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    • 1. 发明专利
    • Tin alloy used for replenishing stannous ions, method for replenishing stannous ions using it, and electrolytic tin-plating method
    • 用于补充稳定离子的钛合金,使用它来补偿稳定离子的方法和电解镀锌方法
    • JP2006299369A
    • 2006-11-02
    • JP2005125817
    • 2005-04-22
    • Daiki Engineering KkKoji Hashimoto大機エンジニアリング株式会社功二 橋本
    • HASHIMOTO KOJIKATO YOSHIHIROKUMAGAI NAOKAZU
    • C25D21/14C22C13/00C25D3/30
    • PROBLEM TO BE SOLVED: To provide a tin alloy used for replenishing stannous ions, which relates to improvement in a technology of manufacturing a tin-plated steel sheet with an electrolytic tin-plating method using an insoluble anode, and can quickly replenish the stannous ions that are consumed during plating, to provide a method for replenishing the stannous ions with the use of the tin alloy, and to further provide the electrolytic tin-plating method adopting the method for replenishing the stannous ions.
      SOLUTION: The tin alloy for replenishing the stannous ions comprises a parent phase of tin and a phase of tin phosphide Sn
      4 P
      3 , and includes phosphor in an amount of 0.1 to 10 atom%. The tin phosphide phase has high oxygen-reducing capability and acts as a cathode. On the other hand, the parent phase of tin acts as an anode. When the tin alloy is immersed in water and an oxygen gas is blown therein, tin easily elutes as an ion. The electrolytic tin-plating method adopting the method for replenishing the stannous ions can plate a steel sheet while avoiding the formation of insoluble tin dioxide.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供用于补充亚锡离子的锡合金,其涉及使用不溶性阳极的电解镀锡法制造镀锡钢板的技术的改进,并且可以快速补充 在电镀期间消耗的亚锡离子,提供使用锡合金补充亚锡离子的方法,并进一步提供采用补充亚锡离子的方法的电解镀锡方法。 解决方案:用于补充亚锡离子的锡合金包括锡的母相和锡磷化合物Sn P 3 的相,并且包括量的磷光体 为0.1〜10原子%。 锡磷化物相具有较高的氧还原能力,可作为阴极。 另一方面,锡的母相作为阳极。 当锡合金浸入水中并在其中吹入氧气时,锡容易作为离子洗脱。 采用补充亚锡离子的方法的电解镀锡方法可以在避免形成不溶性二氧化锡的同时对钢板进行平板化。 版权所有(C)2007,JPO&INPIT
    • 2. 发明专利
    • Electrode for oxygen generation and method of manufacturing the same
    • 用于氧气生成的电极及其制造方法
    • JP2007138254A
    • 2007-06-07
    • JP2005334092
    • 2005-11-18
    • Daiki Engineering KkKoji Hashimoto大機エンジニアリング株式会社功二 橋本
    • HASHIMOTO KOJIEL-MONEIM AHMED AKUMAGAI NAOKAZU
    • C25B11/10C23F1/26C25B1/02C25B11/04C25D9/06
    • PROBLEM TO BE SOLVED: To provide a high activity long life electrode for oxygen generation which is used for electrolysis of an aqueous solution containing chlorine ion represented by sea water to generate oxygen while suppressing the generation of chlorine and has an intermediate layer containing platinum group metal oxide and formed on a titanium electrode substrate and a conductive coating film of Mn-Mo-W multiple oxide of an anode active material formed on the surface by an anode electrodeposition method and is capable of high oxygen generation efficiency even in the long period electrolysis at high curent density.
