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1. 发明专利

JP2010221167A Exhaust gas cleaning catalyst, and catalyst plate and exhaust gas cleaning method using the same 审中-公开
标题翻译：排气清洁催化剂，催化剂板和使用其的排气清洁方法
公开(公告)号：JP2010221167A
公开(公告)日：2010-10-07
申请号：JP2009073067
申请日：2009-03-25
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： YOSHIDA NORIKO , IIZUKA HIDEHIRO , ARATO TOSHIAKI , MUKAI TOSHIFUMI
IPC分类号： B01D53/94 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/10 , F01N3/08
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas cleaning catalyst that prevents itself from being poisoned by phosphorus compounds in an exhaust gas and is excellent in durability, and a catalyst plate and an exhaust gas cleaning method using it.
SOLUTION: The catalyst for removing nitrogen oxides in the exhaust gas containing the nitrogen oxides and phosphorus compounds has mesopores of which the mean pore diameter is 2-8 nm and of which the mean pore diameter showing a maximum value of differential pore volume in pore-size distribution of the catalyst is 2-8 nm. The wall of the mesopores contains an oxide containing at least one element selected from Mo, W and V and Ti.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种排气净化催化剂，其能够防止废气中的磷化合物中毒，耐久性优异，催化剂板和使用其的排气净化方法。解决方案：用于除去含有氮氧化物和磷化合物的废气中的氮氧化物的催化剂具有平均孔径为2-8nm的中孔，其平均孔径显示出不同孔体积的最大值催化剂的孔径分布为2-8nm。中孔的壁含有含有至少一种选自Mo，W和V的元素和Ti的氧化物。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2013208533A Carbon dioxide recovery system 审中-公开
标题翻译：二氧化碳回收系统
公开(公告)号：JP2013208533A
公开(公告)日：2013-10-10
申请号：JP2012079861
申请日：2012-03-30
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： ORITA HISAYUKI , MUKAIDE MASAAKI , HOKARI NOBUYUKI , YOSHIDA NORIKO , YOKOYAMA KOICHI , SHIMAMURA JUN
IPC分类号： B01D53/14 , B01D53/62 , B01D61/02 , C01B32/50
CPC分类号： Y02A50/2342 , Y02C10/04 , Y02C10/06 , Y02P20/152
摘要： PROBLEM TO BE SOLVED: To provide a carbon dioxide absorption system which maintains low concentration of an absorbent ingredient contained in a cleaning solution of a scattered absorbent cleaning section and reduces the amount of the solution returned to an absorption section or the scattered absorbent cleaning section.SOLUTION: In a carbon dioxide absorption system including an absorption section 31, a scattered absorbent cleaning section 32 and a regeneration section 15, a filtration section 46 for obtaining a reflux liquid having removed an absorbent component from a cleaning solution of the scattered absorbent cleaning section 32 is provided, and the reflux liquid is reused as a cleaning solution in the scattered absorbent cleaning section 32.
摘要翻译：要解决的问题：提供一种二氧化碳吸收系统，其保持包含在散射吸收剂清洁部分的清洁溶液中的吸收成分的低浓度，并且减少返回到吸收部分或分散的吸收剂清洁部分的溶液的量。解决方案：在吸收部分31，分散吸收剂清洗部分32和再生部分15的二氧化碳吸收系统中，用于获得从分散的吸收剂清洗部分的清洗溶液中除去吸收成分的回流液体的过滤部分46 32，回流液在分散吸收剂清洗部32中作为清洗液重新使用。

