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1. 发明专利

JP2014069447A Decorative sheet and decorative resin molded product 有权
标题翻译：装饰板和装饰树脂模制产品
公开(公告)号：JP2014069447A
公开(公告)日：2014-04-21
申请号：JP2012217395
申请日：2012-09-28
申请人： Dainippon Printing Co Ltd , 大日本印刷株式会社
发明人： AWA AI , AKO TAKAYOSHI , SAITO NOBUO
IPC分类号： B32B27/20 , B29C45/14 , B32B33/00
摘要： PROBLEM TO BE SOLVED: To provide a decorative sheet capable of having both excellent moldability and chemical resistance and a decorative resin molded product using the decorative sheet.SOLUTION: There is provided a decorative sheet having at least a surface protective layer formed of a cured product of a resin composition containing an ionizing radiation curable resin on a substrate layer, wherein the decorative sheet can be provided with both excellent moldability and chemical resistance by designing the cured product to have a resin hardness index defined in the specification of 4600 or more and incorporating acrylic beads into the cured product.
摘要翻译：要解决的问题：提供能够具有优异的成型性和耐化学性的装饰片和使用该装饰片的装饰性树脂成型体。解决方案：提供一种装饰片，其至少具有由固化物形成的表面保护层在基材层上含有电离辐射固化树脂的树脂组合物，其中通过将固化产物设计成具有4600或更高规格的树脂硬度指数，可以使装饰片具有优异的成型性和耐化学性，并结合丙烯酸珠进入固化产物。

2. 发明专利

JP2012166383A Decorative sheet and decorative resin molding using the same 有权
标题翻译：装饰板和装饰树脂使用相同的模具
公开(公告)号：JP2012166383A
公开(公告)日：2012-09-06
申请号：JP2011027491
申请日：2011-02-10
申请人： Dainippon Printing Co Ltd , 大日本印刷株式会社
发明人： TAKEUCHI EMI , SAITO NOBUO , AKO TAKAYOSHI
IPC分类号： B32B27/16 , B29C45/14 , B29L9/00 , B32B27/00
摘要： PROBLEM TO BE SOLVED: To provide a decorative sheet which gives moldability, designing property and excellent surface physical properties such as wear resistance and scratch resistance to a decorative resin molding and further which has excellent printing work efficiency (productivity) and to provide a decorative resin molding using the decorative sheet.SOLUTION: The decorative sheet has a surface protection layer which is composed of a material obtained by performing crosslinking curing of an ionizing radiation-curable resin composition on the printing film of a base material having at least a base film and the printing film. The decorative sheet is characterized in that modulus of bending elasticity of the printing film at 25°C is larger than that of the base film at 25°C. There is also provided the decorative resin molding using the decorative sheet.
摘要翻译：要解决的问题：提供一种装饰性片材，其赋予成型性，设计性能和优异的表面物理性能，例如耐装饰性树脂成型品的耐磨性和耐刮擦性，并且还具有优异的印刷工作效率（生产率），并提供使用该装饰片的装饰树脂成型品。解决方案：装饰片具有表面保护层，该表面保护层由通过在至少具有基膜的基材的印刷膜上进行电离辐射固化树脂组合物的交联固化而获得的材料和印刷膜。装饰片的特征在于，在25℃下，印刷膜的弯曲弹性模量比基底膜的弯曲弹性模量大25℃。还提供了使用装饰片的装饰树脂成型体。版权所有（C）2012，JPO＆INPIT

3. 发明专利

JP2014069446A Decorative sheet and decorative resin molded product 有权
标题翻译：装饰板和装饰树脂模制产品
公开(公告)号：JP2014069446A
公开(公告)日：2014-04-21
申请号：JP2012217393
申请日：2012-09-28
申请人： Dainippon Printing Co Ltd , 大日本印刷株式会社
发明人： AKO TAKAYOSHI , SAITO NOBUO
IPC分类号： B32B27/20 , B29C45/14 , B32B33/00
摘要： PROBLEM TO BE SOLVED: To provide a decorative sheet having designability with high texture and rich low-gloss feeling and excellent moldability, and to provide a decorative resin molded product using the decorative sheet.SOLUTION: There is provided a decorative sheet having at least a primer layer and a surface protective layer in order on a substrate layer, wherein the surface protective layer is formed from a cured product of an ionizing radiation-curable resin composition containing a matting agent and an ionizing radiation-curable resin and the decorative sheet can be provided with designability with high texture and rich low-gloss feeling and excellent moldability by blending synthetic resin particles in the primer layer.
摘要翻译：要解决的问题：提供具有高质感和丰富的低光泽感和优异成型性的可设计性的装饰片，并提供使用该装饰片的装饰性树脂模塑制品。解决方案：提供一种至少具有底涂层和表面保护层，其中表面保护层由包含消光剂和电离辐射固化树脂的电离辐射固化树脂组合物和装饰片的固化产物形成，可以是通过在底漆层中混合合成树脂颗粒，具有高质感和丰富的低光泽感和优异的成型性的可设计性。