      SOLUTION: Before the intermediate layer is formed on the titanium electrode substrate, an oxide coating film on the surface is removed by treating with hydrofluoric acid and successively etched with concentrated sulfuric acid to enhance the surface roughness. Because the platinum group metal oxide forming the intermediate layer is entered into projecting and recessed parts produced on the surface of the titanium electrode substrate by the etching to increase the adhesiveness, the peeling of the anode active material from the electrode substrate is prevented to attain long electrode life.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:为了提供用于电解含有由海水表示的氯离子的水溶液产生氧而同时抑制氯的产生的用于产生氧气的高活性长寿命电极,并且具有包含 铂族金属氧化物,并且通过阳极电沉积法在钛电极基板上形成阳极活性物质的Mn-Mo-W多重氧化物的导电涂膜,并且即使在长时间内也能够产生高氧发生效率 高电解密度下的电解时间。 解决方案:在钛电极基板上形成中间层之前,通过用氢氟酸处理除去表面上的氧化物涂膜,并用浓硫酸连续蚀刻以提高表面粗糙度。 由于形成中间层的铂族金属氧化物通过蚀刻进入在钛电极基板的表面上产生的突起和凹陷部分以增加粘合性,所以防止阳极活性材料从电极基板剥离得到长时间 电极寿命。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Electrode for generating oxygen and manufacturing method therefor
    • 用于生成氧气的电极及其制造方法
    • JP2006233302A
    • 2006-09-07
    • JP2005052138
    • 2005-02-25
    • Daiki Engineering KkKoji Hashimoto大機エンジニアリング株式会社功二 橋本
    • HASHIMOTO KOJIKATO YOSHIHIROKUMAGAI NAOKAZUASAMI KATSUHIKO
    • C25B11/10C25B1/04C25B11/04C25D9/06
    • Y02E60/366
    • PROBLEM TO BE SOLVED: To provide an electrode that generates oxygen while inhibiting the generation of chlorine gas when used in the electrolysis of such an aqueous solution containing chlorine ions as is represented by seawater, has an intermediate layer containing an oxide of a metal in a platinum group formed on an electrode substrate of titanium, and an electroconductive coating made from a complex oxide of Mn-Mo, Mn-W or Mn-Mo-W, which is an anode active material, formed on the surface by an anodic electrodeposition technique, but contains a reduced amount of the oxide of the metal in the platinum group composing the intermediate layer.
      SOLUTION: The intermediate layer is formed from a mixture of the oxide of the metal (M) in the platinum group and the oxide of tungsten (W). An amount of each oxide is selected from the following range: 1×10
      -3 to 2×10
      -3 mol/m
      2 for M and 1×10
      -3 to 15×10
      -3 mol/m
      2 for W; or 2×10
      -3 to 10×10
      -3 mol/m
      2 for M and 0.1×10
      -3 to 15×10
      -3 mol/m
      2 for W, in terms of a metallic element per area of the intermediate layer.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:为了提供在用于电解含有如海水所表示的氯离子的水溶液时,产生氧气同时抑制氯气产生的电极,具有含有氧化物的中间层 形成在钛电极基板上的铂族金属和由Mn-Mo,Mn-W或Mn-Mo-W的复合氧化物制成的导电涂层,其是阳极活性材料,其表面由 阳极电沉积技术,但是在构成中间层的铂族中含有金属的氧化物的量减少。 解决方案:中间层由铂族金属(M)的氧化物与钨的氧化物(W)的混合物形成。 每个氧化物的量选自以下范围:对于M,1×10 -3 至2×10 -3 mol / m 2 对于W为1×10 -3 至15×10 -3 mol / m 2 或2×10 -3 至10×10 -3 mol / m 2 和0.1×10 -3 < 对于W,以中间层的每个面积的金属元素计,SP>至15×10 -3 mol / m 2 。 版权所有(C)2006,JPO&NCIPI
    • 5. 发明专利
    • Electrode for producing oxygen
    • 用于生产氧气的电极
    • JP2010059523A
    • 2010-03-18
    • JP2008229122
    • 2008-09-05
    • Daiki Ataka Engineering Co LtdKoji Hashimotoアタカ大機株式会社功二 橋本
    • HASHIMOTO KOJIKATO YOSHIHIROKUMAGAI NAOKAZU
    • C25B11/10C25B1/02C25B11/04C25B11/06C25D9/06
    • PROBLEM TO BE SOLVED: To provide an electrode for producing oxygen which has a low anode potential upon electrolysis, therefore, is an anode of energy-saving type having low power consumption and has a long life even when being used for a neutral or acidic electrolyte, in regard to the electrode for producing oxygen generating no chlorine and generating only oxygen in the electrolysis of an aqueous solution containing chlorine ion like sea water. SOLUTION: The electrode for producing oxygen has a structure formed by covering the surface prepared by applying an IrO 2 coating onto an electrode substrate made of Ti with an electrode inner layer (A) and an electrode outer layer (B) both of which are made of metal conjugate oxide in the order. The electrode inner layer (A) is made of one or two kinds of Sn, Sb, Mo and W, and Mn and, on the basis of atomic % for total cation, [one or two kinds of Sn+Sb+Mo and W] are in the range of 0.2 to 20%, wherein Sn is in the range of 0.1 to 3%, Sb is in the range of 0.01 to 1.3% and Mn has the remaining content. The electrode outer layer (B) is made of Sn, Mo and (or) W, and Mn and [one or two kinds of Sn+Mo and W] are in the range of 0.2 to 20%, wherein Sn is in the range of 0.1 to 3% and Mn has the remaining content. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供一种在电解时具有低阳极电位的氧气生产用电极,因此是具有低功耗的节能型阳极,即使用于中性,寿命长 或酸性电解质,用于生成不产生氧的氧的电极,并且在电解含有氯离子如海水的水溶液中仅产生氧。 解决方案:用于生产氧气的电极具有通过将由IrO SB SB2涂层施加的表面覆盖在由Ti制成的电极基底上而形成的结构,其中电极内层(A)和电极 外层(B),它们均由金属偶合氧化物按顺序制成。 电极内层(A)由一种或两种Sn,Sb,Mo和W以及Mn组成,并且基于总阳离子的原子%,[Sn + Sb + Mo和W的一种或两种 ]为0.2〜20%的范围,Sn为0.1〜3%,Sb为0.01〜1.3%,Mn为残留量。 电极外层(B)由Sn,Mo和(或)W制成,Mn和[一种或两种Sn + Mo和W]在0.2〜20%的范围内,其中Sn在 为0.1〜3%,Mn为余量。 版权所有(C)2010,JPO&INPIT
