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    • 1. 发明专利
    • Fuel-low-permeable block copolymer
    • 燃料低渗透性嵌段共聚物
    • JP2009256658A
    • 2009-11-05
    • JP2009074661
    • 2009-03-25
    • Daikin Ind Ltdダイキン工業株式会社
    • FUKUOKA SHOJIWASHINO KEIKONISHII HIDEMIKISHINE MITSURU
    • C08F293/00C08K5/14C08K5/3477C08L53/00
    • PROBLEM TO BE SOLVED: To provide a block copolymer and a composition for peroxide vulcanization, both maintaining the cold resistance of a cold-resistant fluorine-containing rubber and exhibiting a hardness as low as possible and an excellent fuel-low-permeability; and automobile parts of fuel systems prepared by molding the composition.
      SOLUTION: The block copolymer only consists of: a fluorine-containing elastomer segment (A) having a composition which has either (1) the composition ratio of a vinylidene fluoride/perfluoroalkyl vinyl ether copolymer being 50-85/15-50 mol% or (2) the composition ratio of a vinylidene fluoride/tetrafluoroethylene/perfluoroalkyl vinyl ether being 45-85/1-30/14-30 mol%; and a fluorine-containing resin segment (B) melt-moldable with the fluorine-containing elastomer segment (A). The block copolymer has iodine atoms and can be vulcanized with a peroxide.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供一种用于过氧化物硫化的嵌段共聚物和组合物,既保持耐寒含氟橡胶的耐寒性并且显示尽可能低的硬度,并且具有优异的低燃料低渗透性 ; 以及通过模制组合物制备的燃料系统的汽车部件。 解决方案:嵌段共聚物仅由以下组成的含氟弹性体链段(A)组成:(1)偏二氟乙烯/全氟烷基乙烯基醚共聚物的组成比为50-85 / 15-50 摩尔%或(2)偏二氟乙烯/四氟乙烯/全氟烷基乙烯基醚的组成比为45-85 / 1-30 / 14-30摩尔%; 和含氟弹性体链段(A)可熔融成型的含氟树脂链段(B)。 嵌段共聚物具有碘原子并且可以用过氧化物硫化。 版权所有(C)2010,JPO&INPIT
    • 2. 发明专利
    • Curable composition and molded article made of the same
    • 可固化组合物及其制品
    • JP2014074185A
    • 2014-04-24
    • JP2014012643
    • 2014-01-27
    • Daikin Ind Ltdダイキン工業株式会社
    • WASHINO KEIKOFUKUOKA SHOJIOTA DAISUKEKISHINE MITSURU
    • C08L27/16C08K5/21
    • C09K3/1009C08K5/16C08L27/16
    • PROBLEM TO BE SOLVED: To provide a curable composition of a vinylidene fluoride elastomer, assuring improved crosslinking speed by using an inexpensive curing agent, and to provide a molded article obtained from the curable composition, wherein physical properties under normal conditions are improved by the coexistence of a solvent having affinity for a compound generating ammonia.SOLUTION: A curable composition comprises (A) a vinylidene fluoride elastomer which is a copolymer of vinylidene fluoride (a1), at least one perfluoroolefin (a2) selected from the group consisting of tetrafluoroethylene, hexafluoropropylene and perfluoro(alkyl vinyl ether) and a cyano group-containing monomer (a3) (provided that a copolymerization rate of the vinylidene fluoride exceeds 20% by mole), and (B) a compound generating ammonia at 40 to 330°C alone as a curing agent.
