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    • 2. 发明专利
    • Additive for thermoplastic resin
    • 添加剂用于热塑性树脂
    • JP2010070647A
    • 2010-04-02
    • JP2008239677
    • 2008-09-18
    • Unitika Ltdユニチカ株式会社
    • ITO AKIRAFURUKAWA MIKIOYAMAMURA KIYOHIKO
    • C08L101/00C08K5/17C08K5/3492
    • PROBLEM TO BE SOLVED: To provide an additive for a thermoplastic resin excellent in heat stability during process at high temperatures, never vaporizing even when compounded at a temperature higher than the melting temperature of the resin, and efficiently functioning when compounded into the resin. SOLUTION: This additive for the thermoplastic resin comprises an allyl compound obtained by mixing and heating a primary amine compound represented by the following formula (1): R-(NH 2 ) n and a polyfunctional compound having an allyl group and a glycidyl group. In the formula (1), n=1-4, R represents 1-4 aromatic or aliphatic residual substituents. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供高温加工时的热稳定性优异的热塑性树脂添加剂,即使在高于树脂的熔融温度的温度下复合也不会蒸发,并且在配合到 树脂。 解决方案:该热塑性树脂添加剂包括通过混合并加热由下式(1)表示的伯胺化合物获得的烯丙基化合物:R-(NH 2 SBB) 和具有烯丙基和缩水甘油基的多官能化合物。 在式(1)中,n = 1-4,R表示1-4个芳族或脂族残基取代基。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Polylactic acid stereocomplex molded item and its manufacturing method
    • 聚酯酸立方体成型项目及其制造方法
    • JP2008163111A
    • 2008-07-17
    • JP2006352205
    • 2006-12-27
    • Unitika Ltdユニチカ株式会社
    • YAMAMURA KIYOHIKOITO AKIRAUEDA KAZUE
    • C08J5/00C08L67/04C08L101/16
    • PROBLEM TO BE SOLVED: To provide a polylactic acid stereocomplex molded item which is transparent and is excellent in heat resistance, and its manufacturing method.
      SOLUTION: The molded item is obtained by molding a polylactic acid stereocomplex comprised of a crystalline poly-L-lactic acid and a crystalline poly-D-lactic acid, and has a crystalline heat of fusion of at least 20 J/g at 190°C or higher which accounts for at least 90% of the whole crystalline heat of fusion, a melting point derived from the stereocomplex within 205-240°C, a heat distortion temperature under a load of 0.98 MPa of 120°C or higher and a haze of at most 45% as measured with a thickness of 3 mm.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供透明且耐热性优异的聚乳酸立体络合物成型体及其制造方法。 解决方案:通过模制由结晶聚-L-乳酸和结晶聚-D-乳酸组成的聚乳酸立体络合物获得模制品,并且具有至少20J / g的结晶热 在190℃以上,占整个结晶热的至少90%,来自立体复合物的熔点为205-240℃,负荷为0.98MPa的热变形温度为120℃,或 较高,雾度最高为45%,厚度为3mm。 版权所有(C)2008,JPO&INPIT
    • 4. 发明专利
    • Heat sink
    • 散热器
    • JP2014093427A
    • 2014-05-19
    • JP2012243222
    • 2012-11-05
    • Unitika Ltdユニチカ株式会社
    • ITO AKIRAMASAI YUYAKAIBARA SUSUMUFURUKAWA MIKIO
    • H05K7/20C08K3/00C08L67/00C08L77/00C08L93/04C08L101/16F21S2/00F21V29/00
    • PROBLEM TO BE SOLVED: To provide a heat sink that maintains a mechanical characteristic, prevents bleed-out, ensures molding with satisfactory processability, is lightweight and excellent in heat dissipation.SOLUTION: In a heat sink containing molded body formed from molding a thermoplastic resin composition. The thermoplastic resin composition containing (A) thermoplastic resin, (B) filler of heat conductivity of not lower than 5 W/(m K), and (C) rosin. The thermoplastic resin (A) is (A1) polyamide resin, (A2) aliphatic polyester resin, or (A3) semi-aromatic polyester resin. The volume ratio (A/B) of the thermoplastic resin (A) to filler (B) is 80/20 to 25/75. The content of (C) rosin with respect to 100 parts by mass of the total of thermoplastic resin (A) and filler (B) is 0.3 to 5 parts by mass. The acid number of the rosin (C) is 60 mgKOH/g or greater.