    • 6. 发明专利
    • Methanation method of hydrocarbon
    • 烃的甲烷化方法
    • JP2013119526A
    • 2013-06-17
    • JP2011267413
    • 2011-12-06
    • Daiki Ataka Engineering Co Ltdアタカ大機株式会社Koji Hashimoto功二 橋本
    • HASHIMOTO KOJITAKANO HIROYUKIKUMAGAI NAOKAZUIZUMIYA KOICHISHINOMIYA HIROYUKI
    • C07C4/06B01J23/755B01J37/18C07B61/00C07C4/18C07C9/04
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a method for improving a product yield and dispensing with separating higher-order hydrocarbons for combustion and disposal thereof, when natural gas obtained from a gas well is completely converted into methane by subjecting the natural gas containing hydrocarbons having two or more carbon atoms to hydrogenation treatment so as to be converted into pure methane, and the pure methane is required as a product.SOLUTION: A catalyst is used, in which an iron group element in the metal state is carried as an active species on a carrier which has a composition, in terms of atom% based on metals in the elemental state, comprising (A)18-70 atom% Zr, (B) 1-20 atom% one or two or more kinds (in the case of two or more kinds, the total) of tetragonal zirconia structure stabilizing elements (Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca, Mg), and (C) a 25-80 atom% iron element (in condition that Ni occupies an atom ratio of ≥0.6), and which is stabilized by taking even a part of the iron group element together with the stabilizing elements into a crystal structure; and mixed gas comprising natural gas and hydrogen is brought into contact with the catalyst, to thereby subject hydrocarbons having two or more carbon atoms to hydrocracking so as to be converted into methane.
    • 要解决的问题:为了提供一种提高产物产率并分配用于燃烧和处理的高级烃的分离方法,当从气井获得的天然气通过使含有 具有两个或更多个碳原子的烃进行氢化处理以转化为纯甲烷,纯甲烷作为产物。 解决方案:使用催化剂,其中金属状态的铁族元素作为活性物质载带在载体上,该载体具有以基于元素状态的金属为原子%的组成,其包含(A )18-70原子%Zr,(B)1-20原子%四方晶氧化锆结构稳定化元素(Y,La,Ce,Pr等)的一种或两种以上(总共为两种以上) Nd,Sm,Gd,Dy,Ca,Mg)和(C)25-80原子%的铁元素(在Ni占原子比≥0.6的条件下),并且通过将甚至一部分 铁族元素与稳定元素一起成晶体结构; 使包含天然气和氢气的混合气体与催化剂接触,从而使具有两个或更多个碳原子的烃加氢裂化,从而转化为甲烷。 版权所有(C)2013,JPO&INPIT
    • 7. 发明专利
    • Method of manufacturing methanation catalyst of carbon oxide, and methanation method using the catalyst
    • 氧化碳甲烷催化剂的制备方法和使用催化剂的甲烷化方法
    • JP2011206770A
    • 2011-10-20
    • JP2011124681
    • 2011-06-02
    • Daiki Ataka Engineering Co LtdKoji Hashimotoアタカ大機株式会社功二 橋本
    • HASHIMOTO KOJITAKANO HIROYUKIIZUMIYA KOICHIKUMAGAI NAOKAZUKATO YOSHIHIROSHINOMIYA HIROYUKI
    • B01J23/76B01J23/78B01J37/04B01J37/08B01J37/16C07B61/00C07C1/04C07C1/12C07C9/04
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide an improved method of manufacturing a methanation catalyst to be used for a methanation reaction for obtaining methane by reacting carbon dioxide, a mixture of carbon monoxide and carbon dioxide, or a mixture including them as a principal component, with hydrogen.SOLUTION: Hydrosol of Zr (A), a salt of one or two or more kinds of stabilizing element (B) selected from among Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg, and a salt of iron group element (C) are mixed, condensed, dried and baked to form a catalyst precursor. The catalyst precursor is reduced to obtain the catalyst. In this process, a chemical composition consists of A: 18-70%, B: 1-20%, C: 25-80% by atomic% on the basis of metals in element state. Thus, the catalyst is obtained by carrying the iron group element in a metal state on double oxide of a tetragonal zirconia structure stabilized by including a part of the iron group element as well as the stabilizing element into the crystal structure. The iron group element is Ni or one or two kinds of Ni, Fe and Co. Ni is contained by 0.6 or more of the total in atomic ratio.