    • 要解决的问题:提供一种偏二氟乙烯弹性体的固化性组合物,通过使用便宜的固化剂确保改善的交联速度,并提供由可固化组合物获得的模制品,其中在正常条件下通过共存提高物理性能 对于产生氨的化合物具有亲和性的溶剂。溶解性:可固化组合物包含(A)偏二氟乙烯弹性体,其是偏二氟乙烯(a1),至少一种全氟烯烃(a2)的共聚物,选自四氟乙烯, 六氟丙烯和全氟(烷基乙烯基醚)和含氰基单体(a3)(偏二氟乙烯的共聚比例超过20摩尔%),(B)仅在40〜330℃产生氨的化合物 作为固化剂。
    • 3. 发明专利
    • Method for producing vulcanizable fluorine-containing elastomer
    • 用于生产含氟化的含氟弹性体的方法
    • JP2006036861A
    • 2006-02-09
    • JP2004216323
    • 2004-07-23
    • Daikin Ind Ltdダイキン工業株式会社
    • WASHINO KEIKONISHIMURA YOSUKEIRIE MASAKIKISHINE MITSURU
    • C08F214/18C08F2/38F16J15/20
    • PROBLEM TO BE SOLVED: To provide a method for producing a fluorine-containing elastomer by which the polymerization rate is extremely increased regardless of a small amount of a polymerization initiator by carrying out an iodine transfer polymerization under high pressure, and which has high productivity equal to a method not using the iodine transfer polymerization; and to provide the fluorine-containing elastomer produced by the method. SOLUTION: The method for producing the fluorine-containing elastomer by a batch-type copolymerization method carried out under a condition of ≥0.95 reduced temperature and ≥0.80 reduced pressure of critical constants calculated by using a Peng-Robinson equation from the critical temperature and the critical pressure of each monomer in the vapor phase part in a reaction vessel, and a composition ratio thereof involves copolymerizing an ethylenically unsaturated compound containing at least one kind of a fluoroolefin and a compound represented by general formula (2) and/or a compound represented by general formula (3): CF 2 =CF(CX 1 X 2 ) p (CX 3 X 4 ) q I in the presence of an iodine compound represented by general formula (1): R f 1 ×I X . COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供一种制备含氟弹性体的方法,通过在高压下进行碘转移聚合,聚合速率极大地提高,而不管少量的聚合引发剂,聚合速率是高的 高生产率等于不使用碘转移聚合的方法; 并提供通过该方法制备的含氟弹性体。 解决方案:通过间歇式共聚方法制备含氟弹性体的方法,其在≥0.95降低的温度和≥0.80的关键常数降低的压力下进行,所述临界常数通过使用来自临界的Peng-Robinson方程计算 温度和反应容器中气相部分中各单体的临界压力,其组成比包括使含有至少一种氟代烯烃的烯属不饱和化合物与通式(2)表示的化合物和/或 由通式(3)表示的化合物:CF 2 SB 2 = CF(CX 1 X 2 在通式(1)表示的碘化合物存在下,将CX 3 X 4 SB> 1 ×I X 。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Fixing roll and fixing belt
    • 固定滚筒和固定皮带
    • JP2013068748A
    • 2013-04-18
    • JP2011206529
    • 2011-09-21
    • Daikin Ind Ltdダイキン工業株式会社
    • WASHINO KEIKOYANAGIGUCHI TOMIHIKO
    • G03G15/20
    • PROBLEM TO BE SOLVED: To provide a fixing roll having excellent abrasion resistance.SOLUTION: There is provided a fixing roll 1 comprising a substrate and a fluorine-containing elastomer surface layer obtained by crosslinking a curable composition, wherein the curable compound contains at least one selected from the group consisting of (A) a non-perfluoro elastomer, (B) a curing agent, (C) a compound generating ammonia at 40 to 330°C and (F) inorganic nitride particles, (A1) the vinylidene fluoride-based elastomer is a copolymer of (a2) a perfluoro olefin and (a3) a monomer containing a cyano group, a carboxyl group or an alkoxycarbonyl group, and (A2) the tetrafluoroethylene-propylene based elastomer is a copolymer of tetrafluoroethylene, propylene and a monomer containing a cyano group, a carboxyl group or an alkoxycarbonyl group.