3. 发明专利

JP2004002121A Apparatus for producing hydrogen, method for operating the same, and power generation system using the same 审中-公开
公开(公告)号：JP2004002121A
公开(公告)日：2004-01-08
申请号：JP2002161062
申请日：2002-06-03
申请人： Babcock Hitachi Kk , Hitachi Ltd , バブコック日立株式会社 , 株式会社日立製作所
发明人： KOMACHIYA MASAHIRO , HIYAMA KIYOSHI , YOSHIDA NORIKO , IMADA NORIYUKI , OKANO TETSURO , KAKO HIROYUKI , YATABE HIROSHI
IPC分类号： C01B3/38 , H01M8/04 , H01M8/06 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To speedily and easily control the runaway temperature of a catalytic reactor involved in an apparatus for producing hydrogen without adversely affecting the composition of gas. SOLUTION: An H 2 -rich gaseous mixture 102 containing CO of lowered concentration is supplied to a CO selective oxidation section 12, a gaseous mixture discharged from the CO selective oxidation section in which residual CO is converted to CO 2 by a catalytic reaction is cooled, and reflux gas 104 obtained by diverging part of the cooled gaseous mixture is supplied again to the CO selective oxidation section, whereby the runaway temperature of the catalytic reaction section can speedily be controlled without adversely affecting the composition of gas. COPYRIGHT: (C)2004,JPO

4. 发明专利

JP2013208531A Carbon dioxide recovery system 审中-公开
标题翻译：二氧化碳回收系统
公开(公告)号：JP2013208531A
公开(公告)日：2013-10-10
申请号：JP2012079846
申请日：2012-03-30
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： YOSHIDA NORIKO , ORITA HISAYUKI , MUKAIDE MASAAKI , HOKARI NOBUYUKI , YOKOYAMA KOICHI , SHIMAMURA JUN
IPC分类号： B01D53/62 , B01D53/14 , C01B32/50
CPC分类号： Y02A50/2342 , Y02C10/06 , Y02P20/152
摘要： PROBLEM TO BE SOLVED: To perform control on regeneration of absorption liquid by forecasting the deterioration state of the absorption liquid without carrying out analysis of the absorption liquid in a carbon dioxide recovery system.SOLUTION: In a carbon dioxide recovery system using an absorption liquid such as an amine aqueous solution, an acidic gas detection part (a SOx analyzer 41 and a NOx analyzer 42) for detecting concentration of the acidic gas such as SOx and NOx included in CO-containing gas is provided to a CO-containing gas introducing pipe for introducing combustion exhaust gas 2 of an absorption tower 5. At a control part 40, extracting amount of deteriorated absorption liquid or the like at an absorption liquid regeneration apparatus 30 is controlled based on the concentration of the acidic gas.
摘要翻译：要解决的问题：通过预测吸收液体的劣化状态来进行对吸收液体的再生的控制，而不进行二氧化碳回收系统中的吸收液体的分析。解决方案：在使用吸收液体的二氧化碳回收系统作为胺水溶液，将含有CO的气体中含有的SOx，NOx等酸性气体的浓度的酸性气体检测部（SOx分析器41和NOx分析器42）提供给含CO气体导入管用于引入吸收塔5的燃烧废气2.在控制部分40，基于酸性气体的浓度来控制吸收液体再生装置30处的劣化的吸收液体等的提取量。

