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1. 发明专利

JP2004223740A Multi-color thermal recording material and method for forming image 审中-公开
公开(公告)号：JP2004223740A
公开(公告)日：2004-08-12
申请号：JP2003010849
申请日：2003-01-20
申请人： Fuji Photo Film Co Ltd , 富士写真フイルム株式会社
发明人： ARAI KINZO , SATO KOJI , KAWAGISHI TOSHIO , NARUSE HIDEAKI
IPC分类号： B41M5/323 , B41M5/26 , B41M5/28 , B41M5/30 , B41M5/337 , B41M5/34
摘要： PROBLEM TO BE SOLVED: To provide a multi-color thermal recording material capable of decreasing a fixing work and forming a high quality multi-color image with excellent light-resistance simply and at a low cost. SOLUTION: The multi-color thermal recording material has at least two image forming layers on a substrate. One layer of the image forming layers is a non-photocurable layer comprising a precursor of a color developing main chemical oxidative body expressed by general formula (I) and a coloring matter forming coupler. At least one layer of the image forming layers is a photocurable layer comprising the precursor of the color developing main chemical oxidative body expressed by general formula (I), the coloring matter forming coupler, and a photopolymerizable composition comprising a photopolymerization initiator and a polymerizable monomer. In the formula, A 3 is a group except a hydrogen atom which releases accompanied by a bonding electron pair with a nitrogen atom and forms the color developing main chemical oxidative body; A 2 is a group which releases by accompanying with formation of the coloring matter after the color developing main chemical oxidative body caused by releasing of A 3 is coupled with the coloring matter forming coupler to form a coloring matter precursor; and A 1 is a group which forms a coloring matter with a nitrogen atom and the coupler. COPYRIGHT: (C)2004,JPO&NCIPI

2. 发明专利

JP2003312149A Image forming material and method for forming image 审中-公开
标题翻译：图像形成材料和形成图像的方法
公开(公告)号：JP2003312149A
公开(公告)日：2003-11-06
申请号：JP2002123586
申请日：2002-04-25
申请人： Fuji Photo Film Co Ltd , 富士写真フイルム株式会社
发明人： SATO KOJI , ARAI KINZO
IPC分类号： B41M5/323 , B41M5/30
摘要： PROBLEM TO BE SOLVED: To provide an image forming material having excellent unsensitized preservability before recording and image storage stability after recording without necessity of a silver halide, and to provide a method for forming an image using the same. SOLUTION: The image forming material comprises: a dye precursor color developable by the contact with a base represented by formula (1); and an image forming layer containing at least one type of base precursor, [wherein Ar is an aromatic ring or a heterocyclic ring which may have a substituent, Cp is a coupler residue, which may not form a ring, L 1 is a protective group released from blocking by a base, and L 2 is a hydrogen atom or a substituent desorbed in the step of forming the dye]. The method for forming the image comprises the steps of: heating the image forming material in an image-like state and forming the image. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种在记录之前具有优异的未敏化保存性和在不需要卤化银的记录之后的图像保存稳定性的图像形成材料，并提供一种使用其形成图像的方法。图像形成材料包括：通过与由式（1）表示的碱接触可显影的染料前体颜料; 和含有至少一种碱前体的图像形成层，[其中Ar是可以具有取代基的芳香环或杂环，Cp是不能形成环的成色剂残基，L / SP>是由碱基封闭而释放的保护基，L 2 是在形成染料的步骤中解吸的氢原子或取代基的取代基]。形成图像的方法包括以下步骤：以图像状态加热图像形成材料并形成图像。版权所有（C）2004，JPO