4. 发明专利

JP2013082221A Decorative sheet and decorative resin molded article 有权
标题翻译：装饰板和装饰树脂模制品
公开(公告)号：JP2013082221A
公开(公告)日：2013-05-09
申请号：JP2012217394
申请日：2012-09-28
申请人： Dainippon Printing Co Ltd , 大日本印刷株式会社
发明人： AKO TAKAYOSHI , SAITO NOBUO
IPC分类号： B32B27/00 , B29C45/14 , B32B27/20
CPC分类号： B32B25/08 , B32B23/08 , B32B23/20 , B32B25/14 , B32B27/08 , B32B27/16 , B32B27/20 , B32B27/283 , B32B27/308 , B32B27/365 , B32B2250/02 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2264/025 , B32B2264/0264 , B32B2264/0292 , B32B2307/408 , B32B2307/412 , B32B2307/51 , B32B2307/584 , B32B2307/712 , B32B2307/714 , B32B2451/00 , B32B2605/00 , B32B2605/003 , B44C1/1712 , B44C1/175 , B44F1/00 , B44F9/02 , Y10T428/24868
摘要： PROBLEM TO BE SOLVED: To provide a decorative sheet and a decorative resin molded article which have few gloss change before and after decorative molding and have scratch resistance.SOLUTION: A substrate layer has at least a surface protective layer. The surface protective layer includes: at least one kind of synthetic resin particle selected from urethane beads, silicone beads, nylon beads, and acrylic beads; and a cured product of ionizing-radiation curable resin composition including an ionizing-radiation curable resin.
摘要翻译：要解决的问题：提供在装饰成型之前和之后几乎没有光泽变化并且具有耐划伤性的装饰片和装饰性树脂模塑制品。解决方案：基底层至少具有表面保护层。表面保护层包括：选自聚氨酯珠，硅氧烷珠，尼龙珠和丙烯酸珠中的至少一种合成树脂颗粒; 以及包含电离辐射固化树脂的电离辐射固化树脂组合物的固化产物。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2014069445A Decorative sheet and decorative resin molded product 审中-公开
标题翻译：装饰板和装饰树脂模制产品
公开(公告)号：JP2014069445A
公开(公告)日：2014-04-21
申请号：JP2012217392
申请日：2012-09-28
申请人： Dainippon Printing Co Ltd , 大日本印刷株式会社
发明人： AKO TAKAYOSHI , SAITO NOBUO
IPC分类号： B32B27/16 , B29C45/14 , B32B27/00 , B32B33/00
摘要： PROBLEM TO BE SOLVED: To provide a decorative sheet having designability with high texture and rich low-gloss feeling and excellent moldability, and to provide a decorative resin molded product using the decorative sheet.SOLUTION: There is provided a decorative sheet having at least a primer layer and a surface protective layer in order on a substrate layer, wherein the surface protective layer is formed from a cured product of an ionizing radiation-curable resin composition containing a matting agent and an ionizing radiation-curable resin and the decorative sheet can be provided with designability with high texture and rich low-gloss feeling and excellent moldability by blending hydrophobically treated silica particles in the primer layer.
摘要翻译：要解决的问题：提供具有高质感和丰富的低光泽感和优异成型性的可设计性的装饰片，并提供使用该装饰片的装饰性树脂模塑制品。解决方案：提供一种至少具有底涂层和表面保护层，其中表面保护层由包含消光剂和电离辐射固化树脂的电离辐射固化树脂组合物和装饰片的固化产物形成，可以是通过在底漆层中混合疏水处理的二氧化硅颗粒，具有高质感和丰富的低光泽感和优异的成型性。

6. 发明专利

JP2012153122A Decorative sheet and decorative resin molded product provided therewith 有权
标题翻译：装饰用品和装饰树脂模制产品
公开(公告)号：JP2012153122A
公开(公告)日：2012-08-16
申请号：JP2011016874
申请日：2011-01-28
申请人： Dainippon Printing Co Ltd , 大日本印刷株式会社
发明人： AKO TAKAYOSHI , TAKEUCHI EMI , SAITO NOBUO
IPC分类号： B32B33/00 , B32B27/30
摘要： PROBLEM TO BE SOLVED: To provide a decorative sheet which has excellent three-dimensional formability, and imparts excellent scratch resistance, chemical resistance, and a high design to a decorative resin molded product, and the decorative resin molded product provided therewith.SOLUTION: The decorative sheet 10 includes a second pattern layer 15 which is partially arranged on a base material film layer 11, and a surface protective layer 16 which exists on and is in contact with the second pattern layer 15 and covers the entire surface including an area in which the second pattern layer 15 is formed and the other area in which the second pattern layer is not formed. A binder resin of a second pattern ink which forms the second pattern layer 15 is a thermoplastic resin, and the surface protective layer is formed by crosslinking and curling an ionization radiation-curable resin composition including a specified acrylate as an ionization radiation-curable resin. In the surface protective layer 16, a low glossy pattern layer 17 having a low gloss area is formed immediately above the second pattern layer 15 by interaction between the ionization radiation-curable resin and the thermoplastic resin.
摘要翻译：要解决的问题：提供一种具有优异的三维成型性，赋予装饰性树脂成型体的耐刮擦性，耐化学性，高设计性的装饰性片材，以及具有该装饰性树脂成型体的装饰性片材。解决方案：装饰片10包括部分地布置在基材膜层11上的第二图案层15和存在于第二图案层15上并与第二图案层15接触并覆盖整个的表面保护层16 表面包括形成第二图案层15的区域和不形成第二图案层的另一区域。形成第二图案层15的第二图案油墨的粘结剂树脂是热塑性树脂，并且表面保护层通过将包含特定丙烯酸酯的电离辐射固化树脂组合物交联并卷曲而形成为电离辐射固化树脂。在表面保护层16中，通过电离辐射固化树脂和热塑性树脂之间的相互作用，在第二图案层15的正上方形成具有低光泽面积的低光泽图案层17。版权所有（C）2012，JPO＆INPIT

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