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1. 发明专利

JP2000175681A NEW MICROORGANISM AND PRODUCTION OF AMIDE COMPOUND 失效
公开(公告)号：JP2000175681A
公开(公告)日：2000-06-27
申请号：JP35622998
申请日：1998-12-15
申请人： DAICEL CHEM
发明人： MATSUYAMA AKIKAZU , KAWABE MASATO , NAGASAWA TORU
IPC分类号： C12N15/09 , C12N1/20 , C12P13/02 , C12R1/01
摘要： PROBLEM TO BE SOLVED: To obtain a new microorganism as a kind of microorganisms containing 16S rRNA gene having specific base sequences, having the ability to convert a nitrile to the corresponding amide in high production efficiency, and useful in e.g. producing an amide compound for producing feed additives, or the like. SOLUTION: The new kind of microorganism is e.g. Rhodococcus sp.Cr4 strain (FERM BP-6596), containing 16S rRNA gene having respective base sequences of formula I and formula II and having the ability to convert a nitrile to the corresponding amide, thus being useful in producing the corresponding amide compound from a nitrile such as a cyanohydrin of formula III (R1 is a hydrocarbon group or heterocyclic group optionally having substituent(s)). The Rhodococcus sp.Cr4 strain as the new kind of microorganisms has been afforded by isolation using an accumulation method by culture in a selective medium from the soil collected from a certain field soil in Okayama City, Okayama Prefecture, Japan.

2. 发明专利

JPH11199545A PRODUCTION OF METHYL METHACRYLATE 失效
公开(公告)号：JPH11199545A
公开(公告)日：1999-07-27
申请号：JP473198
申请日：1998-01-13
申请人： DAICEL CHEM
发明人： KAWABE MASATO , KITAYAMA KENJI
IPC分类号： B01J31/24 , C07B61/00 , C07C67/38 , C07C69/54
摘要： PROBLEM TO BE SOLVED: To economically produce the subject industrially useful compound by feeding water so that a specific Broensted acid in the reactional system is kept at a specific concentration and reacting propyne, etc., with carbon monoxide and methanol using a carbonylating catalyst containing the Broensted acid. SOLUTION: Water in an amount of 0.5-5.0 wt.% based on the total weight of a reactional mixture is preferably fed so that the concentration of (iii) a Broensted acid in the reactional system is kept at 1-30 wt.% and (A) propyne and/or an arene, (B) carbon monoxide and (C) methanol are reacted in the presence of (D) a catalyst system containing (i) a supply source of an atom or an ion of a metal belonging to group VIII of the periodic table of elements [e.g. tetrakis(triphenylphosphine)platinum], (ii) a ligand selected from an organophosphorus compound, an organoarsenic compound and an organoantimony compound (e.g. triphenylphosphine) and (iii) methacrylic acid which is the Broensted acid to afford the objective compound.

3. 发明专利

JP2005035974A Method for producing 1,6-hexanediol 审中-公开
标题翻译： 1,6-己二醇的制备方法
公开(公告)号：JP2005035974A
公开(公告)日：2005-02-10
申请号：JP2004127304
申请日：2004-04-22
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： KAWABE MASATO
IPC分类号： B01J23/72 , B01J23/80 , B01J23/86 , C07B61/00 , C07C29/149 , C07C31/20
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a technique for producing 1,6-hexanediol at a low cost by using cyclohexanone as a starting raw material. SOLUTION: In the method, 1,6-Hexanediol is produced by a catalytic reduction reaction of a crude ε-caprolactone fraction obtained from a reaction process of an organic peracid and/or hydroperoxide with cyclohexanone or a by-product fraction composed mainly of residual ε-caprolactone left after separating ε-caprolactone from the crude ε-caprolactone, by-produced oxycaproic acid, adipic acid and their oligomers as they are in the presence of a hydrogenation catalyst or after esterifying the fraction with an alcohol. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种通过使用环己酮作为起始原料以低成本生产1,6-己二醇的技术。解决方案：在该方法中，通过由有机过酸和/或氢过氧化物与环己酮的反应过程获得的粗ε-己内酯馏分或副产物部分的催化还原反应制备1,6-己二醇或副产物部分主要是在粗ε-己内酯，副产的氧己酸，己二酸及其低聚物分离ε-己内酯之后留下的残余ε-己内酯，因为它们在氢化催化剂存在下或在用醇酯化之后。版权所有（C）2005，JPO＆NCIPI