5. 发明专利

JP2013139013A Co2 capture system by chemical absorption 有权
标题翻译：通过化学吸收的CO2捕获系统
公开(公告)号：JP2013139013A
公开(公告)日：2013-07-18
申请号：JP2012000960
申请日：2012-01-06
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： HOKARI NOBUYUKI , ORITA HISAYUKI , MUKAIDE MASAAKI , SHIMAMURA JUN , YOKOYAMA KOICHI , YOSHIDA NORIKO
IPC分类号： B01D53/62 , B01D53/14 , C01B32/50
CPC分类号： B01D53/62 , B01D53/1425 , B01D53/1475 , B01D2258/0283 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： PROBLEM TO BE SOLVED: To reduce regeneration energy charged into a regeneration tower from the outside and to improve the energy efficiency of a COcapture system by chemical absorption by reducing the cooling waste heat of the gas cooling of exhaust gas.SOLUTION: The COcapture system by chemical absorption includes an absorber for absorbing COby a solvent and a regenerator which heats the CO-absorbed absorption liquid to discharge the CO, and also includes a gas discharge system which discharges the gas released from the absorption liquid in the regenerator to the outside, a gas compressor installed downstream of the gas discharge system, a heat exchanger installed downstream of the gas compressor and exchanging heat between the compressed gas and a rich liquid to be sent to the regenerator, a gas-liquid separator installed downstream of the heat exchanger and separating the gas and condensed water, a condensed water supply system supplying the condensed water from the gas-liquid separator to the regenerator, another gas discharge system discharging the gas containing high concentration COfrom the gas-liquid separator, and a compressor installed downstream of the gas-liquid separator in the another gas discharge system and pressurizing the gas containing high concentration CO.
摘要翻译：要解决的问题：通过减少排气气体冷却的冷却废热，通过化学吸收来减少从外部进入再生塔的再生能量并提高CO捕集系统的能量效率。解决方案：CO捕集系统由化学吸收包括用于吸收溶剂中的CO的吸收剂和加热CO吸收的吸收液体以排出CO的再生器，并且还包括将从再生器中的吸收液体释放的气体排出到外部的气体排出系统，安装在排气系统下游的气体压缩机，安装在气体压缩机下游的热交换器，并且将压缩气体与要送往再生器的富液体之间的热交换，安装在热交换器下游的气液分离器，气体和冷凝水，从气液分离器供应冷凝水的冷凝水供应系统在再生器的另一个气体放电系统中，从气液分离器排出含有高浓度CO的气体的另一个气体放电系统，以及安装在另一气体放电系统中的气液分离器下游的压缩机，并对含有高浓度CO的气体加压。

