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    • 1. 发明专利
    • Method for manufacturing plastic optical fiber
    • 制造塑料光纤的方法
    • JP2005326501A
    • 2005-11-24
    • JP2004142708
    • 2004-05-12
    • Fuji Photo Film Co LtdSekisui Chem Co Ltd富士写真フイルム株式会社積水化学工業株式会社
    • SEN HIROYOSHIIKEMOTO YOICHINAKAMURA YOSHISADAMIZUSHIMA YASUYUKIOGURA TORUMIYASAKA SATOSHI
    • G02B6/44
    • PROBLEM TO BE SOLVED: To obtain a plastic optical fiber by coating an optical fiber with a resin, without giving thermal damages to the optical fiber.
      SOLUTION: The optical fiber (POF) 12 is conveyed to a coating apparatus 23. Polyethylene of 120°C is coated on the POF 12 so that the thickness is 225μm. The first protective layer-formed coated optical fiber 26a is conveyed to a water tank 27. Therein, the first protective layer-formed coated optical fiber 26a is cooled with cooling water of 15°C, and the polyethylene is hardened. The first protective layer-formed coated optical fiber 26a is conveyed to a second coating apparatus 29. Polyethylene of 120°C is coated on the first protective layer-formed coated optical fiber 26a so that the thickness is 225μm. The coated optical fiber 26 is conveyed to a water tank 32. Therein, the coated optical fiber 26 is cooled with cooling water of 15°C, and the polyethylene is hardened. As a result, the coated optical fiber 26 whose protective layer has a thickness of 450μm can be obtained.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:通过用树脂涂布光纤来获得塑料光纤,而不会对光纤造成热损伤。 解决方案:将光纤(POF)12输送到涂布装置23.将120℃的聚乙烯涂覆在POF 12上,使得厚度为225μm。 将第一保护层形成的涂覆光纤26a输送到水箱27.其中,第一保护层形成的涂覆光纤26a用15℃的冷却水冷却,聚乙烯硬化。 将第一保护层形成的涂覆光纤26a输送到第二涂覆装置29.将120℃的聚乙烯涂覆在第一保护层形成的涂覆光纤26a上,使得厚度为225μm。 涂覆的光纤26被输送到水箱32.其中,涂覆光纤26用15℃的冷却水冷却,聚乙烯硬化。 结果,可以获得保护层的厚度为450μm的被覆光纤26。 版权所有(C)2006,JPO&NCIPI
    • 3. 发明专利
    • Plastic primary coated optical fiber and manufacturing method therefor
    • 塑料原包装光纤及其制造方法
    • JP2006178102A
    • 2006-07-06
    • JP2004369992
    • 2004-12-21
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • MIZUSHIMA YASUYUKINAKAMURA YOSHISADA
    • G02B6/032G02B6/00G02B6/028
    • PROBLEM TO BE SOLVED: To reduce the refractive index of a clad in a plastic primary coated optical fiber (POF) without depending on material. SOLUTION: An outer tube 12 with a large number of fine pores 33 is formed. A core polymer is put in the outer tube 12 to constitute a core material 30 by rotational polymerization, and a preform 21 is prepared composed of the outer tube 12 and the core material 30. The POF is obtained by heating and drawing the preform 21. A large number of fine pores 33 of the outer tube 12 are dispersed through the heating and drawing, so that a number of micro pores are formed in the clad of the POF. The size of the micro pores is set to 1-1,000 μm, and the quantity thereof is set 1-70 vol%. The refractive index of the clad is reduced by these micro pores. Even if the same material as the outer core material is used for the clad, a clad having a lower refractive index than the outer core can be obtained, thereby expanding the selectivity of the base material for the clad. Thus, the POF having a superior affinity, a high NA and a high transmission rate can be obtained. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:降低塑料初级涂覆光纤(POF)中的包层的折射率,而不依赖于材料。 解决方案:形成具有大量细孔33的外管12。 将芯聚合物放入外管12中,通过旋转聚合构成芯材30,制备由外管12和芯材30构成的预制件21.通过加热和拉伸预成型件21获得POF。 外管12的大量细孔33通过加热和拉伸分散,使得在POF的包层中形成多个微孔。 微孔尺寸设定为1-1000μm,其数量为1-70体积%。 通过这些微孔,包层的折射率降低。 即使使用与外芯材料相同的材料作为包层,也可以获得折射率比外芯低的包层,从而扩大了包层的基材的选择性。 因此,可以获得具有优异亲和力,高NA和高透射率的POF。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Optical fiber cable and its manufacturing method
