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    • 3. 发明专利
    • Optical information recording medium
    • 光信息记录介质
    • JP2008041181A
    • 2008-02-21
    • JP2006214938
    • 2006-08-07
    • Fujifilm Corp富士フイルム株式会社
    • OBARA TOMOSATOWATANABE TETSUYAWATANABE KOSUKETAKAHASHI KEITA
    • G11B7/24B41M5/26G11B7/244
    • PROBLEM TO BE SOLVED: To provide an optical information recording medium that is provided with a recording layer, capable of performing high density recording and reproduction of information and having superior recording quality, even if it is irradiated with a laser light having wavelength of 450 nm or shorter. SOLUTION: A first write-once type recording layer 14, capable of recording information by irradiation with the laser light having wavelength of 450 nm or shorter is provided on a first substrate 12 of a first optical information recording medium 10A. A dyestuff, indicating a first weight reduction at 250°C or lower and a second weight reduction at 260°C or higher and having 60% weight reduction ratio or smaller at the time of reaching 300°C by thermogravimetric analysis, is contained in the first write-once type recording layer 14. An oxonol dyestuff is mentioned as a suitable example of such a dyestuff. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种具有记录层的光学信息记录介质,能够进行信息的高密度记录和再现并且具有优良的记录质量,即使用具有波长的激光照射 为450nm以下。 解决方案:在第一光学信息记录介质10A的第一基板12上设置能够通过用波长为450nm或更短波长的激光照射来记录信息的第一一次写入型记录层14。 表示在250℃以下的第一重量减少和260℃以上的第二重量减少,通过热重分析在达到300℃时具有60%重量减少率或更小的染料包含在 第一次一次写入型记录层14.作为这种染料的适当例子,提及氧杂菁染料。 版权所有(C)2008,JPO&INPIT
    • 4. 发明专利
    • Optical recording medium, information recording method, and method of utilizing dye
    • 光学记录介质,信息记录方法和使用染色体的方法
    • JP2008016110A
    • 2008-01-24
    • JP2006185378
    • 2006-07-05
    • Fujifilm Corp富士フイルム株式会社
    • KATAYAMA KAZUTOSHIWATANABE TETSUYAWATANABE KOSUKETAKAHASHI KEITAKINOSHITA ATSUHIRO
    • G11B7/24G11B7/244
    • PROBLEM TO BE SOLVED: To provide an optical recording medium having satisfactory reproduction durability without reducing a content of an additive agent to an organic dye that is a material of a recording layer and lowering an output of laser light. SOLUTION: In a first optical recording medium 10A including a first substrate 12 and a first write-once type recording layer 14 formed on the first substrate 12 and containing the dye and performing information recording and/or reproducing by irradiating the first write-once type recording layer 14 with a laser beam 46 having a wavelength of ≤450 nm, R3>-0.5 is satisfied, where R1 is the light absorbance of the first write-once type recording layer 14 before recording information on the first write-once type recording layer 14 by the laser beam 46, R2 is the light absorbance of the first write-once type recording layer 14 after recording information on the first write-once type recording layer 14 by the laser beam 46, and R3=(R1-R2)/R1 is a light absorbance changing rate of the first write-once type recording layer 14 before and after the recording. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供具有令人满意的再现耐久性的光学记录介质,而不会将添加剂的含量降低到作为记录层的材料的有机染料并降低激光输出。 解决方案:在包括形成在第一基板12上并包含染料并且通过照射第一写入执行信息记录和/或再现的第一基板12和第一一次写入型记录层14的第一光学记录介质10A中 - 具有波长为≤450nm的激光束46的类型记录层14,R3> -0.5,其中R1是在第一写入 - 记录层14记录信息之前的第一写入型记录层14的吸光度, 通过激光束46一次型记录层14,R2是通过激光束46记录在第一一次写入型记录层14上的信息之后的第一一次写入型记录层14的吸光度,并且R3 =(R1 -R2)/ R1是记录前后的第一一次写入型记录层14的吸光度变化率。 版权所有(C)2008,JPO&INPIT
    • 5. 发明专利
    • Optical recording medium
    • 光学记录介质
    • JP2007257687A
    • 2007-10-04
    • JP2006077340
    • 2006-03-20
    • Fujifilm Corp富士フイルム株式会社
    • KATAYAMA KAZUTOSHIKOBAYASHI NOBUYUKIWATANABE TETSUYA
    • G11B7/24B41M5/26G11B7/244