6. 发明专利

JP2011230042A Exhaust gas cleaning catalyst 审中-公开
标题翻译：排气净化催化剂
公开(公告)号：JP2011230042A
公开(公告)日：2011-11-17
申请号：JP2010101588
申请日：2010-04-27
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： YOSHIDA NORIKO , ARATO TOSHIAKI , MUKAI TOSHIFUMI
IPC分类号： B01J23/34 , B01D53/94 , B01J23/847 , B01J23/889
摘要： PROBLEM TO BE SOLVED: To improve the denitration activity of a catalyst by preventing the poisoning of the catalyst by a phosphorus compound or the like contained in exhaust gas.SOLUTION: Mesoporous silica is used as a carrier, and the carrier carries at least one or more kinds of elements selected from a group composed of Mn, Co, Fe and Ni, and at least one or more kinds of elements selected from a group composed of V, Mo and W. Preferably, these elements are oxides or composite oxides.
摘要翻译：要解决的问题：通过防止由废气中所含的磷化合物等引起的催化剂的中毒，提高催化剂的脱硝活性。解决方案：介孔二氧化硅用作载体，载体携带选自由Mn，Co，Fe和Ni组成的组中的至少一种或多种元素，以及至少一种或多种选自由V，Mo和W组成的组。优选地，这些元素是氧化物或复合氧化物。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2011045849A Nitrogen oxide removal catalyst and nitrogen oxide removal apparatus using the same 审中-公开
标题翻译：使用氮氧化物除氧催化剂和氮氧化物除去装置
公开(公告)号：JP2011045849A
公开(公告)日：2011-03-10
申请号：JP2009197673
申请日：2009-08-28
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： ARATO TOSHIAKI , YOSHIDA NORIKO , IIZUKA HIDEHIRO , MUKAI TOSHIFUMI
IPC分类号： B01J23/28 , B01D53/94 , F01N3/10
摘要： PROBLEM TO BE SOLVED: To provide a nitrogen oxide removal catalyst with little deterioration by a catalytic poisoning component such as phosphorus and arsenic and excellent in oxidation resistance and heat resistance. SOLUTION: The nitrogen oxide removal catalyst includes a carrier having fine pores and an active component for removing the nitrogen oxide in an exhaust gas and the average diameter of the fine pores is 20 to 100 Å, the volume of the fine pores with a diameter of 20 to 100 Å is 80% or more in the total volumes of all fine pores and the volume of the fine pores with a diameter of 20 to 100 Å is 0.1 to 0.4 cm 3 per gram of the catalyst. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种几乎不受诸如磷和砷的催化中毒成分的劣化的氮氧化物去除催化剂，并且具有优异的耐氧化性和耐热性。解决方案：氮氧化物去除催化剂包括具有细孔的载体和用于除去排气中的氮氧化物的活性组分，并且细孔的平均直径为20至100埃，细孔的体积为在所有细孔的总体积中，直径为20至100的直径为80％或更多，并且直径为20至100的细孔的体积为0.1至0.4cm 3 / SP 的催化剂。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2010036137A Catalyst for removing nitrogen oxide, apparatus and method for removing nitrogen oxide using the same 审中-公开
标题翻译：用于除去氮氧化物的催化剂，使用其除去氮氧化物的装置和方法
公开(公告)号：JP2010036137A
公开(公告)日：2010-02-18
申请号：JP2008203695
申请日：2008-08-07
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： ARATO TOSHIAKI , YOSHIDA NORIKO , IIZUKA HIDEHIRO , HIGASHIYAMA KAZUHISA , MUKAI TOSHIFUMI
IPC分类号： B01J23/22 , B01D53/94 , F01N3/08
CPC分类号： F01N3/2066 , B01D53/9413 , B01D2251/204 , B01D2251/2062 , B01D2251/2067 , B01D2251/208 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2255/9205 , B01J21/063 , B01J23/22 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/08 , F01N2370/02 , F01N2610/02 , F23J15/02 , F23J2217/102 , F23J2219/10 , Y02T10/24
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for removing nitrogen oxides that is prevented from degrading due to a phosphorus compound or an arsenic compound, and to provide an apparatus and method for removing nitrogen oxides using the catalyst. SOLUTION: The catalyst for removing nitrogen oxides in an exhaust gas, wherein a component for removing the nitrogen oxides is supported by a carrier, has pores whose average pore size is 20 to 100 Å measured by a gas adsorption method for measuring a pore size of 20 to 3,000 Å, and whose volume is 50% or more of the total volume of the pores measured by the gas adsorption method. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于除去由磷化合物或砷化合物引起的降解的氮氧化物的催化剂，并提供使用该催化剂除去氮氧化物的装置和方法。解决方案：用于去除排气中的氮氧化物的催化剂，其中用于除去氮氧化物的组分由载体负载，具有通过气体吸附法测量的平均孔径为20至100的孔孔径为20〜3000，体积为通过气体吸附法测定的孔的总体积的50％以上。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2013208532A Carbon dioxide chemical absorption system 审中-公开
标题翻译：二氧化碳吸收系统
公开(公告)号：JP2013208532A
公开(公告)日：2013-10-10
申请号：JP2012079851
申请日：2012-03-30
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： HOKARI NOBUYUKI , ORITA HISAYUKI , MUKAIDE MASAAKI , SHIMAMURA JUN , YOKOYAMA KOICHI , YOSHIDA NORIKO
IPC分类号： B01D53/14 , B01D53/34 , B01D53/62 , C01B32/50
CPC分类号： Y02A50/2342 , Y02C10/06 , Y02P20/152
摘要： PROBLEM TO BE SOLVED: To stably operate a decompression evaporator and a compression part which are components in a carbon dioxide chemical absorption system to which a vapor recompression (VR) method is applied.SOLUTION: In a carbon dioxide chemical absorption system, a vapor recompression part is provided with a decompression evaporator 20 for decompressing/evaporating lean liquid extracted from a regeneration tower 2 via a regeneration tower bottom pipe 19, a compression part 22 for pressurizing vapor generated by the decompression evaporator 20, and a recompression vapor pipe (VR vapor pipe 23) for putting the vapor pressurized by the compression part 22 into the regeneration tower 2. A lean liquid pipe 26 for evaporation which transports lean liquid from the regeneration tower 2 to the decompression evaporator 20 is provided with a flow rate adjustment valve CV1, and the decompression evaporator 20 is provided with a pressure gauge P1 for measuring the pressure inside the decompression evaporator 20. An opening degree of the flow rate adjustment valve CV1 or input of the compression part 22 is controlled so that a measurement value of the pressure gauge P1 becomes constant.
摘要翻译：要解决的问题：稳定地运行作为二氧化碳化学吸收系统中应用了蒸气压缩（VR）方法的组分的减压蒸发器和压缩部件。解决方案：在二氧化碳化学吸收系统中，蒸气重新压缩部分设置有减压蒸发器20，用于通过再生塔底管19从再生塔2抽取的贫液稀释/蒸发，用于对由减压蒸发器20产生的蒸汽加压的压缩部22和再压缩蒸气管用于将由压缩部22加压的蒸汽输送到再生塔2中的蒸气管23将用于将稀薄液体从再生塔2输送至减压蒸发器20的用于蒸发的贫液管26设置有流量调节阀CV1，并且减压蒸发器20设置有用于测量分解内的压力的压力计P1 控制流量调节阀CV1的开度或压缩部22的输入，使得压力表P1的测量值恒定。