3. 发明专利

JP2003076000A Image forming material and image forming method 审中-公开
标题翻译：图像形成材料和图像形成方法
公开(公告)号：JP2003076000A
公开(公告)日：2003-03-12
申请号：JP2001269843
申请日：2001-09-06
申请人： Fuji Photo Film Co Ltd , 富士写真フイルム株式会社
发明人： ARAI KINZO , SATO KOJI
IPC分类号： G03F7/004 , G03F7/027 , G03F7/029 , G03F7/031 , G03F7/26
摘要： PROBLEM TO BE SOLVED: To provide a unicolor or multicolor image forming material for which various light sources emitting lights of wavelengths ranging from the ultraviolet region to the near infrared region can be utilized, in a thoroughly dry processing system in which the use of a developing solution, etc., is not necessary and no waste is generated and capable of rapidly forming a high image quality and high resistance image with high sensitivity and to provide an image forming method. SOLUTION: The image forming material has an image forming layer containing a dye precursor and a deprotecting agent which reacts with the dye precursor to form a dye on the surface of a support, wherein the deprotecting agent is a nucleophilic agent.
摘要翻译：要解决的问题：提供一种单色或多色图像形成材料，其可以在使用显影剂的彻底干燥的处理系统中利用从紫外线区域到近红外区域发射波长的各种光源的各种光源溶液等不是必需的，并且不会产生浪费并且能够以高灵敏度快速形成高图像质量和高电阻图像并提供图像形成方法。解决方案：图像形成材料具有包含染料前体和脱保护剂的图像形成层，其与染料前体反应以在载体的表面上形成染料，其中脱保护剂是亲核剂。

4. 发明专利

JP2003073579A Dye-forming material, image-forming material and method for forming image 审中-公开
标题翻译：成型材料，图像形成材料和形成图像的方法
公开(公告)号：JP2003073579A
公开(公告)日：2003-03-12
申请号：JP2001264488
申请日：2001-08-31
申请人： Fuji Photo Film Co Ltd , 富士写真フイルム株式会社
发明人： SATO KOJI , ARAI KINZO
IPC分类号： G03F7/004 , B41M5/26 , B41M5/30 , B41M5/323 , B41M5/337 , C09B55/00
摘要： PROBLEM TO BE SOLVED: To provide a dye-forming material by which image can be formed in good efficiency without requiring an oxidizing agent such as silver halide and an image-forming method using the material and to provide a method for forming image. SOLUTION: The dye-forming material comprising an azomethine dye precursor represented by the general formula (1) [wherein Ar is an aromatic ring or the like; Cp is a coupler residue; L is structural formula (1) (wherein X is O, S or SO2 ; R and R are each hydrogen atom or a substituent group); L is hydrogen atom or a substituent group] and a deblocking agent represented by the general formula (2): (A)p (B)q [wherein A is an atomic group having a monovalent or trivalent cation; B is an atomic group having an anion neutralizing the charge of A; p and q are each an integer of 1 or 6] and forming an azomethine dye by acting on the azomethine dye precursor, the image-forming material using the dye-forming material and the method for forming image are provided.
摘要翻译：要解决的问题：提供一种能够以高效率形成图像的染料形成材料，而不需要诸如卤化银的氧化剂和使用该材料的图像形成方法，并提供形成图像的方法。解决方案：包含由通式（1）表示的偶氮甲碱染料前体的染料形成材料[其中Ar是芳环等; Cp是成色剂残基; L 1是结构式（1）（其中X是O，S或SO 2; R 1和R 2各自是氢原子或取代基）; L 2是氢原子或取代基]和由通式（2）表示的去封闭剂：（A）p（B）q [其中A是具有一价或三价阳离子的原子团; B是具有中和A电荷的阴离子的原子团; p和q各自为1或6的整数]，并通过作用于偶氮甲碱染料前体形成偶氮甲碱染料，提供使用染料形成材料的成像材料和形成图像的方法。

5. 发明专利

JP2003002920A Polymerizable phenol derivative, photopolymerizable composition and recording material 审中-公开
标题翻译：可聚合苯酚衍生物，光聚合组合物和记录材料
公开(公告)号：JP2003002920A
公开(公告)日：2003-01-08
申请号：JP2001189896
申请日：2001-06-22
申请人： Fuji Photo Film Co Ltd , 富士写真フイルム株式会社
发明人： ARAI KINZO , FUKUSHIGE YUICHI
IPC分类号： G03F7/027 , C07C271/16 , C07C275/10 , C07C311/04 , C07C317/28 , C08F20/36 , C08F20/38 , C08F20/60 , G03F7/004 , G03F7/26
摘要： PROBLEM TO BE SOLVED: To provide a polymerizable phenol derivative that has excellent stability, storability and increased photo-polymerization sensitivity, a photopolymerizable composition including the derivative and a recording material. SOLUTION: The polymerizable phenol derivative is represented by the following general formula (I) (wherein R through R are each a H atom or a substituent of which at least one is hydroxyl; L is a divalent linkage group having the region capable of intermolecularly forming the hydrogen bonds; P is a polymerizable substituent bearing an unsaturated bond).
摘要翻译：要解决的问题：提供具有优异的稳定性，保存性和提高光聚合敏感性的可聚合苯酚衍生物，包含该衍生物和记录材料的光聚合组合物。解决方案：可聚合苯酚衍生物由以下通式（I）表示（其中R 1至R 5各自为H原子或其至少一个为羟基的取代基; L为具有能够分子上形成氢键的区域; P是具有不饱和键的可聚合取代基）。

