物，并且几乎不损害树脂模制品的高温可靠性和介电性能。反应性基团的环磷腈化合物由式（1）表示[式（1）中n为3-15的整数; A的一个实例是选自由式（2）表示的丙烯酰氧基取代的苯基和甲基丙烯酰氧基取代的苯基的基团; 在式（2）中，E 1 -E 5 各自独立; 其中至少一个是丙烯酰氧基或甲基丙烯酰氧基; 其中至少一个是至少一个选自1-6C烷基和链烯基和芳基的基团; 其余各为氢原子]。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2010037241A Glycidyloxy group-containing cyclic phosphazene compound and its production method 有权
标题翻译：含糖基团的环状磷酸酯化合物及其生产方法
公开(公告)号：JP2010037241A
公开(公告)日：2010-02-18
申请号：JP2008200291
申请日：2008-08-02
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： TADA YUJI , UTSUMI KEIICHIRO , IKEDA NORIAKI , MORIYA NARIMASA , KANAZAWA MAKOTO , SUZUKI ATSUKO
IPC分类号： C07F9/6593 , C08K5/5399 , C08L101/00 , C09K21/12
摘要： PROBLEM TO BE SOLVED: To provide a glycidyloxy group-containing phosphazene compound which can enhance the flame retardance of resin molded products and hardly deteriorates the mechanical characteristics and reliability of the resin molded products at high temperature. SOLUTION: Provided is a glycidyloxy group-containing cyclic phosphazene compound represented by formula (1), wherein, (n) is an integer of 3-8; A is a group selected from the group consisting of the following A1 group, A2 group, and A3 group, and at least one of 2n A groups is the A3 group. A1 group: a 1C-8C alkoxy group which may be substituted with a 1C-6C alkyl group or the like. A2 group: a 6C-20C aryloxy group which may be substituted with a 1C-6C alkyl group or the like. A3 group: at least one selected from the group consisting of 2-methyl-4-glycidyloxy-phenyloxy group, 3-methyl-4-glycidyloxy-phenyloxy group and 3,5-dimethyl-4-glycidyloxy-phenyloxy group. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供能够提高树脂成型体的阻燃性的含缩水甘油基氧基的磷腈化合物，并且几乎不降低树脂成型体在高温下的机械特性和可靠性。解决方案：提供由式（1）表示的含缩水甘油氧基的环状磷腈化合物，其中（n）为3-8的整数; A是选自以下A1组，A2组和A3组的组，并且2n A组中的至少一个是A3组。 A1基团：可以被1C-6C烷基等取代的1C-8C烷氧基。 A2基团：可被1C-6C烷基等取代的6C-20C芳氧基。 A3组：选自2-甲基-4-缩水甘油氧基 - 苯氧基，3-甲基-4-缩水甘油氧基 - 苯氧基和3,5-二甲基-4-缩水甘油氧基 - 苯氧基的至少一种。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2006117637A Method for producing cyclotriphosphazene derivative and cyclotriphosphazene derivative mixture 有权
标题翻译：生产环磷酰胺衍生物和环磷酰胺衍生物混合物的方法
公开(公告)号：JP2006117637A
公开(公告)日：2006-05-11
申请号：JP2005258751
申请日：2005-09-07
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： MARUYAMA MINORU , IKEDA NORIAKI , OTSUKA TATSUYA , MIYATAKE HIROAKI
IPC分类号： C07F9/659
摘要： PROBLEM TO BE SOLVED: To easily produce a cyclotriphosphazene derivative containing SOLUTION: The method for producing the cyclotriphosphazene derivative comprises a first reaction process in which hexahalogenated cyclotriphosphazene is reacted with a phenol salt in cyclopentyl methyl ether at a temperature ranging from -30°C to 80°C to obtain partially substituted halogenated cyclotriphosphazene and a second reaction process in which the partially substituted halogenated cyclotriphosphazene is reacted with a 4-cyanophenol salt in cyclopentyl methyl ether at a temperature ranging from 20°C to the boiling point of cyclopentyl methyl ether. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：为了容易地制备含有<50ppm残留卤素的环三磷腈衍生物。解决方案：环三磷腈衍生物的制备方法包括在-30℃至80℃的温度范围内使六卤化环三磷腈与苯酚盐在环戊基甲基醚中反应的第一反应方法，得到部分取代的卤代环三磷腈和第二反应方法，其中部分取代的卤代环三磷腈与环戊基甲基醚中的4-氰基苯酚盐在20℃至环戊基甲基醚的沸点温度下反应。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2012232927A Oligo(phenyleneoxy) group-containing cyclic phosphazene compound modified with cyanate group, and production method of the same 有权
标题翻译：含有氰基的OLIGO（苯乙烯）基团的环状磷酸酯化合物及其制备方法
公开(公告)号：JP2012232927A
公开(公告)日：2012-11-29
申请号：JP2011102550
申请日：2011-04-29
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： MORIYA NARIMASA , KAGAWA MASAMI , FUSHIMI TOSHITAKE , UTSUMI KEIICHIRO , IKEDA NORIAKI , KANAZAWA MAKOTO , TADA YUJI
IPC分类号： C07F9/6593 , C08G65/48 , C08K5/5399 , C08L71/12 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To provide a cyclic phosphazene compound that increases flame retardancy and dielectric characteristics of a resin molded body without decreasing high-temperature reliability and mechanical characteristics.SOLUTION: An oligo(phenyleneoxy) group-containing cyclic phosphazene compound modified with a cyanate group is provided, which is expressed by formula (1). In formula (1), n represents an integer of 1 to 6; in a plurality of A, at least one A represents a phenyleneoxy group expressed by formula (3) and others represent an aryloxy group. In formula (3), q represents an integer of 1 to 50; and Eto Erepresent a hydrogen atom, an alkyl group or the like.
摘要翻译：要解决的问题：提供增加树脂成型体的阻燃性和介电特性的环状磷腈化合物，而不降低高温可靠性和机械特性。解决方案：提供用氰酸酯基改性的含低级（亚苯基氧基）基团的环磷腈化合物，其由式（1）表示。在式（1）中，n表示1〜6的整数，在多个A中，至少一个A表示由式（3）表示的苯撑氧基，其余的表示芳氧基。式（3）中，q表示1〜50的整数， E 6 表示氢原子，烷基等。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2011001275A Phosphazene ring-having unsaturated carboxylate compound 有权
标题翻译：邻苯二甲酸环己酸不饱和羧酸酯化合物
公开(公告)号：JP2011001275A
公开(公告)日：2011-01-06
申请号：JP2009143752
申请日：2009-06-16
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： TADA YUJI , IKEDA NORIAKI , MORIYA NARIMASA , UTSUMI KEIICHIRO , FUSHIMI TOSHITAKE , SUZUKI ATSUKO
IPC分类号： C07F9/6593 , C08F220/36 , C09K21/12
摘要： PROBLEM TO BE SOLVED: To enhance flame retardancy without deteriorating the heat resistance and high temperature reliability of a molded resin article.SOLUTION: A resin composition comprising a phosphazene ring-having unsaturated carboxylate compound represented by formula (1) [wherein (n) is an integer of 1 to 6, at least one of groups A is an unsaturated carbonyloxy-2-hydroxypropoxy group-containing aryloxy group, and the others are each 1 to 8C alkoxy or a 6 to 20C aryloxy] and a resin component is produced, and then molded.
摘要翻译：要解决的问题：提高阻燃性而不会降低模制树脂制品的耐热性和高温可靠性。解决方案：一种树脂组合物，其包含由式（1）表示的具有磷腈环的不饱和羧酸酯化合物[其中（n）为 1〜6的整数，A组中的至少1个为不饱和的含氧羰基-2-羟基丙氧基的芳氧基，其余为1〜8个烷氧基或6〜20℃的芳氧基]，制造树脂成分，然后成型。