    • 光纤电缆及其制造方法
    • JP2006058774A
    • 2006-03-02
    • JP2004242615
    • 2004-08-23
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • MIZUSHIMA YASUYUKINAKAMURA YOSHISADATAKEMASA KATSUYA
    • G02B6/00G02B6/44
    • PROBLEM TO BE SOLVED: To obtain a plastic optical fiber cable with which thermal contraction is suppressed. SOLUTION: A preform is obtained by forming a core part having a GI type refractive index profile in a hollow cylindrical clad pipe. A GI type POF can be obtained by heating/fusion-drawing the preform. A GI type core wire 16 is obtained by covering the outer circumferential face of the GI type POF with polyethylene to form a protective layer 123. The GI type core wire 16 is arranged with a large number of aramid fibers on the outer circumference and covered with polyvinyl chloride to form the outermost layer 125, so that the plastic optical fiber cable 20 is obtained. The aramid fibers become a loose-type coating buffer layer 124, relaxing a stress imparted radially to the optical fiber cable 20. The optical fiber cable 20 is annealed at 60°C for 17 hours. Since the polymer of the outermost layer 124 is reoriented, longitudinal contraction is suppressed in the optical fiber cable 20 even when heat is applied thereto. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:获得抑制热收缩的塑料光缆。 解决方案:通过在中空圆柱形包覆管中形成具有GI型折射率分布的芯部来获得预制件。 可以通过加热/熔融预成型件获得GI型POF。 通过用聚乙烯覆盖GI型POF的外周面,形成GI型芯线16,形成保护层123.GI型芯线16在外周配置有大量芳族聚酰胺纤维,并被覆盖 聚氯乙烯以形成最外层125,从而获得塑料光缆20。 芳族聚酰胺纤维变成松散型涂层缓冲层124,缓解径向施加到光缆20的应力。光缆20在60℃下退火17小时。 由于最外层124的聚合物重新取向,所以即使在加热时也抑制了光纤20的纵向收缩。 版权所有(C)2006,JPO&NCIPI
    • 5. 发明专利
    • Plastic optical fiber preform and manufacturing method therefof
    • 塑料光纤预制件及其制造方法
    • JP2005316358A
    • 2005-11-10
    • JP2004276805
    • 2004-09-24
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • SATO MASATAKAUCHINO AYAHIWATARI YUKAMIZUSHIMA YASUYUKIONO SHIGETOSHI
    • G02B6/00
    • PROBLEM TO BE SOLVED: To suppress air bubbles in manufacturing a preform, and to reduce loss in manufacturing steps. SOLUTION: A raw material for an inner core is injected into a clad in which an outer core is formed on the inner surface, and the clad is loaded in a polymerization container 38. The polymerization container 38 is set in a rotary polymerizer 41 so as to rotate almost in a horizontal state. The outer core is a polymer formed by radical polymerization. A radical polymerization initiator and a chain-transfer agent are added to the outer core and the inner core raw material, and a monomer for the inner core is a radical polymerization compound. While the polymerization container 38 is being rotated, the reaction between the monomer for the inner core and the outer core and the polymerization reaction of the monomer for the inner core are performed. The obtained plastic optical fiber preform is formed with the cores on the whole inner surface of the clad without generation of air bubbles and the whole length can be made into a POF (plastic optical fiber) by extension. The POF to be obtained has an excellent transmission characteristic. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:在制造预成型件时抑制气泡,并减少制造步骤的损失。 解决方案:将用于内芯的原料注入到在内表面上形成外核的包层中,并将包层装载到聚合容器38中。将聚合容器38放置在旋转聚合器 41,以便几乎处于水平状态。 外核是通过自由基聚合形成的聚合物。 自由基聚合引发剂和链转移剂加入到外核和内核原料中,内核的单体是自由基聚合化合物。 当聚合容器38旋转时,进行用于内芯的单体和外芯之间的反应以及用于内芯的单体的聚合反应。 所得到的塑料光纤预制件在包层的整个内表面上形成有芯,而不产生气泡,并且整个长度可以通过扩展制成POF(塑料光纤)。 要获得的POF具有优异的传输特性。 版权所有(C)2006,JPO&NCIPI
    • 7. 发明专利
    • Plastic optical transmission body and its manufacturing method
    • 塑料光传输体及其制造方法
    • JP2003344674A
    • 2003-12-03
    • JP2002153371
    • 2002-05-28
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • MIZUSHIMA YASUYUKI
    • G02B6/00
    • PROBLEM TO BE SOLVED: To provide a plastic optical transmission body having an excellent optical transmission ability and being superior to heat-resistance, and to provide its manufacturing method. SOLUTION: The transmission body has at least an area composed of compositions containing polymers and inorganic oxides. The manufacturing method comprises a hydrolysis step of hydrolyzing alkoxides to generate the inorganic oxides and obtain the compositions containing polymers and inorganic oxides, while substantially maintaining transparency of a solution in the solution in which the polymers and the inorganic oxides are dissolved; and a molding step of molding the compositions. COPYRIGHT: (C)2004,JPO
    • 要解决的问题:提供具有优异的光传输能力并且优于耐热性的塑料光传输体,并提供其制造方法。 解决方案:透射体至少具有由含有聚合物和无机氧化物的组合物组成的区域。 该制造方法包括水解醇化物以产生无机氧化物的水解步骤,并获得含有聚合物和无机氧化物的组合物,同时基本上保持溶液中溶解有聚合物和无机氧化物的溶液的透明度; 和模塑该组合物的模制步骤。 版权所有(C)2004,JPO
    • 8. 发明专利
    • Method for manufacturing plastic optical member
    • 制造塑料光学构件的方法
    • JP2003329858A
    • 2003-11-19
    • JP2002141579
    • 2002-05-16
    • Fuji Photo Film Co LtdKoike Yasuhiro富士写真フイルム株式会社小池 康博
    • SATO MASATAKAMIYOSHI TAKAHITOSHIROKURA YUKIOOGURA TORUMIZUSHIMA YASUYUKI
    • G02B6/00
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a plastic optical member excellent in productivity by suppressing foaming from the member in working in the manufacturing of the plastic optical member. SOLUTION: In the method for manufacturing the plastic optical member consisting of a core part and a cladding part, a hollow tube to be the cladding part is fabricated and the core part is subsequently fabricated by polymerizing a polymerizable monomer in the hollow tube. The method for manufacturing the plastic optical member is characterized by slowly cooling the workpiece with 3°C/min or lower cooling rate until reaching Tg of the plastic optical member or lower temperature after finishing the polymerization step in the step to fabricate the core part. COPYRIGHT: (C)2004,JPO
    • 解决的问题:提供一种通过在制造塑料光学构件的工作中抑制来自构件的发泡而制造生产率优异的塑料光学构件的方法。 解决方案:在由芯部分和包层部分组成的塑料光学部件的制造方法中,制造作为包层部分的中空管,然后通过在中空管中聚合可聚合单体制造芯部分 。 制造塑料光学部件的方法的特征在于,在步骤中完成聚合步骤之后,以3℃/ min或更低的冷却速度缓慢冷却工件直到达到塑料光学部件的Tg或较低的温度,以制造芯部。 版权所有(C)2004,JPO
    • 9. 发明专利
    • Method for manufacturing plastic optical fiber preform
