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    • 3. 发明专利
    • Curable composition and cured product of the same
    • 可固化组合物及其固化产物
    • JP2013194076A
    • 2013-09-30
    • JP2012059803
    • 2012-03-16
    • Daicel Corp株式会社ダイセル
    • MIZUTA TOMOYAIKURA SEI
    • C08F220/28
    • C08F220/28C08F222/1006C08G65/18C08L63/00G03F7/027G03F7/038
    • PROBLEM TO BE SOLVED: To provide a curable composition, which has superior workability with a low viscosity before irradiation with light and/or heat and which is rapidly cured by irradiation with light and/or heat and formed into a cured product with excellent flexibility and heat resistance, and to provide a cured product with the composition.SOLUTION: A cationic polymerizable resin comprises at least the following component (A), component (B), component (C), component (D) and component (E). Component (A) is an oxetane ring-containing (meth)acryloyl compound; component (B) is a cationic polymerizable group-containing compound; component (C) is a monofunctional radical polymerizable group-containing compound and a polyfunctional radical polymerizable group containing compound, in a compounding proportion of 5.0 mol or less of radical polymerizable groups in the polyfunctional radical polymerizable group-containing compound with respect to 1 mol of radical polymerizable groups in the monofunctional radical polymerizable group-containing compound; component (D) is a cationic polymerization initiator; and component (E) is a radical polymerization initiator.
    • 要解决的问题:提供一种在光和/或热照射之前具有优异的可加工性和低粘度的固化性组合物,并且通过光和/或热照射快速固化并形成具有优异柔性的固化产物, 耐热性,并提供具有该组合物的固化产物。溶液:阳离子可聚合树脂至少包含以下组分(A),组分(B),组分(C),组分(D)和组分(E)。 组分(A)是含有氧杂环丁烷的(甲基)丙烯酰基化合物; 组分(B)是含阳离子可聚合基团的化合物; 组分(C)是含有多官能团可自由基聚合基团的化合物中含有单官能自由基聚合基团的化合物和含有多官能团自由基聚合基团的化合物,所述多官能可自由基聚合基团化合物的配合比为5.0摩尔或更少的可自由基聚合基团,相对于1摩尔 含单官能自由基聚合性基团的自由基聚合性基团; 组分(D)是阳离子聚合引发剂; 组分(E)是自由基聚合引发剂。