7. 发明专利

JP2010106167A Resin composition for electronic material 有权
标题翻译：电子材料用树脂组合物
公开(公告)号：JP2010106167A
公开(公告)日：2010-05-13
申请号：JP2008280329
申请日：2008-10-30
申请人： Fushimi Pharm Co Ltd , Mitsui Chemicals Inc , 三井化学株式会社 , 株式会社伏見製薬所
发明人： HIROTA KOSUKE , OKAWADO ETSUO , FUNAKI KATSUHIKO , TAWARA SHUJI , IKEDA NORIAKI , UTSUMI KEIICHIRO , SUZUKI ATSUKO , TADA YUJI
IPC分类号： C08F2/44 , C08G59/40 , C08K5/5399 , C08L63/00 , H05K3/28
摘要： PROBLEM TO BE SOLVED: To provide a resin composition which is a photosensitive resin composition containing an additive-type flame retardant and does not cause problems (such as bleed out) owing to phase separation between a resin matrix and the flame retardant when used commonly as a material for printed boards. SOLUTION: The resin composition for electronic materials contains (A) the phenoxy phosphazene flame retardant and (B) a compound having a photopolymerizable unsaturated double bond. The melting point of (A) the phenoxy phosphazene flame retardant is ≤100°C and the average number of functional groups each having an unsaturated bond per one molecule of the phenoxy phosphazene flame retardant is ≤0.1. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决方案：为了提供一种树脂组合物，其是含有添加型阻燃剂的感光性树脂组合物，并且由于树脂基质和阻燃剂之间的相分离而不会引起问题（例如渗出）通常用作印刷电路板的材料。解决方案：电子材料用树脂组合物含有（A）苯氧基磷腈阻燃剂和（B）具有光聚合性不饱和双键的化合物。（A）苯氧基磷腈阻燃剂的熔点≤100℃，苯氧基磷腈阻燃剂每1分子具有不饱和键的官能团的平均数≤0.1。版权所有（C）2010，JPO＆INPIT