    • 要解决的问题:为了提供一种保持机械特性的散热器,防止渗出,确保成型具有令人满意的加工性,重量轻且散热性优异。解决方案:在包含由热塑性树脂成型而形成的成型体的散热片 组成。 含有(A)热塑性树脂,(B)导热率不低于5W /(m K)的填料和(C)松香的热塑性树脂组合物。 热塑性树脂(A)为(A1)聚酰胺树脂,(A2)脂肪族聚酯树脂或(A3)半芳香族聚酯树脂。 热塑性树脂(A)与填料(B)的体积比(A / B)为80/20〜25/75。 (C)松香相对于热塑性树脂(A)和填料(B)的总量100质量份的含量为0.3〜5质量份。 松香(C)的酸值为60mgKOH / g以上。
    • 5. 发明专利
    • Resin composition and molded article comprising the same
    • 树脂组合物和包含其的成型制品
    • JP2013159624A
    • 2013-08-19
    • JP2012019866
    • 2012-02-01
    • Unitika Ltdユニチカ株式会社
    • KAIHARA OSAMUITO AKIRAMASAI YUYAFURUKAWA MIKIO
    • C08L101/00C08K3/00C08K5/01C08K5/098C08L77/08C08L93/04
    • PROBLEM TO BE SOLVED: To provide a resin composition excellent in thermal conductivity, and excellent in melt flowability when molded.SOLUTION: A resin composition includes a thermoplastic resin (A), a filler (B), a predetermined amount of a melt viscosity reducing agent (C), and a fatty acid metal salt (D), wherein 0.1-5 pts.mass of (D) is contained in the resin composition per 100 pts.mass of total amount of (A), (B) and (C), and (C) is any one selected from a group comprising following (1)-(3). (1) (C) is a polyfunctional allyl compound (C1), and the content of (C1) is 3-20 pts.vol. with respect to 100 pts.vol. of the total amount of (A), (B) and (C1). (2) (C) is a dimer acid-based thermoplastic resin (C2), and the content of (C2) is 5-35 pts.vol. with respect to 100 pts.vol. of the total amount of (A), (B) and (C2). (3) Rosin (C3) in which an acid value of (C) is 60 mgKOH/g or more, and the content of (C3) is 0.5-11 pts.vol. with respect to 100 pts.vol. of the total amount of (A), (B) and (C3).
    • 要解决的问题:提供导热性优异,成型时熔融流动性优异的树脂组合物。溶液:树脂组合物包含热塑性树脂(A),填料(B),预定量的熔体粘度降低 (C)和脂肪酸金属盐(D),其中,(A),(B)和(B)和(B)的总量每100重量份,树脂组合物中含有0.1-5重量份的(D) C)和(C)是选自以下(1) - (3)的组中的任一种。 (1)(C)是多官能烯丙基化合物(C1),(C1)的含量为3-20点。 相对于100 pts.vol。 (A),(B)和(C1)的总量。 (2)(C)是二聚酸类热塑性树脂(C2),(C2)的含量为5-35重量份。 相对于100 pts.vol。 (A),(B)和(C2)的总量。 (3)(C)的酸值为60mgKOH / g以上,(C3)的含量为0.5〜11份的松香(C3)。 相对于100 pts.vol。 (A),(B)和(C3)的总量。
    • 7. 发明专利
    • Resin composition, and molding formed thereof
    • 树脂组合物及其成型
    • JP2013028661A
    • 2013-02-07
    • JP2011163787
    • 2011-07-27
    • Unitika Ltdユニチカ株式会社
    • MASAI YUYAITO AKIRAKAIHARA OSAMUFURUKAWA MIKIO
    • C08L101/00C08K3/00C08K5/3492C08L67/00C08L77/00
    • PROBLEM TO BE SOLVED: To provide a resin composition excellent in heat conductivity not only in the plane direction but in the thickness direction, and maintaining molding processability and strength, and to provide a molding formed thereof.SOLUTION: The resin composition contains a thermoplastic resin (A), a heat conductive filler (B), a fluidity improver (C), and a three-dimensional acicular metal oxide (D), and (C) is the following (a) or (b), and the content of (D) is 10 to 50 vol% to the total of (B) and (D). (a) A fluidity improver (C) is a polyfunctional allyl compound (C1), and the content is 3 to 20 vol% based on the total of (A), (B), (C) and (D). (b) A fluidity improver (C) is a dimmer acid-based thermoplastic resin (C2), and the content is 5 to 35 vol% based on the total of (A), (B), (C) and (D).