    • PROBLEM TO BE SOLVED: To provide an optical recording medium excellent in initial characteristics such as the PRSNR (Partial Response Signal to Noise Ratio). SOLUTION: The optical recording medium which has a recording layer to record or reproduce signals by being irradiated with a laser beam of a wavelength of 450 nm or less through a lens having a numerical aperture (NA) of 0.6 or larger and less than 0.7, and has the C/N rise power of 2.5 mW or larger when recording by using a single wave of 16.2 MHz. It is desirable that this recording layer contains at least two kinds of dyes preferably satisfying at least one of the following condition A or condition B. Condition A: contains the main dye A and a dye B having an extinction coefficient k which is larger than that of the dye A by 0.1 or more for the two kinds of dyes. Condition B: contains the main dye A and a dye B having a decomposition temperature which is lower than that of the dye A by 50°C or less for the two kinds of dyes. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供诸如PRSNR(部分响应信噪比)的初始特性优异的光记录介质。 解决方案:具有记录层的光记录介质,其通过用波长为450nm以下的激光束照射数值孔径(NA)为0.6以上的透镜而记录或再生信号 超过0.7,并且通过使用16.2MHz的单波进行记录时,C / N上升功率为2.5mW以上。 理想的是,该记录层含有至少两种优选满足以下条件A或条件B中的至少一种的染料。条件A:含有主染料A和具有大于其的消光系数k的染料B 的染料A为两种染料0.1以上。 条件B:对于两种染料,含有主染料A和染料B的分解温度比染料A的分解温度低50℃以下。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Optical information recording medium, information recording method and novel azo dye
    • 光学信息记录介质,信息记录方法和新型AZO DYE
    • JP2009255563A
    • 2009-11-05
    • JP2009071206
    • 2009-03-24
    • Fujifilm Corp富士フイルム株式会社
    • KANAZAWA YOSHINORIWATANABE KOSUKEWATANABE TETSUYAHASHIZUME TARO
    • B41M5/26G11B7/24G11B7/244
    • PROBLEM TO BE SOLVED: To provide an optical information recording medium capable of recording information by short wave laser light irradiation and having excellent light resistance of a dye and excellent stability of an amorphous film. SOLUTION: The optical information recording medium has a recording layer on a substrate. An azo dye expressed by formula (1): A p- *(X q+ ) k' [in formula (1), A p- expresses p-valent azo dye anion, p expresses integers of 1-5, X q+ expresses q-valent cation, q expresses integers of 1-5, k' is in a range of 0≤k'≤5 and expresses a value obtained by dividing the negative charge (p) in an anionic part expressed by A by (q), where the azo dye expressed by formula (1) contains no metal ion in the molecule] is incorporated in the recording layer. COPYRIGHT: (C)2010,JPO&INPIT
    • 解决的问题:提供能够通过短波激光照射记录信息并且具有优异的染料耐光性和非晶膜的稳定性优异的光学信息记录介质。 光信息记录介质在基板上具有记录层。 由式(1)表示的偶氮染料:在式(1)中,A *(X q + ) SP> p - 表示p价偶氮染料阴离子,p表示1-5的整数,X q +表示q价阳离子,q表示1-5的整数,k' 在0≤k'≤5的范围内,表示通过将由A表示的阴离子部分中的负电荷(p)除以(q)而得到的值,其中由式(1)表示的偶氮染料不含有金属离子 分子]结合在记录层中。 版权所有(C)2010,JPO&INPIT
    • 9. 发明专利
    • Optical recording medium and information-recording method
    • 光记录介质和信息记录方法
    • JP2007287298A
    • 2007-11-01
    • JP2006188992
    • 2006-07-10
    • Fujifilm Corp富士フイルム株式会社
    • KATAYAMA KAZUTOSHIWATANABE TETSUYAWATANABE KOSUKETAKAHASHI KEITA
    • G11B7/24B41M5/26G11B7/244
    • PROBLEM TO BE SOLVED: To provide an optical recording medium which can excellently record even with a short wavelength laser beam, clarify an optical constant required to a recording layer, in particular, a value of a real part (refractive index) of a complex refractive index and a variation in refractive index before and after recording, and is excellent in recording characteristics. SOLUTION: A second optical recording medium 10B is provided with a second substrate 24, a second write once type recording layer 26 formed on the second substrate 24 and a second light-reflecting layer 30. The second write once type recording layer 26 is irradiated with laser light 46 having a wavelength of 450 nm or shorter to record/reproduce information. In this case, the real part of the complex refractive index of the second write once type recording layer 26 is 1.2-1.5 before the information is recoded to the second write once type recording layer 26 with the laser light 46, and the real part of the complex refractive index of the second write once type recording layer 26 is 1.7-1.9 after the information is recoded to the second write once type recording layer 26 with the laser light 46. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供甚至可以用短波长激光束优异地记录的光学记录介质,阐明了记录层所需的光学常数,特别是实际部分(折射率)的值 记录前后的复折射率和折射率的变化,记录特性优异。 解决方案:第二光记录介质10B设置有第二基板24,形成在第二基板24上的第二一次写入型记录层26和第二光反射层30.第二一次写入型记录层26 用波长为450nm以下的激光46照射以记录/再现信息。 在这种情况下,第二写入型记录层26的复折射率的实部在信号被重新编码到具有激光46的第二写一次记录层26之前是1.2-1.5,实际部分 在使用激光46将信息重新编码到第二写入型记录层26之后,第二写入型记录层26的复折射率为1.7-1.9。(C)2008,JPO&INPIT