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    • 1. 发明专利
    • Polyamide/polyolefin resin composition
    • 聚酰胺/聚烯烃树脂组合物
    • JP2008163180A
    • 2008-07-17
    • JP2006353942
    • 2006-12-28
    • Denso CorpKyosan Denki Co LtdUnitika Ltdユニチカ株式会社京三電機株式会社株式会社デンソー
    • KATAHIRA SHINICHIROTAGAMI HIRONARIANDO YUKIYA
    • C08L77/00C08K3/34C08L23/26
    • PROBLEM TO BE SOLVED: To provide a resin composition excellent in fuel penetration resistance, welding strength in welding with a polyolefin based resin composition and the welding part exhibits welding strength with reduced decrease in soaking in a fuel. SOLUTION: The polyamide/polyolefin resin composition comprises (A) a polyamide resin composition composed of 100 pts.mass of a polyamide resin and 2-20 pts.mass of a swelling lamellar silicate dispersed in a molecular level wherein the composition has at least 2.0 of relative viscosity at 25°C, 1 g/dl of concentration dissolved in concentrated sulfuric acid of 96 mass% of concentration, and having amino terminal groups not more than 0.07 mmol/g, and (B) a modified polyolefin resin composition comprising a polyolefin resin with at least 0.92 g/cm 3 of density, modified with 1.0-4.0 pts.mass of acid anhydrides, etc., per 100 pts.mass of the polyolefin resin. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供耐燃料渗透性优异的树脂组合物,使用聚烯烃类树脂组合物的焊接中的焊接强度和焊接部分显示焊接强度,同时降低燃料中的浸泡减少。 聚酰胺/聚烯烃树脂组合物包含(A)聚酰胺树脂组合物,该聚酰胺树脂组合物由聚酰胺树脂的100个聚酰胺树脂和分散在分子水平上的2-20重量份的膨胀层状硅酸盐组成,其中组合物 25℃下的相对粘度为2.0以上,溶解浓度为96质量%浓度的浓硫酸浓度为1g / dl,氨基末端基为0.07mmol / g以下,(B)改性聚烯烃树脂 组合物包含每100磅聚烯烃树脂至少0.92g / cm 3密度的聚烯烃树脂,用1.0-4.0重量份的酸酐等改性。 版权所有(C)2008,JPO&INPIT
    • 4. 发明专利
    • Glass-fiber-reinforced polyamide resin composition
    • 玻璃纤维增​​强聚酰胺树脂组合物
    • JP2009215534A
    • 2009-09-24
    • JP2009005806
    • 2009-01-14
    • Unitika Ltdユニチカ株式会社
    • KIZARA YOSHIHITOFUJII SHIGETAFUJII HIROSHIKATAHIRA SHINICHIRO
    • C08J5/08C08K7/14C08L77/06
    • PROBLEM TO BE SOLVED: To provide a glass-fiber-reinforced polyamide resin composition which excels in mechanical strength, thin wall moldability, and surface appearance, and is suitable for a portable electric device component and a personal computer enclosure component having a thin wall.
      SOLUTION: The glass-fiber-reinforced polyamide resin composition comprises blending 50-150 mass parts of glass fiber based on 100 mass part of a polyamide resin composition which consists of 90-99 mass% of a polyamide resin and 1-10 mass% of an acid modification polystyrene based elastomer, wherein the polyamide resin comprises blending 20-60 mass% of polyamide 66 resin, 20-40 mass% of polyamide 12 resin, and 20-50 mass% of an amorphous polyamide resin, and the total amount is 100 mass%.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:提供一种机械强度,薄壁成型性和表面外观优异的玻璃纤维增​​强聚酰胺树脂组合物,并且适用于便携式电子设备部件和个人计算机外壳部件,其具有 薄壁。 解决方案:玻璃纤维增​​强聚酰胺树脂组合物包括:将基于100质量份的由90-99质量%的聚酰胺树脂和1-10重量份的聚酰胺树脂组成的聚酰胺树脂组合物混合50-150质量份的玻璃纤维 质量%的酸改性聚苯乙烯类弹性体,其中,聚酰胺树脂包含20-60质量%的聚酰胺66树脂,20-40质量%的聚酰胺12树脂和20-50质量%的无定形聚酰胺树脂, 总量为100质量%。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Glass fiber-reinforced polyamide resin composition
    • 玻璃纤维增​​强聚酰胺树脂组合物
    • JP2010001364A
    • 2010-01-07
    • JP2008160541
    • 2008-06-19
    • Unitika Ltdユニチカ株式会社
    • KATAHIRA SHINICHIRO
    • C08L77/02C08J5/10C08K3/34C08K7/14C08L23/26C08L71/02