10. 发明专利

JP2008221203A Catalyst for removal of nitrogen oxide and method for removal of nitrogen oxide 审中-公开
标题翻译：用于除去氧化氮的催化剂和除去氮氧化物的方法
公开(公告)号：JP2008221203A
公开(公告)日：2008-09-25
申请号：JP2007296204
申请日：2007-11-15
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： YOSHIDA NORIKO , IIZUKA HIDEHIRO , KATO YASUYOSHI , NAGAI YOSHINORI , ARATO TOSHIAKI
IPC分类号： B01J29/14 , B01D53/94 , B01J29/035 , B01J29/16 , B01J35/02 , B01J35/10 , B01J37/02
CPC分类号： B01J29/08 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01D2255/30 , B01D2255/50 , B01D2255/9205 , B01J23/22 , B01J23/28 , B01J29/0308 , B01J29/0341 , B01J29/061 , B01J29/072 , B01J29/076 , B01J29/14 , B01J29/143 , B01J29/146 , B01J29/16 , B01J35/023 , B01J35/1033 , B01J35/1057 , B01J35/1061 , B01J37/0246 , F01N3/10 , F01N3/2066 , F01N3/2803 , F01N2330/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for removal of nitrogen oxide in which the catalyst for removing a nitrogen oxide from an exhaust gas containing the nitrogen oxides is prevented from being poisoned by a phosphorus compound contained in an exhaust gas and having excellent durability and a method for the removal of nitrogen oxides.
SOLUTION: The catalyst comprising a porous material having a controlled pore size and an active ingredient carried inside of a pore of the porous material is used. The pore of the porous material may have a diameter of 8 to 9 Å. Preferably, the diameter of the pore is 8 to 9 Å as measured by a gas adsorption method which can measure a pore size ranging from 3.4 to 14 Å or as calculated from a crystalline structure. Alternatively, the porous material may be a mesoporous silica. Preferably, the mesoporous silica has a primary particle diameter of 150 to 300 nm.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于除去氮氧化物的催化剂，其中防止含氮氧化物的废气中除去氮氧化物的催化剂被包含在废气中的磷化合物中毒，并且具有优异的耐久性和除去氮氧化物的方法。解决方案：使用包含可控孔径的多孔材料和承载在多孔材料的孔内的活性成分的催化剂。多孔材料的孔可以具有8至9的直径。优选地，通过气体吸附法测量孔的直径为8〜9，该气体吸附法可以测量从3.4至14埃的孔径或从晶体结构计算。或者，多孔材料可以是介孔二氧化硅。优选地，介孔二氧化硅的初级粒径为150〜300nm。版权所有（C）2008，JPO＆INPIT

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