8. 发明专利

JP2010037240A Hydroxy group-containing cyclic phosphazene compound and its production method 有权
标题翻译：含羟基的环状磷酸酯化合物及其生产方法
公开(公告)号：JP2010037240A
公开(公告)日：2010-02-18
申请号：JP2008200289
申请日：2008-08-02
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： TADA YUJI , MORIYA NARIMASA , IKEDA NORIAKI , ISHIKAWA SATORU , WATO TOMOKO
IPC分类号： C07F9/6581 , C07F9/6593 , C08K5/5399 , C08L101/00 , C09K21/12
摘要： PROBLEM TO BE SOLVED: To provide a hydroxy group-containing phosphazene compound which can enhance the flame retardance of resin molded products and hardly deteriorates the mechanical characteristics and reliability of the resin molded products at high temperature. SOLUTION: Provided is the hydroxy group-containing cyclic phosphazene compound represented by formula (1), wherein, (n) is an integer of 3 to 8; A is a group selected from the group consisting of the following A1 group, A2 group, and A3 group, and at least one of 2n A groups is the A3 group. A1 group: a 1-8C alkoxy group which may be substituted with a 1-6C alkyl group or the like. A2 group: a 6-20C aryloxy group which may be substituted with a 1-6C alkyl group or the like. A3 group: at least one selected from the group consisting of 2-methyl-4-hydroxy-phenyloxy group, 3-methyl-4-hydroxy-phenyloxy group and 4-hydroxy-3,5-dimethyl-phenyloxy group. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够提高树脂成型体的阻燃性的含羟基的磷腈化合物，并且几乎不降低树脂成型体在高温下的机械特性和可靠性。解决方案：提供式（1）表示的含羟基的环状磷腈化合物，其中，（n）为3〜8的整数， A是选自以下A1组，A2组和A3组的组，并且2n A组中的至少一个是A3组。 A1基团：可以被1-6C烷基等取代的1-8C烷氧基。 A2基团：可以被1-6C烷基等取代的6-20个芳氧基。 A3组：选自2-甲基-4-羟基 - 苯氧基，3-甲基-4-羟基 - 苯氧基和4-羟基-3,5-二甲基 - 苯氧基中的至少一种。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2009161716A Flame retardant resin composition 有权
标题翻译：阻燃树脂组合物
公开(公告)号：JP2009161716A
公开(公告)日：2009-07-23
申请号：JP2008013543
申请日：2008-01-24
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： TADA YUJI , UTSUMI KEIICHIRO , KANAZAWA MAKOTO , ISHIKAWA SATORU , KOYAMA SHIGETO , IKEDA NORIAKI
IPC分类号： C08L101/00 , C08K5/5399
摘要： PROBLEM TO BE SOLVED: To provide a resin producing a highly flame retardant resin molded product by using a phosphazene flame retarder without deteriorating heat resistance and high-temperature reliability. SOLUTION: A resin component contains a cyclic aryloxy phosphazene compound. The cyclic aryloxy phosphazene compound has an aryloxy group, which has a substituent having a Hammett substituent constant of 3.0 or more and no active hydrogen, and is represented by a specific formula. COPYRIGHT: (C)2009,JPO&INPIT

10. 发明专利

JP2008247800A Cyclic phosphazene compound containing reactive group and method for producing the same 有权
标题翻译：包含反应性组的环状磷酸酯化合物及其制造方法
公开(公告)号：JP2008247800A
公开(公告)日：2008-10-16
申请号：JP2007090637
申请日：2007-03-30
申请人： Fushimi Pharm Co Ltd , 株式会社伏見製薬所
发明人： NAKANAGA TAKEFUMI , TADA YUJI , IKEDA NORIAKI
IPC分类号： C07F9/6593 , C08K5/5399 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To provide a phosphazene compound effectively improving the flame retardancy of a molded resin article without deteriorating the mechanical properties of the article, keeping the high-temperature reliability of the molded resin article and having high adhesiveness. SOLUTION: The phosphazene compound is expressed by formula (1) (in the formula, n is an integer of 3-15; and A is a specific substituted phenyloxy group having allyl group and hydroxy group). COPYRIGHT: (C)2009,JPO&INPIT

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