6. 发明专利

JP2001207073A AZOMETHINE PIGMENT PRECURSOR, IMAGE-FORMING MATERIAL AND IMAGE-FORMING METHOD 失效
公开(公告)号：JP2001207073A
公开(公告)日：2001-07-31
申请号：JP2000018425
申请日：2000-01-27
申请人： FUJI PHOTO FILM CO LTD
发明人： SATO KOJI , YUMOTO MASATOSHI , ARAI KINZO , MATSUMOTO HIROTAKA
IPC分类号： G03F7/004 , B41M5/323 , C07D273/06 , C08F2/46 , C09B55/00 , C09B67/28 , G03C1/498 , G03C7/32 , G03F7/027 , G03F7/028 , G03F7/029 , G03F7/26 , G03F7/40 , B41M5/30
摘要： PROBLEM TO BE SOLVED: To obtain an azomechine pigment precursor which exhibits a good developed color with less energy and becomes extremely good in storage stability of an image obtained, and to obtain a monochromatic or polychromatic image-forming material capable of rapidly forming a highly sensitive, high image quality and highly resistant image, and to provide an image-forming method. SOLUTION: An image-forming material and an image-forming method use an azomethine pigment precursor represented by general formula (1): (in general formula (1), Ar is an aromatic ring or a heterocycle which may have substituents; X is a bivalent group linking a carbon atom to a nitrogen atom; Cp is a coupler residue which may either form a ring or not).

7. 发明专利

JP2005119220A Method for manufacturing recording medium and method for manufacturing inkjet recording medium 审中-公开
标题翻译：制造记录介质的方法和制造喷墨记录介质的方法
公开(公告)号：JP2005119220A
公开(公告)日：2005-05-12
申请号：JP2003358803
申请日：2003-10-20
申请人： Fuji Photo Film Co Ltd , 富士写真フイルム株式会社
发明人： ARAI KINZO
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a recording medium which specially shows high image resistance such as light resistance/anti-ozone properties; excellent surface smoothness/glossiness of a recording surface; is capable of forming a high-resolution/high-density; and free from the generation of a phenomenon such as tinting of paper surface; and less odorous, and a method for manufacturing an inkjet recording medium which especially shows high image resistance such as light resistance/anti-ozone properties; excellent surface smoothness/glossiness of a recording surface; is almost free from bleeding over time and the generation of a phenomenon such as tinting of a paper surface; is capable of forming a high-resolution/high-density image; and is less odorous. SOLUTION: The method for manufacturing a recording medium uses at least an oxidation treatment liquid obtained by oxidatively treating a thioether compound and the method for manufacturing an inkjet recording medium includes a process to form an ink acceptance layer by applying a coating liquid for the ink acceptance layer to the surface of a support. In addition, the method for manufacturing an inkjet recording medium employs the oxidation treatment liquid obtained by oxidatively treating the thioether compound. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种专门显示诸如耐光/抗臭氧性能的高图像电阻的记录介质的制造方法; 良好的表面平滑度/光泽度的记录表面; 能够形成高分辨率/高密度; 并且不会产生诸如着色纸表面的现象; 并且不那么恶臭，以及特别显示诸如耐光/抗臭氧性能的高图像电阻的喷墨记录介质的制造方法; 良好的表面平滑度/光泽度的记录表面; 随着时间的推移几乎没有出血，并且产生了纸张表面的着色等现象; 能够形成高分辨率/高密度图像; 而且不那么恶心。解决方案：用于制造记录介质的方法至少使用通过氧化硫醚化合物而获得的氧化处理液，并且喷墨记录介质的制造方法包括通过涂布用于油墨接受层到支撑体的表面。此外，喷墨记录介质的制造方法采用通过氧化硫醚化合物而得到的氧化处理液。版权所有（C）2005，JPO＆NCIPI