    • PROBLEM TO BE SOLVED: To provide a glass fiber reinforced polyamide resin composition that is usable as a housing material for an electric power tool, has excellent impact strength, modulus of elasticity, bond strength to elastomer and surface gloss. SOLUTION: The glass fiber reinforced polyamide resin composition comprises 100 parts by mass of a polyamide 6 resin composition (a), 0.1-10 parts by mass of a polyamide/polyether resin (b), 1-30 parts by mass of a modified polyolefin resin (c) and 5-100 parts by mass of glass fiber (d). The polyamide 6 resin composition (a) is obtained by uniformly dispersing 0.1-10 parts by mass of a swelling laminar silicate into 100 parts by mass of a polyamide 6 resin. When the average fiber length of glass fiber (d) is L (μm), the average particle diameter is D (μm) and the average particle diameter of the swelling laminar silicate is Q (μm) and K=L/(D×Q), the relation represented by following general formula (I): 3≤K≤20 is satisfied. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种可用作电动工具的外壳材料的玻璃纤维增​​强聚酰胺树脂组合物,具有优异的冲击强度,弹性模量,与弹性体的粘结强度和表面光泽度。 解决方案:玻璃纤维增​​强聚酰胺树脂组合物包含100质量份聚酰胺6树脂组合物(a),0.1-10质量份聚酰胺/聚醚树脂(b),1-30质量份 改性聚烯烃树脂(c)和5-100质量份玻璃纤维(d)。 聚酰胺6树脂组合物(a)通过将0.1〜10质量份的溶胀层状硅酸盐均匀分散在100质量份的聚酰胺6树脂中而获得。 当玻璃纤维(d)的平均纤维长度为L(μm)时,平均粒径为D(μm),膨胀层状硅酸盐的平均粒径为Q(μm),K = L /(D×Q ),由以下通式(I)表示的关系:3≤K≤20。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Glass fiber-reinforced polyamide resin composition
    • 玻璃纤维增​​强聚酰胺树脂组合物
    • JP2009035591A
    • 2009-02-19
    • JP2007199118
    • 2007-07-31
    • Unitika Ltdユニチカ株式会社
    • KATAHIRA SHINICHIROFUJII SHIGETA
    • C08L77/00C08K7/10C08K9/04C08K9/06
    • PROBLEM TO BE SOLVED: To provide a reinforced polyamide resin composition in which both glass fibers and a swelling laminar silicate are used to improve the mechanical properties, especially tensile strength, of the reinforced polyamide resin composition.
      SOLUTION: This polyamide resin composition comprises: a swelling laminar silicate (A) prepared by inserting 0.5 to 30 pts.mass of an aliphatic primary amine between the layers based on 100 pts.mass of a swelling laminar silicate; surface-treated glass fibers (B) surface-treated with a sizing agent including 0.01 to 1 pt.mass of a silane coupling agent based on 100 pts.mass of a sizing agent; and fine fibrous magnesium silicate (C), wherein the swelling laminar silicate (A), the surface-treated glass fibers (B), and the fine fibrous magnesium silicate (C) are compounded in amounts of 1 to 50 pts.mass, 5 to 150 pts.mass and 1 to 20 pts.mass, respectively, based on 100 pts.mass of the polyamide resin.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:提供一种增强的聚酰胺树脂组合物,其中使用玻璃纤维和膨胀层状硅酸盐来提高增强聚酰胺树脂组合物的机械性能,特别是拉伸强度。 解决方案:该聚酰胺树脂组合物包括:基于100质量份的膨胀层状硅酸盐在层之间插入0.5至30磅脂肪族伯胺制备的溶胀层状硅酸盐(A) 表面处理过的玻璃纤维(B)用施胶剂进行表面处理,该施胶剂包括基于100粒度的上浆剂的0.01至1pt.mass的硅烷偶联剂; 和细纤维状硅酸镁(C),其中,膨胀层状硅酸盐(A),表面处理玻璃纤维(B)和细纤维状硅酸镁(C)的配合量为1〜50质量度,5 分别为100 pts.mass和1至20 pts.mass,基于100 pts.mass的聚酰胺树脂。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Glass fiber-reinforced polyamide resin composition
    • 玻璃纤维增​​强聚酰胺树脂组合物
    • JP2009035593A
    • 2009-02-19
    • JP2007199120
    • 2007-07-31
    • Unitika Ltdユニチカ株式会社
    • KATAHIRA SHINICHIROFUJII SHIGETA
    • C08L77/00C08G69/04C08K9/04C08K9/06
    • PROBLEM TO BE SOLVED: To provide a reinforced polyamide resin composition in which both glass fibers and a swelling laminar silicate are used to improve the mechanical properties, especially tensile strength, of the reinforced polyamide resin composition.