    • 要解决的问题:提供一种制备甲烷化催化剂的改进方法,其用于通过使二氧化碳,一氧化碳和二氧化碳的混合物或其包含它们作为主要组分的混合物与甲烷化反应获得甲烷,与 氢.SOLUTION:Zr(A)的水溶胶,选自Y,La,Ce,Pr,Nd,Sm,Gd,Dy,Ca和Mg中的一种或两种以上的稳定化元素(B)的盐,以及 将铁族元素(C)的盐混合,浓缩,干燥并烘烤以形成催化剂前体。 催化剂前体被还原以获得催化剂。 在该方法中,化学组成由元素状态的金属的A:18-70%,B:1-20%,C:25-80%原子%组成。 因此,催化剂是通过将金属状态的铁族元素带入通过将一部分铁族元素以及稳定化元素包含在晶体结构中而稳定的四方晶氧化锆结构体的双氧化物上而得到的。 铁族元素为Ni或Ni,Fe,Ni中的一种或两种,Ni的原子比为0.6以上。
    • 8. 发明专利
    • Methanizing catalyst of carbonic oxide, its manufacturing method and methanizing method using methanizing catalyst
    • 氧化亚铁的甲基化催化剂,其制备方法和使用甲基化催化剂的甲基化方法
    • JP2010022944A
    • 2010-02-04
    • JP2008187970
    • 2008-07-18
    • Daiki Ataka Engineering Co LtdKoji Hashimotoアタカ大機株式会社功二 橋本
    • HASHIMOTO KOJITAKANO HIROYUKIIZUMIYA KOICHIKUMAGAI NAOKAZUKATO YOSHIHIROSHINOMIYA HIROYUKI
    • B01J23/76B01J23/78B01J37/04B01J37/08B01J37/18C07B61/00C07C1/02C07C1/12C07C9/04
    • PROBLEM TO BE SOLVED: To provide a catalyst used for methanizing reaction for reacting carbon dioxide, a mixture of carbon monoxide and carbon dioxide or a mixture based on them with hydrogen to obtain methane, and its manufacturing method. SOLUTION: A hydrosol of Zr (A), a salt of at least one kind of a stabilizing element (B) selected from Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg and a salt of an iron group element (C) are mixed and the resulting mixture is concentrated, dried up and baked to obtain a catalyst precursor. This catalyst precursor is subjected to reduction treatment to obtain the catalyst. At this time, a chemical composition consisting of A: 18-70%, B: 1-20% and C: 25-80% on an atomic% basis is set based on metals in an elemental state. By this method, the catalyst wherein the iron group element of a metal state is supported on a composite oxide of a tetragonal zirconia structure stabilized by taking a part of the iron group element in a crystal structure along with the stabilizing element is obtained. The iron group element is one or two kinds of Ni, Fe and Co, and Ni must occupy 0.6 or above as a whole in an atomic ratio. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供用于甲烷化反应的催化剂,其用于使二氧化碳,一氧化碳和二氧化碳的混合物或基于它们的混合物与氢气反应以获得甲烷,及其制造方法。 解决方案:选自Y,La,Ce,Pr,Nd,Sm,Gd,Dy,Ca和Mg中的至少一种稳定化元素(B)的盐的Zr(A)的水溶胶和 将铁族元素(C)的盐混合并将所得混合物浓缩,干燥并烘烤,得到催化剂前体。 对该催化剂前体进行还原处理,得到催化剂。 此时,以元素状态的金属为基准,设定以原子%为基准的A:18〜70%,B:1-20%,C:25〜80%的化学成分。 通过这种方法,获得了将金属状态的铁族元素负载在通过将一部分铁基元素与稳定化元素结合在晶体结构中而稳定化的四方晶氧化锆结构的复合氧化物上的催化剂。 铁族元素是Ni,Fe和Co中的一种或两种,并且Ni必须以原子比整体占据0.6以上。 版权所有(C)2010,JPO&INPIT
    • 9. 发明专利
    • Electrode for oxygen generation
    • 氧气发生电极
    • JP2007302927A
    • 2007-11-22
    • JP2006130892
    • 2006-05-09
    • Daiki Ataka Engineering Co LtdKoji Hashimotoアタカ大機株式会社功二 橋本
    • HASHIMOTO KOJIEL-MONEIM AHMED AKUMAGAI NAOKAZU
    • C25B11/10C25B11/16C25D9/06
    • C25B11/0484
    • PROBLEM TO BE SOLVED: To provide an electrode for oxygen generation which is capable of generating only oxygen while suppressing the generation of chlorine by electrolyzing a sodium chloride aqueous solution, wherein high performance and durability are ensured and the use amount of precious metal materials is reduced and the manufacturing cost is reduced to contribute to relieve the resources problem.
