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1. 发明专利

JPH0431413A RESIN COMPOSITION 失效
公开(公告)号：JPH0431413A
公开(公告)日：1992-02-03
申请号：JP13577490
申请日：1990-05-25
申请人： DAINIPPON INK & CHEMICALS
发明人： IRIE TOSHINOBU , YAMAUCHI NOBUHIKO
IPC分类号： C08F299/02 , C08F290/00
摘要： PURPOSE:To improve the mechanical strengths, stability, impact strength, and abrasion characteristics of a molded article at high temp. by compounding an epoxidized vinyl ester compd., a maleimide compd., and a vinylated urethane compd. CONSTITUTION:A novolac epoxy resin (e.g. a polyglycidyl ether of phenol novolac resin) is reacted with an alpha,beta-unsatd. acid (e.g. methacrylic acid) to give an epoxidized vinyl ester compd. 100 pts.wt. said compd., 10-200 pts.wt. maleimide compd. (e.g. diphenylmethanebismaleimide), 2-30 pts.wt. vinylated urethane compd. having a urethane group and, pref., two or more vinyl groups in the backbone chain, and, if necessary, 0.05-0.8 pts.wt. polymn. initiator and a filler are compounded.

3. 发明专利

JP2001278951A POLYARYLENE SULFIDE COMPOSITION 失效
公开(公告)号：JP2001278951A
公开(公告)日：2001-10-10
申请号：JP2000097099
申请日：2000-03-31
申请人： DAINIPPON INK & CHEMICALS
发明人： HIMORI TOSHIO , FURUSAWA TAKASHI , YAMAUCHI NOBUHIKO
IPC分类号： C08G59/42
摘要： PROBLEM TO BE SOLVED: To provide a polyarylene sulfide composition that improves a melt viscosity and a fluidity of a resin after blending, while keeping an adhesion and an adherence. SOLUTION: The polyarylene sulfide composition contains a carboxyl (a1) of 50-100 μmol/g in the resin, a PPS whose content of a carboxylate (a2) is 20 μmol/g or less in the resin and a novolak epoxy resin.

4. 发明专利

JPH03292321A RESIN COMPOSITION 失效
公开(公告)号：JPH03292321A
公开(公告)日：1991-12-24
申请号：JP9466390
申请日：1990-04-10
申请人： DAINIPPON INK & CHEMICALS
发明人： YAMAUCHI NOBUHIKO , IRIE HIDENOBU
IPC分类号： C08G59/40
摘要： PURPOSE:To obtain a resin composition improved in moldability and the mechanical strengths of a molding by mixing an epoxy(vinyl ester) compound with a maleimide compound. CONSTITUTION:An epoxy resin, desirably a novolac epoxy resin (e.g. polyglycidyl ether of phenol novolac) is reacted with an alpha,beta-unsaturated acid (e.g. methacrylic acid) to obtain an epoxy vinyl ester compound (a). Component (a) is mixed with 10-200 pts.wt., per 100 pts.wt. component (a), maleimide compound (b) (e.g. N-methylmaleimide), 5-50 pts.wt., per 100 pts.wt. component (b), epoxy compound (c) (e.g. polyglycidyl ether of phenol novolac) and optionally 60wt.% or below vinyl monomer (d) (e.g. styrene monomer), a polymerization initiator, a reinforcement, etc.

6. 发明专利

JPH03119016A MOLDING RESIN COMPOSITION 失效
公开(公告)号：JPH03119016A
公开(公告)日：1991-05-21
申请号：JP25731589
申请日：1989-10-02
申请人： DAINIPPON INK & CHEMICALS
发明人： YAMAUCHI NOBUHIKO , KANETANI HIROMI , IRIE HIDENOBU
IPC分类号： C08F299/00 , C08F290/00
摘要： PURPOSE:To obtain the title composition showing excellent storage stability at normal temperature, rapidly curing during heating, having high Tg and small coefficient of thermal expansion, containing novolak type epoxyvinyl ester, vinyl-based monomer, maleimide-based compound and polymerization initiator. CONSTITUTION:The objective composition containing (A) a novolak type epoxyvinyl ester (reaction product of novolak type epoxy resin and alpha,beta-unsaturated acid), (B) a vinyl based monomer [e.g. methyl (meth)acrylate], (C) a maleimide-based compound (e.g. Nmethylmaleimide) and (D) a polymerization initiator (preferably dicumyl peroxide or ditertiary butyl peroxide).

7. 发明专利

JP2002356556A PRODUCTION METHOD OF OXIDATIVE-CROSSLINKED POLYARYLENE SULFIDE 审中-公开
公开(公告)号：JP2002356556A
公开(公告)日：2002-12-13
申请号：JP2002088271
申请日：2002-03-27
申请人： DAINIPPON INK & CHEMICALS
发明人： HIMORI TOSHIO , YAMAUCHI NOBUHIKO , MINE TAKAYUKI
IPC分类号： C08J3/24 , C08G75/02 , C08G75/0295
摘要： PROBLEM TO BE SOLVED: To provide a production method of an oxidative-crosslinked polyarlene sulfide resin, excellent in productivity and effectively removing a gas component in the polyarylene sulfide. SOLUTION: Powder or aggregate of polyarylene sulfide are fed from a resin inlet 2 to a reaction tank 3, and are contacted with oxygen-containing heated gas that is fed from a gas inlet 5 through a gas-permeable partition 8, under a moderate shearing by rotation of the horizontal heating unit in an upper vacant 9. Then, polyarylene sulfide oxidative-crosslinked, is took out from a resin discharging outlet 6 through a rotary feeder 13.

9. 发明专利

JPS6067539A HEAT-RESISTANT MOLDING COMPOUND 失效
公开(公告)号：JPS6067539A
公开(公告)日：1985-04-17
申请号：JP17649483
申请日：1983-09-26
申请人： DAINIPPON INK & CHEMICALS
发明人： KAMEDA MAMORU , YAMAUCHI NOBUHIKO
IPC分类号： C08G73/00 , C08G73/10 , C08J5/24
摘要： PURPOSE:To obtain titled molding compound capable of low-pressure molding, therefore of autoclave molding, by impregnating reinforcing fiber with a specific blend comprising polyimide resin and other several components followed by bringing the resultant composite into a B-stage to make a flexible prepreg. CONSTITUTION:A blend consisting of (A) a polyimide resin, (B) 10-70 (pref. 20- 50)wt% of a reactive epoxy or vinyl group-contg. polymeric oligomer with a molecular weight 200-100,000, (C) 10-100pts.wt., based on 100pts.wt. of the component (A), or 10-200pts.wt., based on 100pts.wt. of the component (A) plus the solvent (D), of one sort, pref. several sorts of reactive vinyl group-contg. monomer(s) with boiling point(s) ranging from that of the solvent (D) to 180 deg.C, and (D) a solvent, i.e. a mixture of a high-boiling point solvent homogeneoulsy dispersible pref. dissolvable for the blend and a low-boiling point solvent is impregnated in (E) reinforcing fiber followed by drying at 70-200 deg.C for several-several tenth minutes to bring the resultant composite into a B-stage to make a prepreg, i.e. the ojbective molding compound.

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