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    • 3. 发明专利
    • Manufacturing method of positive electrode active material paste for lead-acid storage battery, and positive electrode plate for lead-acid storage battery using the paste
    • 用于铅酸蓄电池的正极电极活性材料浆料的制造方法和使用该浆料的铅酸蓄电池的正极电极板
    • JP2009231014A
    • 2009-10-08
    • JP2008074209
    • 2008-03-21
    • Furukawa Battery Co Ltd:The古河電池株式会社
    • AKASAKA YUICHIMIDORIKAWA ATSUSHIFURUKAWA ATSUSHI
    • H01M4/20H01M4/14
    • Y02P70/54
    • PROBLEM TO BE SOLVED: To provide a positive electrode active material paste for a lead-acid storage battery in which chemical conversion efficiency and adhesiveness are improved since sufficient chemical conversion efficiency is hard to be obtained and adhesiveness problem is caused since reaction of red lead and sulfuric acid progresses too much and lead sulfate is formed excessively depending on an additive amount of diluted sulfuric acid in a manufacturing method of the positive electrode active material paste for the lead-acid storage battery containing lead powder, dilute sulfuric acid, and red lead.
      SOLUTION: In the manufacturing method of the positive electrode active material paste for the lead-acid storage battery containing at least the lead powder having lead monoxide as the main component, diluted sulfuric acid, and red lead, this is the manufacturing method of the positive electrode active material paste for the lead-acid storage battery in which the proportion of sulfuric acid against lead powder is 2 mass% or more and less than 7 mass%.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种铅酸蓄电池用正极活性物质糊剂,其中化学转化效率和粘合性得到改善,因为难以获得足够的化学转化效率,并且由于反应产生粘合性问题, 在含铅铅蓄电池的正极活性物质浆料的制造方法中,含有铅粉末,稀硫酸和铅酸蓄电池的制造方法中,红铅和硫酸进行过多,依赖于稀硫酸的添加量而过度形成硫酸铅 红铅 解决方案:在铅酸蓄电池用正极活性物质糊剂的制造方法中,至少含有以一氧化铅为主要成分的铅粉末,稀硫酸和红铅,这是制造方法 的铅酸蓄电池用正极活性物质糊料,其中硫酸对铅粉的比例为2质量%以上且小于7质量%。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Grid for lead-acid storage battery, and lead-acid storage battery using the same
    • 铅酸蓄电池网和使用该蓄电池的铅酸蓄电池
    • JP2009037775A
    • 2009-02-19
    • JP2007199374
    • 2007-07-31
    • Furukawa Battery Co Ltd:The古河電池株式会社
    • AKASAKA YUICHI
    • H01M4/68H01M4/73
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a grid for a lead-acid storage battery wherein PCL is not caused even if deep discharge cycles are repeated, and decrease of the storage battery liquid can be prevented.
      SOLUTION: In this grid for the lead-acid storage battery, a Pb-Sb alloy layer is formed on the surface of a Pb-Ca based alloy grid, Sb concentration of the Pb-Sb alloy layer is more than 50 mass% and not more than 99 mass%, and its thickness is 0.3-5.0 μm. Since the Pb-Sb alloy layer having proper composition is formed on the surface of the Pb-Ca based alloy grid so as to have a proper thickness in this grid for the lead-acid storage battery, both PCL (Premature Capacity Loss) and decrease of the storage battery liquid are prevented. Since this Pb-Sb alloy layer is thin, it can be formed in a short time and is excellent in productivity. The thickness and Sb concentration of the Pb-Sb alloy layer can be properly formed by an electroplating method.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供一种铅酸蓄电池的栅格,其中即使重复深度放电循环也不会引起PCL,并且可以防止蓄电池液体的减少。

      解决方案:铅酸蓄电池的栅格中,Pb-Ca系合金栅极表面形成Pb-Sb合金层,Pb-Sb合金层的Sb浓度超过50质量% %以上且99质量%以下,其厚度为0.3〜5.0μm。 由于在Pb-Ca系合金网格的表面上形成具有适当组成的Pb-Sb合金层,以便在该铅酸蓄电池的栅格中具有适当的厚度,因此PCL(过早容量损失)和减少 的蓄电池液体。 由于该Pb-Sb合金层薄,所以可以在短时间内形成,生产率优异。 可以通过电镀法适当地形成Pb-Sb合金层的厚度和Sb浓度。 版权所有(C)2009,JPO&INPIT

    • 5. 发明专利
    • Manufacturing method of electrode plate for lead-acid storage battery
    • 铅酸蓄电池电极板的制造方法
    • JP2007287599A
    • 2007-11-01
    • JP2006116392
    • 2006-04-20
    • Furukawa Battery Co Ltd:The古河電池株式会社
    • AKASAKA YUICHI
    • H01M4/21
    • Y02P70/54