    • 制造塑料光纤预制件的方法
    • JP2006010775A
    • 2006-01-12
    • JP2004184017
    • 2004-06-22
    • Fuji Photo Film Co Ltd富士写真フイルム株式会社
    • MIZUSHIMA YASUYUKISATO MASATAKATAKEMASA KATSUYA
    • G02B6/00
    • PROBLEM TO BE SOLVED: To reduce a clad loss due to volume decrease in core polymerization of a preform. SOLUTION: An inner core is formed by tying an extension member 51 to one end part of a clad 12 provided with an outer core, and by injecting a monomer for the inner core into the outer core together with dopant or the like for polymerization. Before injecting the monomer, a volume ratio of the volume of the monomer for the inner core before polymerization to a polymerized body obtained after polymerization is obtained beforehand, and then an injection amount of the monomer for the inner core is determined so that the inside of the clad is filled with the core after polymerization. As to the plastic optical fiber preform thus obtained, the inside of the clad is filled with the core and the clad does not have a loss part, but the plastic optical fiber can be manufactured without waste. The optical fiber obtained has an excellent transmission characteristic. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了减少由于预成型体的芯聚合体积减小引起的包层损失。 解决方案:通过将延伸构件51与设置有外芯的包层12的一个端部连接并且通过将掺杂剂等与内芯的单体一起注入到外芯中而形成内芯, 聚合。 在注入单体之前,预先获得聚合前的内芯的单体体积与聚合后得到的聚合体的体积体积比,然后确定内芯的单体的注入量, 聚合后包层填充芯。 对于由此获得的塑料光纤预制件,包层的内部填充有芯,并且包层不具有损耗部分,但是可以无废弃地制造塑料光纤。 所获得的光纤具有优异的传输特性。 版权所有(C)2006,JPO&NCIPI
    • 10. 发明专利
    • Method for manufacturing plastic optical member
    • 制造塑料光学构件的方法
    • JP2003329859A
    • 2003-11-19
    • JP2002141491
    • 2002-05-16
    • Fuji Photo Film Co LtdKoike Yasuhiro富士写真フイルム株式会社小池 康博
    • SATO MASATAKAMIYOSHI TAKAHITOOGURA TORUSHIROKURA YUKIOMIZUSHIMA YASUYUKI
    • G02B6/00C08F2/00
    • PROBLEM TO BE SOLVED: To stably fabricate a plastic optical member having excellent performance with high productivity. SOLUTION: In the method for manufacturing the plastic optical member consisting of a core part and a cladding part, a hollow tube to be the cladding part is formed and the core part is subsequently formed by infusing a polymerizable monomer into the hollow tube and polymerizing it therein. The method for manufacturing the plastic optical member is characterized by conducting the polymerization reaction in the core part forming step under controlled pressure and varying the pressure. Preferably the polymerization reaction is conducted under at least two-stage pressure control wherein the pressure P 1 at the initial stage of the polymerization is 0.01-0.2 MPa and the pressure P 2 at the second stage is at least P 1 or higher. In the case the polymerization temperature T exceeds the boiling point of the polymerizable monomer, the heating polymerization is conducted at a pressure in which the boiling point of the polymerizable monomer is at least higher than T. COPYRIGHT: (C)2004,JPO
    • 要解决的问题:为了稳定地制造具有优异性能的高生产率的塑料光学部件。 解决方案:在由芯部分和包层部分构成的塑料光学部件的制造方法中,形成作为包层部分的中空管,随后通过将可聚合单体注入中空管中而形成芯部 并在其中聚合。 制造塑料光学构件的方法的特征在于在受控压力下在芯部形成步骤中进行聚合反应并改变压力。 优选地,聚合反应在至少两阶段的压力控制下进行,其中聚合初始阶段的压力P 1 为0.01-0.2MPa,压力P 2 在第二阶段为至少P 1 或更高。 在聚合温度T超过可聚合单体的沸点的情况下,加热聚合在可聚合单体的沸点至少高于T的压力下进行。(C)2004, JPO