      SOLUTION: The electrode for oxygen generation is obtained by forming successively an intermediate layer and a layer of an electrode active material on a conductive base material. The intermediate layer having a composition comprising a multiple oxide of Sn, Sb and a platinum group metal, wherein the molar ratio Sn:Sb as cations is (1:1)-(40:1) and Sn and Sb occupy ≥90 mol% of the intermediate layer and the remaining is the oxide of the platinum group metal, is formed by a firing method. The layer of the electrode active material is formed by an anodic deposition method to produce the multiple oxide which comprises Sn occupying 0.1-3 mol% in cations, Mo and (/or) W occupying 0.2-20 mol% in cations and the balance the oxide of the platinum group metal.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种能产生氧气的氧气电极,同时通过电解氯化钠水溶液来抑制氯的产生,其中确保了高性能和耐久性以及贵金属的使用量 材料减少,制造成本降低,有助于减轻资源问题。 解决方案:用于产生氧气的电极是通过在导电性基材上连续形成中间层和电极活性物质层而获得的。 中间层具有包含Sn,Sb和铂族金属的多重氧化物的组成,其中作为阳离子的阳离子的摩尔比为(1:1) - (40:1),Sn和Sb占据≥90摩尔% 的中间层,剩余的是铂族金属的氧化物,通过烧成法形成。 通过阳极沉积法形成电极活性材料层,以产生包含Sn在阳离子中占据0.1-3mol%的多重氧化物,Mo和(/或)W在阳离子中占0.2-20mol%,余量为 铂族金属的氧化物。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Electrode for oxygen generation
    • 氧气发生电极
    • JP2007302925A
    • 2007-11-22
    • JP2006130890
    • 2006-05-09
    • Daiki Ataka Engineering Co LtdKoji Hashimotoアタカ大機株式会社功二 橋本
    • HASHIMOTO KOJIEL-MONEIM AHMED AKUMAGAI NAOKAZU
    • C25B11/10C25B1/02C25D9/06
    • C25B11/0484
    • PROBLEM TO BE SOLVED: To provide an anode for oxygen generation which is capable of generating only oxygen while suppressing the generation of chlorine by electrolyzing a sodium chloride aqueous solution, and has high performance and durability and in particular, capable of electrolyzing a strong acidic liquid in the same way as for a neutralized liquid.
      SOLUTION: The electrode is obtained by covering the surface of an electrode base body made from titanium with IrO
      2 and forming a multiple oxide comprising Mn-Mo-Sn, Mn-W-Sn or Mn-Mo-W-Sn as cation thereon using an anodic deposition method. The multiple oxide has a composition comprising Sn occupying 0.1-3 mol in cations, Mo and(/or)W occupying 0.2-20 mol% in cations and Mn of remaining in cations.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:提供一种氧气生成用阳极,其能够仅通过电解氯化钠水溶液来抑制氯的产生而产生氧,并且具有高性能和耐久性,特别是能够电解 强酸性液体与中和液体相同。 解决方案:通过用IrO 2 覆盖由钛制成的电极基体的表面并形成包含Mn-Mo-Sn,Mn-W-Sn或Mn的多重氧化物来获得电极 -Mo-W-Sn作为阳离子,使用阳极沉积法。 多重氧化物具有包含Sn在阳离子中占据0.1-3mol的组成,Mo和(/或)W占阳离子中的0.2-20mol%,而在阳离子中残留Mn。 版权所有(C)2008,JPO&INPIT