4. 发明专利

JPH10114698A CARBONYLATION PROCESS AND PRODUCTION OF CARBONYLATED PRODUCT 失效
公开(公告)号：JPH10114698A
公开(公告)日：1998-05-06
申请号：JP27257496
申请日：1996-10-15
申请人： DAICEL CHEM
发明人： KAWABE MASATO , HAN RITSUZUI
IPC分类号： B01J31/24 , C07B61/00 , C07C51/14 , C07C51/56 , C07C67/38 , C07C69/533 , C07C69/54
摘要： PROBLEM TO BE SOLVED: To keep the catalytic activity over a long period and suppress the formation of by-products by reacting an acetylenic or olefinic unsaturated compound with carbon monoxide having low hydrogen content ion the presence of a carbonylation catalyst. SOLUTION: An acetylenically or olefinically unsaturated compound (preferably a 2-10C α-acetylenically or α-olefinically unsaturated compound) is carbonylated by reacting with carbon monoxide in the presence of a carbonylation catalyst. The reaction is carried out by using carbon monoxide having a hydrogen content of to 1×10 mol in terms of metallic atom and that of carbon monoxide is 1-5mol based on 1mol of the unsaturated compound.

5. 发明专利

JPS63162655A SEPARATION OF PHENYLPROPIONIC ACID ISOMER 失效
公开(公告)号：JPS63162655A
公开(公告)日：1988-07-06
申请号：JP31444186
申请日：1986-12-25
申请人： DAICEL CHEM
发明人： KAWABE MASATO , TANAKA YASUTAKA
IPC分类号： C07C57/30 , B01D9/02 , C07C51/00 , C07C51/43 , C07C67/00
摘要： PURPOSE:To obtain one isomer of phenylpropionic acid useful as a drug economically, efficiently and in high purity, by dissolving an isomer mixture of a phenylpropionic acid in a solvent and carrying out crystallization. CONSTITUTION:An isomer mixture of a phenylpropionic acid shown by the formula (R is H, alkyl, alkenyl or aryl) is dissolved in a solvent (e.g. hexane, heptane, methanol, acetone, ethyl acetate, etc.). The concentration of the solution is ordinarily up to about 15wt%. After the dissolution, crystal is precipitated by methods of (i) changing temperature of the solution, (ii) adding a solvent such as water, etc., (iii) distilling away part of the solvent, etc., to give the aimed compound. When purity of the crystal is insufficient, the crystal is redissolved in the solvent and crystallization is repeated to improve purity.

6. 发明专利

JPH11147854A CARBONYLATION 失效
公开(公告)号：JPH11147854A
公开(公告)日：1999-06-02
申请号：JP31567297
申请日：1997-11-17
申请人： DAICEL CHEM
发明人： KAWABE MASATO
IPC分类号： B01J31/24 , C07B61/00 , C07C67/38 , C07C69/54
摘要： PROBLEM TO BE SOLVED: To provide a carbonylation method for an ethylene- or acetylene-based hydrocarbon which is capable of suppressing metallization of a metal complex occurring during the carbonylation in the presence of a catalytic system containing a group VIII metal complex. SOLUTION: This carbonylation method for an ethylene- or acetylene-based hydrocarbon includes a process to react, in the presence of a catalytic system containing (1) a supply source of a group VIII metal atom or its ion, (2) an organophosphine compound and (3) an acid, (a) an ethylene- or acetylene-based hydrocarbon compound having one or more unsaturated bonds between carbons, with (b) carbon monoxide and (c) at least one nucleophilic compound selected from the group consisting of water, alcohols and carboxylic acids, wherein the reaction process is advanced by maintaining the concentration of the carbon monoxide in the reaction liquor to be 0.05-0.3 mol/L.

7. 发明专利

JPH10114703A CARBONYLATION PROCESS AND PRODUCTION OF CARBONYLATION PRODUCT 失效
公开(公告)号：JPH10114703A
公开(公告)日：1998-05-06
申请号：JP27257396
申请日：1996-10-15
申请人： DAICEL CHEM
发明人： KAWABE MASATO , HAN RITSUZUI
IPC分类号： B01J31/24 , C07B61/00 , C07C51/145 , C07C57/04 , C07C67/38 , C07C69/533 , C07C69/54
摘要： PROBLEM TO BE SOLVED: To carry out carbonylation of an acetylene-type or allene-type unsaturated compound while stably keeping high conversion over a 1.ong period by reacting the unsaturated compound with carbon monoxide in the presence of a specific catal-ysl:: while keeping the conversion of the unsaturated corrpound within a specific range. SOLUTION: A carbonylation catalyst is produced e.g. by compounding l mol of a group Vlll metal source (e.g. tetrakistriphenylphosphineplatinum), 2-100 mol of a ligand (e.jg. triphenylphosphine) and 2-400 mol of an acid (e.g. methacrylic acid). An acetylene-type or allene-type unsaturated compound (e.g. propyne) is carbonylated with carbon monoxide at 10-250'C under atmospheric pressure to 150 atm in the presence of the catalyst while keeping the conversion of the unsaturated compound to ?9O%, preferdly S95%.