    • 待解决的问题:为了提供不仅在平面方向上而且在厚度方向上的导热性优异且保持成型加工性和强度的树脂组合物,并且提供由其形成的模制品。 解决方案:树脂组合物含有热塑性树脂(A),导热性填料(B),流动性改进剂(C)和三维针状金属氧化物(D),(C)为以下 (A)或(b),(D)的含量相对于(B)和(D)的总量为10〜50体积%。 (a)流动性改进剂(C)为多官能烯丙基化合物(C1),相对于(A),(B),(C)和(D)的总和,含量为3〜20体积%。 (b)流动性改进剂(C)为二聚酸类热塑性树脂(C2),相对于(A),(B),(C)和(D)的总和,含量为5〜35体积% 。 版权所有(C)2013,JPO&INPIT
    • 9. 发明专利
    • Molded article
    • 模制品
    • JP2012193370A
    • 2012-10-11
    • JP2012132442
    • 2012-06-12
    • Unitika Ltdユニチカ株式会社
    • ITO AKIRAUEDA KAZUEMATSUMOTO TATSUYAMASAKI TATSUNORIYAMAMURA KIYOHIKO
    • C08L67/04C08K5/1515C08K5/29C08K5/353C08L63/00C08L69/00C08L101/16
    • C08L69/00C08K5/1515C08K5/29C08K5/353C08L23/0884C08L67/04Y10T428/254C08L2666/18C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a molded article which is low in the degree of dependence on petroleum products, and is excellent in surface appearance in addition to heat resistance, impact resistance and durability.SOLUTION: The molded article is obtained by molding a resin composition including a polylactic acid resin (A) and a polycarbonate resin (B), and having a mass ratio (A/B) of the polylactic acid resin (A) to the polycarbonate resin (B) of 40/60 to 80/20 and a ratio (MFR/MFR) of the melt flow rate of the polylactic acid resin (A) (MFR) to that of the polycarbonate resin (B) (MFR) at 240°C, 21.2N load of 20-600. Particles of the polycarbonate resin (B) are dispersed in the polylactic acid resin (A) in a range from the surface of the molded article to a depth 5 μm, and the length of dispersed particle cross sections observed in a cross section of the molded article is 0.1 μm or more.
    • 要解决的问题:提供一种对石油产品的依赖度低的成型品,除了耐热性,耐冲击性和耐久性外,表面外观也优异。 解决方案:模塑制品通过将包含聚乳酸树脂(A)和聚碳酸酯树脂(B)的树脂组合物成型,并将聚乳酸树脂(A)的质量比(A / B)与 40/60至80/20的聚碳酸酯树脂(B)和比例(MFR A / MFR B ) 聚乳酸树脂(A)的熔体流动速率(MFR A )与聚碳酸酯树脂(B)的熔体流动速率(MFR B )在240℃,21.2N负载为20-600。 聚碳酸酯树脂(B)的颗粒在从模制品的表面到5μm深度的范围内分散在聚乳酸树脂(A)中,并且在模制品的横截面中观察到分散的颗粒横截面的长度 制品为0.1μm以上。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Biological treatment carrier
    • 生物处理载体
    • JP2007283222A
    • 2007-11-01
    • JP2006113928
    • 2006-04-18
    • Unitika Ltdユニチカ株式会社
    • UEDA KAZUEMATSUMOTO TATSUYAITO AKIRAYAMAMURA KIYOHIKOCHIGUSA TAKEMICHISHINOHARA REIKO
    • C02F3/10
    • Y02W10/15
    • PROBLEM TO BE SOLVED: To provide a granular biological treatment carrier which has durability, can be properly floated in an aeration tank, can be utilized in the adhesion of microorganisms at a low cost and is enhanced in sewage purifying capacity. SOLUTION: The biological treatment carrier is constituted of a particulate material comprising a thermoplastic resin having pores with a diameter of 0.1-100 μm and has an apparent density of 0.5-1.5 g/ml and manufactured by forming a granular material, which is obtained by melting and kneading a thermoplastic resin and a particulate inorganic compound, treating the granular material with a solvent, which dissolves the inorganic material but not dissolves the thermoplastic resin, to remove the inorganic material from the granular material and forming pores to the parts where the inorganic compound is not present. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供具有耐久性的颗粒状生物处理载体,可以适当地漂浮在曝气池中,可以以低成本利用微生物的粘附,并提高污水净化能力。 解决方案:生物处理载体由包含直径为0.1-100μm的孔的热塑性树脂和表观密度为0.5-1.5g / ml的颗粒材料构成,并通过形成颗粒状材料制成, 通过熔融和捏合热塑性树脂和颗粒状无机化合物,用能够溶解无机材料但不溶解热塑性树脂的溶剂处理颗粒材料,从颗粒状材料中除去无机材料并在该部件上形成孔 其中无机化合物不存在。 版权所有(C)2008,JPO&INPIT