    • 要解决的问题:提供具有优异耐磨性的定影辊。 解决方案:提供了一种定影辊1,其包括基材和通过使可固化组合物交联获得的含氟弹性体表面层,其中可固化化合物包含选自(A)非离子表面活性剂中的至少一种, 全氟弹性体,(B)固化剂,(C)在40〜330℃产生氨的化合物和(F)无机氮化物粒子,(A1)所述偏二氟乙烯类弹性体是(a2)全氟烯烃 和(a3)含有氰基,羧基或烷氧基羰基的单体,(A2)四氟乙烯 - 丙烯类弹性体是四氟乙烯,丙烯和含有氰基,羧基或烷氧基羰基的单体的共聚物 组。 版权所有(C)2013,JPO&INPIT
    • 5. 发明专利
    • Fluoroalkyl carboxylic acid derivative, method for producing fluorine-containing polymer, and aqueous dispersion of fluorine-containing polymer
    • 氟代烷基羧酸衍生物,含氟聚合物的制备方法和含氟聚合物的分散体
    • JP2005036002A
    • 2005-02-10
    • JP2004197178
    • 2004-07-02
    • Daikin Ind Ltdダイキン工業株式会社
    • MORITA SHIGERUTANAKA YOSHIKIWASHINO KEIKOTSUDA NOBUHIKOKISHINE MITSURU
    • C07C59/135C07C51/04C08F2/26C08K5/09C08L27/12
    • PROBLEM TO BE SOLVED: To provide a compound which can be preferably used as a surfactant, and a method for producing a fluorine-containing polymer, a surfactant and an aqueous dispersion of a fluorine-containing polymer using the same. SOLUTION: The fluoroalkyl carboxylic acid derivative is represented by the general formula : Rf 1 (OCH 2 CF 2 CF 2 ) n1 OCX 1 X 2 CF 2 (Rf 2 ) n2 COOM. (In the formula Rf 1 represents a straight chain or branched fluoroalkyl group having 1-20 carbon atoms, wherein fluoroalkyl group may have 1-5 oxygen atoms in the main chain; Rf 2 represents a straight chain or branched fluoroalkylene group having 1-25 carbon atoms, wherein fluoroalkylene group may have 1-5 oxygen atoms in the main chain; n1 is an integer of 0-3; n2 is 0 or 1; X 1 and X 2 may be the same or different, and represent hydrogen atoms or fluorine atoms; and M represents NH 4 or a monovalent metal element). COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供可以优选用作表面活性剂的化合物,以及使用其的含氟聚合物,表面活性剂和含水聚合物的水分散体的制备方法。 解决方案:氟代烷基羧酸衍生物由以下通式表示:Rf 1(OCH 2 SB 2)/(CF 2) N1 OCX 1 X 2 CF 2 (RF 2 N2 COOM。 (式中,Rf 1表示具有1-20个碳原子的直链或支链氟代烷基,其中氟代烷基可以在主链中具有1-5个氧原子; Rf 2 < SP>表示具有1-25个碳原子的直链或支链氟代亚烷基,其中氟亚烷基可以在主链中具有1-5个氧原子; n1是0-3的整数; n2是0或1; X 1 和X 2可以相同或不同,表示氢原子或氟原子; M表示NH 4 或一价金属元素)。 版权所有(C)2005,JPO&NCIPI
    • 7. 发明专利
    • Method for producing vulcanizable fluorine-containing elastomer
    • 用于生产含氟化的含氟弹性体的方法
    • JP2006036860A
    • 2006-02-09
    • JP2004216322
    • 2004-07-23
    • Daikin Ind Ltdダイキン工業株式会社
    • NISHIMURA YOSUKEWASHINO KEIKOIRIE MASAKIKISHINE MITSURU
    • C08F2/38C08F14/22F16J15/20
    • PROBLEM TO BE SOLVED: To provide a method for producing a fluorine-containing elastomer by which the polymerization rate is extremely increased regardless of a small amount of a polymerization initiator by carrying out an iodine transfer polymerization under high pressure, and which has high productivity equal to a method not using the iodine transfer polymerization; and to provide the fluorine-containing elastomer produced by the method. SOLUTION: The method for producing the fluorine-containing elastomer by a batch-type copolymerization method, carried out under a condition of ≥0.95 reduced temperature and ≥0.80 reduced pressure of critical constants calculated by using a Peng-Robinson equation from the critical temperature and the critical pressure of each monomer in the vapor phase part in a reaction vessel, and a composition ratio thereof, involves copolymerizing an ethylenically unsaturated compound containing at least one kind of a fluoroolefin and a compound represented by general formula (2): CH 2 =CH(CF 2 ) n I in the presence of an iodine compound represented by general formula (1): R f 1 ×I X . COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供一种制备含氟弹性体的方法,通过在高压下进行碘转移聚合,聚合速率极大地提高,而不管少量的聚合引发剂,聚合速率是高的 高生产率等于不使用碘转移聚合的方法; 并提供通过该方法制备的含氟弹性体。 解决方案:通过间歇式共聚法制备含氟弹性体的方法,在≥0.95降温和≥0.80减压下的临界常数降压条件下进行,该方法使用Peng-Robinson方程 临界温度和反应容器中气相部分中各单体的临界压力及其组成比包括使包含至少一种氟代烯烃的烯键式不饱和化合物与通式(2)表示的化合物进行共聚: 在通式(1)表示的碘化合物存在下,通式(1)表示的化合物:R = CH(CF 2 ˚F 1 ×I X 。 版权所有(C)2006,JPO&NCIPI