      SOLUTION: This polyamide resin composition comprises: a swelling laminar silicate (A) prepared by inserting 0.5 to 30 pts.mass of an aliphatic primary amine between the layers based on 100 pts.mass of a swelling laminar silicate; and surface-treated glass fibers (B) surface-treated with a sizing agent including 0.01 to 1 pt.mass of a silane coupling agent based on 100 pts.mass of the glass fibers, wherein 100 pts.mass of a polyamide resin composition (C) prepared by mixing 100 pts.mass of a polyamide monomer, 0.5 to 20 pts.mass of the swelling laminar silicate (A), and 0 to 20 pts.mass of pure water and then polymerizing the polyamide monomer and 5-200 pts.mass of the surface-treated glass fibers (B) are compounded.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:提供一种增强的聚酰胺树脂组合物,其中使用玻璃纤维和膨胀层状硅酸盐来提高增强聚酰胺树脂组合物的机械性能,特别是拉伸强度。 解决方案:该聚酰胺树脂组合物包括:基于100质量份的膨胀层状硅酸盐在层之间插入0.5至30磅脂肪族伯胺制备的溶胀层状硅酸盐(A) 和表面处理过的玻璃纤维(B),其中上浆玻璃纤维(B)用基于100磅/平方米玻璃纤维的硅烷偶联剂0.01〜1pt.mass进行表面处理,其中聚酰胺树脂组合物100重量份( C)通过将100磅聚酰胺单体,0.5-20质量份的膨胀层状硅酸盐(A)和0至20份纯水混合,然后聚合聚酰胺单体和5-200份 将表面处理玻璃纤维(B)的质量配合。 版权所有(C)2009,JPO&INPIT
    • 10. 发明专利
    • Polyamide resin composition and method for producing the same
    • 聚酰胺树脂组合物及其制造方法
    • JP2008150400A
    • 2008-07-03
    • JP2006336445
    • 2006-12-14
    • Unitika Ltdユニチカ株式会社
    • KATAHIRA SHINICHIROFUJII SHIGETA
    • C08L77/00C08G69/04C08K3/04C08K3/34
    • PROBLEM TO BE SOLVED: To provide a resin composition making moldability, chemical resistance etc., of a polyamide resin united with dimensional stability thereof under high temperature conditions at high levels.
      SOLUTION: The polyamide resin composition comprises 100 pts.mass of a polyamide resin, 0.5-20 pts.mass of carbon particles wet treated with an acid solvent and having 1-20 mass% of mass loss ratio when heated from 25°C to 600°C in an inert gas atmosphere and 0.5-10 pts.mass of a swellable phyllosilicate. The polyamide resin composition is obtained by polymerizing a polyamide monomer in such a state that 100 pts.mass of the polyamide monomer coexists with 0.5-20 pts.mass of the carbon particles wet treated with the acid solvent and having 1-20 mass% of mass loss ratio when heated from 25°C to 600°C in the inert gas atmosphere and 0.5-10 pts.mass of the swellable phyllosilicate.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种在高温条件下以高水平结合其尺寸稳定性的聚酰胺树脂的成型性,耐化学性等的树脂组合物。 解决方案:聚酰胺树脂组合物包含聚酰胺树脂100质量份,用酸性溶剂湿润处理的0.5〜20质量%碳粒子,当从25℃加热时,其质量损失率为1-20质量% 在惰性气体气氛中为C至600℃,可溶胀的页硅酸盐为0.5-10磅。 聚酰胺树脂组合物通过聚酰胺单体的聚合获得,该聚酰胺单体的聚酰胺单体为100质量份,与酸性溶剂湿润处理的碳粒子的0.5〜20质量份共存,且1-20质量% 在惰性气体气氛中从25℃加热至600℃时的质量损失率为0.5-10质量%的可膨胀的页硅酸盐。 版权所有(C)2008,JPO&INPIT