8. 发明专利

JPH08245495A PRODUCTION OF CARBOXYLIC ACID 失效
公开(公告)号：JPH08245495A
公开(公告)日：1996-09-24
申请号：JP7821195
申请日：1995-03-08
申请人： DAICEL CHEM
发明人： KAWABE MASATO
IPC分类号： C07C51/06 , C07B61/00 , C07C51/08 , C07C53/124 , C07C59/08
摘要： PURPOSE: To produce a carboxylic acid while effectively utilizing a salt and ammonia which are components of a catalyst formed as by-products by hydrolyzing a nitrile or an amide compound. CONSTITUTION: A nitrile or an amide compound is hydrolyzed with an acidic catalyst such as an inorganic acid and an ammonium salt of the acidic catalyst formed as a by-product is electrodialyzed to produce an acid and ammonia. The resultant acid is then used as a catalyst in the step for hydrolyzing the nitrile or amide compound and the produced ammonia is used as a nitrogen source in a step for producing the nitrile or amide compound. When the compound is hydrolyzed with a basic catalyst such as an alkali metallic hydroxide, the salt of the carboxylic acid with the base formed as a by-product is electrodialyzed to produce the carboxylic acid and base. The resultant base is then reutilized as a catalyst in a step for hydrolyzing the nitrile compound. The ammonia produced by the electrodialysis is reutilized as the nitrogen source in the step for producing the nitrile or amide compound. The electrodialysis can be carried out with an ion exchange membrane constituted of at least one membrane of a bipolar, a cation exchange and an anion exchange membranes.

9. 发明专利

JPH01203377A PRODUCTION OF DIHYDROXYACETONE DIMER 失效
公开(公告)号：JPH01203377A
公开(公告)日：1989-08-16
申请号：JP2573788
申请日：1988-02-08
申请人： DAICEL CHEM
发明人： KAWABE MASATO
IPC分类号： C07D317/20 , C07D319/12
摘要： PURPOSE:To obtain dihydroxyacetone dimer which is used as a starting substance for medicines through a simple process by keeping crystals of dihydroxyacetone monomer or a mixture thereof with dimer crystals in a certain temperature range near room temperature. CONSTITUTION:The crystals of dihydroxyacetone monomer or a mixture thereof with dimer crystals are kept at 0-40 deg.C to convert the monomer crystals into the dimer crystals completely within at least 1,000hr. The atmosphere on its storage may be air or other inert gases, but the storage in high humidity is not desired.

10. 发明专利

JPH01203348A PRODUCTION OF DIHYDROXYACETONE 失效
公开(公告)号：JPH01203348A
公开(公告)日：1989-08-16
申请号：JP2573988
申请日：1988-02-08
申请人： DAICEL CHEM
发明人： KAWABE MASATO , FUKUNISHI KUNIO
IPC分类号： C12P7/18 , C07C45/00 , C07C45/81 , C07C49/17 , C07C67/00
摘要： PURPOSE:To efficiently and readily obtain the present compound which is a raw material for medicines, by controlling the time up to start of crystallization after concentration and obtaining a crystallization liquor excellent in filterability in concentrating an aqueous solution of dihydroxyacetone, adding a solvent to the concentrated solution and carrying out crystallization. CONSTITUTION:An aqueous solution of dihydroxyacetone is concentrated and a solvent is then added after the concentration to carry out crystallization. In the process, dehydration and concentration are performed until the moisture content in the concentrated solution attains =90wt.%. After the concentration, a solvent is then added to carry out crystallization so that the time up to start of crystallization may not exceed 50hr. Thereby, the aimed compound is obtained. A lower alcohol, such as isopropanol, acetone, etc., are used as the solvent. The amount of the solvent used is preferably 0.3-2.0pts.wt. based on 1pt.wt. dihydroxyacetone. The temperature for carrying out the crystallization is optimally within the range of 0-30 deg.C.

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