    • PROBLEM TO BE SOLVED: To provide a lead-acid storage battery with excellent initial performance and life characteristics by having 4BS mainly produced on the surface of an electrode plate, and, in case paste paper is bonded on the surface of an electrode plate, to provide an electrode plate free from paper peel-off at a stack at assembly by enhancing adhesive force of an active material with the paste paper. SOLUTION: In the manufacturing method of the electrode plate, in which a paste-like active material, after it is filled in a lead-alloy substrate with lead as a main component, is put under an aging process, the aging is to be performed after tetrabasic lead sulfate is made adhered on the surface of the electrode plate. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种具有优异的初始性能和寿命特性的铅酸蓄电池,其主要是在电极板的表面上生产4BS,并且如果粘贴纸粘在电极表面上 以提供在组装时在堆叠处没有纸剥离的电极板,通过增加活性材料与糊纸的粘合力。 解决方案:在电极板的制造方法中,将糊状活性物质填充在以铅为主要成分的铅合金基材中后,进行老化处理,老化为 在四极硫酸铅附着在电极板的表面上之后进行。 版权所有(C)2008,JPO&INPIT
    • 6. 发明专利
    • Grid for lead acid battery
    • 铅酸电池网
    • JP2009076406A
    • 2009-04-09
    • JP2007246341
    • 2007-09-24
    • Furukawa Battery Co Ltd:The古河電池株式会社
    • AKASAKA YUICHI
    • H01M4/73H01M4/68
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a grid for a lead acid battery which does not create a PCL even though deep discharge cycles are repeated.
      SOLUTION: In the grid for the lead acid battery wherein a Sb layer is formed on the surface of the Pb-Ca based alloy grid by a plating method, the Sb layers are multiply laminated, and the width of the first layer of the multiply-laminated Sb layers is set up to be less than 0.3 μm. The PCL (early capacity reduction) of the grid for a lead acid battery can be prevented since the Sb layer with appropriate thickness is formed on the surface of the Pb-Ca based and lead based alloy grid. The battery does not result in a sudden life span caused by a crack so that the Sb layers are laminated and the thickness of the first layer is less than 0.3 μm. The thickness of the Sb layer can be appropriately formed by the electroplating method.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供即使重复深度排放循环也不产生PCL的铅酸电池的栅格。 解决方案:在通过电镀法在Pb-Ca基合金网格的表面上形成Sb层的铅酸电池的栅格中,Sb层被多层叠,并且第一层的宽度 多层叠Sb层被设定为小于0.3μm。 由于在Pb-Ca系和铅系合金网格的表面上形成适当厚度的Sb层,因此能够防止铅酸蓄电池的电网的PCL(早期容量降低)。 电池不会导致由裂纹引起的突然的寿命,使得Sb层被层压,并且第一层的厚度小于0.3μm。 可以通过电镀法适当地形成Sb层的厚度。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Method of manufacturing lead acid battery electrode plate
    • 铅酸电池电极板的制造方法
    • JP2007220644A
    • 2007-08-30
    • JP2006163858
    • 2006-06-13
    • Furukawa Battery Co Ltd:The古河電池株式会社
    • AKASAKA YUICHI
    • H01M4/20
    • Y02P70/54
    • PROBLEM TO BE SOLVED: To provide an electrode plate in which stacks are prevented from paper peeling in assembling by generating an active material consisting of 4BS in the paste-like active material in a preferred condition in the primary step of maturing the electrode plate or when the paste like active material is mixed, so that the bonding strength of the paste-like active material with a paste paper is increased, wherein the 4BS has a larger crystal size than 3BS and a high bonding strength between crystals. SOLUTION: In the method of manufacturing a lead acid battery electrode plate, the paste-like active material is filled into a lead alloy base plate consisting essentially of lead, and paste papers are bonded on the both sides of the plate. The tetrabasic lead sulfate (4BS) is generated in the paste-like active material in the primary step of maturing or in paste mixing step. The amount of 4BS generated is increased not less than 50 wt.% after maturing. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种电极板,其中通过在熟化电极的第一步骤中的优选条件下,在糊状活性材料中产生由4BS组成的活性材料,防止组装中的纸张剥离 当浆料像活性物质混合时,浆糊状活性物质与糊状纸的结合强度增加,其中4BS具有比3BS更大的晶体尺寸和晶体之间的高结合强度。 解决方案:在制造铅酸电池电极板的方法中,将糊状活性物质填充到主要由铅组成的铅合金基板中,并且将糊状物粘合在板的两侧。 在成熟或浆糊混合步骤的一级步骤中,在糊状活性物质中产生四碱性硫酸铅(4BS)。 生成的4BS的量在成熟后增加不小于50重量%。 版权所有(C)2007,JPO&INPIT