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    • 2. 发明专利
    • Method for processing hydrogen sulfide, method for producing hydrogen and photocatalytic reactor
    • 加氢硫化氢的方法,生产氢和光催化反应器的方法
    • JP2006307333A
    • 2006-11-09
    • JP2006088477
    • 2006-03-28
    • Nittetsu Mining Co LtdTohoku Univ国立大学法人東北大学日鉄鉱業株式会社
    • MATSUMOTO HIROMICHIKISHIMOTO AKIRATAJI KAZUYUKI
    • C25B11/06B01J19/08B01J19/24B01J27/04B01J33/00B01J35/02C02F1/46C25B1/02
    • Y02P20/135Y02W10/37
    • PROBLEM TO BE SOLVED: To provide a technique capable of decomposing hydrogen sulfide and producing hydrogen efficiently by using a photocatalyst. SOLUTION: In the method for treating hydrogen sulfide and the method for producing hydrogen, a liquid tank having at least a photocatalyst electrode 1 made of photocatalyst and a liquid tank having a metal electrode 2 are separated by a cation exchange film 3, liquid including hydrogen sulfide or organic substance is stored in the liquid tank having the photocatalyst electrode 1, the photocatalyst electrode 1 is electrically connected with the metal electrode 2 and the photocatalyst is exposed to light. An acidic solution is preferably stored in the liquid tank having the metal electrode 2, and the photocatalyst preferably includes metal sulfide and is preferably formed as fine particles having a lamellar nanocapsule structure. A reactor may be an electrolysis cell 11 in which a photoelectrochemical cell is included. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供能够通过使用光催化剂有效地分解硫化氢和产生氢的技术。 解决方案:在硫化氢的处理方法和氢的制造方法中,至少具有由光催化剂构成的光催化剂电极1和具有金属电极2的液体槽的液体槽由阳离子交换膜3分离, 包含硫化氢或有机物质的液体储存在具有光催化剂电极1的液体槽中,光催化剂电极1与金属电极2电连接,光催化剂暴露于光。 酸性溶液优选储存在具有金属电极2的液体罐中,并且光催化剂优选包含金属硫化物,并且优选形成为具有层状纳米胶囊结构的细颗粒。 反应器可以是包含光电化学电池的电解槽11。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Method for removing polysulfide ion from basic aqueous solution
    • 从基本水溶液中去除聚苯乙烯的方法
    • JP2010089052A
    • 2010-04-22
    • JP2008264205
    • 2008-10-10
    • Nittetsu Mining Co LtdTohoku Univ国立大学法人東北大学日鉄鉱業株式会社
    • MATSUMOTO HIROMICHIKISHIMOTO AKIRATAKAHASHI HIDESHIHAYASHI AMITAJI KAZUYUKI
    • C02F1/72
    • PROBLEM TO BE SOLVED: To provide a method capable of recovering solid sulfur component by treating a basic aqueous solution containing a polysulfide ion generated in treating hydrogen sulfide from a petroleum refinery, etc.
      SOLUTION: The method for removing the polysulfide ion by treating the basic aqueous solution containing the polysulfide ion includes converting the polysulfide ion into elemental sulfur by bringing the basic aqueous solution containing the polysulfide ion into contact with a carbon cluster solution and separating the carbon cluster solution from the treated aqueous solution containing the elemental sulfur, or, alternatively, forming a suspending solution of the carbon cluster by dispersing the carbon cluster into the basic aqueous solution containing the polysulfide ion while converting the polysulfide ion into the elemental sulfur, and solid-liquid separating the suspending solution.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供一种能够通过处理在石油炼厂等处理硫化氢中产生的含有多硫化物离子的碱性水溶液来回收固体硫成分的方法。解决方案: 通过处理含有多硫化物离子的碱性水溶液的多硫化物离子包括通过使含有多硫化物离子的碱性水溶液与碳簇溶液接触而将多硫化物离子转化为元素硫,并将碳簇溶液与处理过的含有 或者,通过将碳簇分散到含有多硫化物离子的碱性水溶液中,同时将多硫化物离子转化为元素硫,并将固定液分离悬浮液,形成碳簇的悬浮溶液。 版权所有(C)2010,JPO&INPIT