8. 发明专利

JP2003012609A Polymerizable phenol derivative, photopolymerizable composition, and recording material 审中-公开
标题翻译：可聚合酚醛衍生物，光聚合组合物和记录材料
公开(公告)号：JP2003012609A
公开(公告)日：2003-01-15
申请号：JP2001191747
申请日：2001-06-25
申请人： Fuji Photo Film Co Ltd , 富士写真フイルム株式会社
发明人： ARAI KINZO , FUKUSHIGE YUICHI
IPC分类号： G03F7/004 , C07C69/84 , C08F20/00 , C08K5/00 , C08L33/00 , C09D11/00 , G03F7/027
摘要： PROBLEM TO BE SOLVED: To obtain a polymerizable phenol derivative excellent in stability and shelf life and improved in photosensitivity and provide a photopolymerizable composition containing the above derivative and a recording material. SOLUTION: This polymerizable phenol derivative is expressed by general formula (I) [wherein R to R express each H or a substituent and at least one of them expresses OH; L expresses a divalent bond group; P expresses a substituent expressed by general formula (II) (wherein A expresses a functional group through a heteroatom; Ra and Rb express each independently H, a halogen, cyano or an organic residue and may form a cyclic structure by bonding to each other)].
摘要翻译：要解决的问题：获得稳定性和保质期优异且光敏性提高的聚合性酚衍生物，并提供含有上述衍生物和记录材料的光聚合性组合物。解决方案：该可聚合苯酚衍生物由通式（I）表示[其中R 1至R 5表示每个H或取代基，并且其中至少一个表示OH; L表示二价键组; P表示由通式（II）表示的取代基（其中A表示通过杂原子的官能团; Ra和Rb各自独立地表示H，卤素，氰基或有机残基，并且可以通过彼此键合形成环状结构） ]。

9. 发明专利

JP2002351067A IMAGE FORMING MATERIAL AND IMAGE FORMING METHOD USING THE SAME 失效
公开(公告)号：JP2002351067A
公开(公告)日：2002-12-04
申请号：JP2001160702
申请日：2001-05-29
申请人： FUJI PHOTO FILM CO LTD
发明人： SATO KOJI , ARAI KINZO , HANAZAKI KYOKO
IPC分类号： G03F7/004 , G03F7/26 , G03F7/40
摘要： PROBLEM TO BE SOLVED: To provide an image forming material from which an image is efficiently formed at a low cost and an image forming method using the image forming material and enabling formation of an image by a simple operation at a low cost. SOLUTION: The image forming material has a photosensitive material A having a layer containing an azomethine dye precursor of formula (1) and/or formula (2), a polymerizable compound and a photopolymerization initiator on a support and a dye forming material A having a layer containing a deprotecting agent which acts on the azomethine dye precursor to form an azomethine dye on a support. In the formula (1), Ar is an aromatic ring or a heterocycle; X is a divalent group which lines C and N together; and Cp is a coupler residue. In the formula (2), Ar is an aromatic ring or a heterocycle; Cp is a coupler residue; L is a protective group; and L is H or a substituent which is released in a dye forming process.

10. 发明专利

JP2000319283A BORATE COMPOUND AND PHOTOPOLYMERIZABLE COMPOSITION AND RECORDING MATERIAL CONTAINING THE SAME 失效
公开(公告)号：JP2000319283A
公开(公告)日：2000-11-21
申请号：JP10846699
申请日：1999-04-15
申请人： FUJI PHOTO FILM CO LTD
发明人： ARAI KINZO , FUKUSHIGE YUICHI
IPC分类号： C07F5/02 , C08F2/50 , C08F4/52 , C09B69/02 , G03F7/029
摘要： PROBLEM TO BE SOLVED: To obtain a photopolymerizable composition having high sensitivity and superior in storage properties even in cases where an acid-containing medium is also present by steric protection effect and a new compound useful as a recording material. SOLUTION: This compound is represented by formula I [R1 is an alkyl; R2 to R4 are each a group of formula II; Z+ is a group capable of forming a cation; R5 is an electron donative group; R6 to R9 are each a substituent group; the total value of the Hammett substituent sigma constants of R5 to R9 is 0-1], e.g. a compound of formula III. The compound of formula I, e.g. the above exemplified compound is obtained by reacting benzylmagnesium chloride with tris(5-fluoro-2-methylpheny)boran and then reacting the reaction product with tetrabutylammonium bromide.

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