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    • 1. 发明专利
    • Method for treating water to be treated containing ammonia
    • 用于处理含有氨的水的方法
    • JP2005313099A
    • 2005-11-10
    • JP2004135285
    • 2004-04-30
    • Babcock Hitachi Kkバブコック日立株式会社
    • YAMADA RIKUOSATO KAZUNORITANIGUCHI YUKIHISATAKEBE NORIYUKI
    • B01D19/00B01D53/86B01J20/34C02F1/20C02F1/28
    • PROBLEM TO BE SOLVED: To provide a method for treating water to be treated containing ammonia which regenerates an ammonia zeolite adsorption layer utilizing an ion-exchange performance by an alkali regenerant to concentrate ammonia into a regenerated liquid in a high concentration. SOLUTION: In the method for passing the water to be treated containing ammonia nitrogen coexisting with a magnesium ion and/or an alkali-earth metal ion through a natural zeolite adsorption column to regenerate zeolite by the alkali regenerant, the ion remaining in a space of the zeolite adsorption column and vacant holes of zeolite is removed by water without substantially containing the magnesium ion and/or the alkali-earth metal ion, and then the regeneration of zeolite is carried out by the alkali regenerant. This method is achieved by providing the concentration of ammonia nitrogen collected in the regenerated liquid to 2,000-10,000 ppm, further emitting ammonia contained in the regenerated liquid in a gas phase by steam or heated air using a solid alkali and/or a liquid alkali as an alkali of the regenerated liquid, and catalytically decomposing. COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供一种处理含水氨的方法,其中,利用碱再生剂利用离子交换性能再生氨沸石吸附层,以将氨浓缩成高浓度的再生液体。 解决方案:在通过天然沸石吸附塔将含有与镁离子和/或碱土金属离子共存的氨氮的待处理水通过碱再生剂再生沸石的方法中, 沸石吸附塔的空间和沸石的空穴通过水除去而基本上不含有镁离子和/或碱土金属离子,然后由碱再生剂进行沸石的再生。 该方法通过将再生液体中收集的氨氮浓度提高到2,000〜10000ppm,通过使用固体碱和/或液态碱的蒸汽或加热空气将气态中的再生液体中所含的氨进一步发出, 再生液体的碱,并进行催化分解。 版权所有(C)2006,JPO&NCIPI
    • 2. 发明专利
    • Soil decontaminating apparatus and soil decontaminating method
    • 土壤去除装置和土壤去除方法
    • JP2005199130A
    • 2005-07-28
    • JP2004005772
    • 2004-01-13
    • Babcock Hitachi Kkバブコック日立株式会社
    • MATSUMOTO SHINICHINOMURA HIROSHIITO MORIOYAMADA RIKUOOYATSU NORIYUKI
    • B09C1/02B09B3/00B09C1/08
    • PROBLEM TO BE SOLVED: To provide a soil decontaminating apparatus decontaminating soil with high treatment efficiency at a low cost.
      SOLUTION: The soil decontaminating apparatus is provided with a soil treatment tank 1 containing contaminated soil 2; a strong acid solution supply means 16 supplying a strong acid solution 15 to the contaminated soil 2 in the tank 1; a strong acid solution recovering means 5 recovering the strong acid solution which has eluted contaminants adhering to the soil from the soil treatment tank 1 by bringing the strong acid solution 15 into contact with the contaminated soil 2; a pumping water treatment apparatus 6 for removing the contaminants from the pumping water recovered by the recovering means 5; and a regulation tank 7 for sending the treated water from the pumping water treatment apparatus 6 to the strong acid solution supply means 16 as the strong acid solution 15, after adjusting pH.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:以低成本提供以高处理效率对土壤进行净化的土壤去污设备。 解决方案:土壤净化装置设有含污染土壤2的土壤处理槽1; 将强酸溶液15供给到罐1中的污染土壤2的强酸溶液供给装置16; 强酸溶液回收装置5通过使强酸溶液15与污染土壤2接触,回收从污垢处理槽1附着到土壤上的污染的污染物的强酸溶液; 用于从由回收装置5回收的泵送水中除去污染物的抽水处理装置6; 以及调节罐7,用于在调节pH后将处理过的水从泵送水处理设备6送到强酸溶液供应装置16作为强酸溶液15。 版权所有(C)2005,JPO&NCIPI
    • 4. 发明专利
    • Method and apparatus for removing ammonia nitrogen in water to be treated
    • 在待处理水中去除硝态氮的方法和装置
    • JP2005349244A
    • 2005-12-22
    • JP2004169542
    • 2004-06-08
    • Babcock Hitachi Kkバブコック日立株式会社
    • YAMADA RIKUOSATO KAZUNORITANIGUCHI YUKIHISATAKEBE NORIYUKI
    • B01D19/00B01D53/86B01J20/26B01J20/34B01J49/00C02F1/20C02F1/42
    • PROBLEM TO BE SOLVED: To provide a method and an apparatus for removing ammonia nitrogen in the water to be treated, by each of which ammonia nitrogen can be removed selectively even from the water which is to be treated and contains not only a high-concentration alkali metal ion and/or a high-concentration alkaline-earth metal ion but also ammonia nitrogen. SOLUTION: When ammonia nitrogen is removed by using a metal chelate resin from the water which is to be treated and contains not only the alkali metal ion and/or the alkaline-earth metal ion but also ammonia nitrogen, if the pH of the water to be treated is adjusted adequately, only ammonia can be adsorbed selectively on the metal chelate resin without adsorbing the alkali metal ion and/or the alkaline-earth metal ion on the metal chelate resin. If the metal chelate resin on which only ammonia is adsorbed selectively is regenerated, the regenerated metal chelate resin can be utilized again for removing ammonia nitrogen in the water to be treated. The ammonia recovered in the recovered regenerating liquid is separated by adding an alkali to the regenerating liquid which is used for regenerating the metal chelate resin and recovered and stripping the alkali-added recovered regenerating liquid by steam or the like. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供一种用于除去待处理水中的氨氮的方法和装置,其中每一种氨氮可以选择性地从待处理的水中除去,并且不仅包含 高浓度碱金属离子和/或高浓度碱土金属离子而且还含有氨氮。 解决方案:通过使用金属螯合树脂从待处理的水中除去氨氮,不仅含有碱金属离子和/或碱土金属离子,而且含有氨氮,如果pH为 要适当调节待处理的水,只有氨能够在金属螯合树脂上选择性吸附,而不会在金属螯合树脂上吸附碱金属离子和/或碱土金属离子。 如果只有氨被选择性地吸附的金属螯合树脂被再生,则再生金属螯合树脂可以再次用于除去待处理水中的氨氮。 通过向用于再生金属螯合树脂的再生液中添加碱分离回收的回收再生液中的氨,并通过蒸汽等回收和汽提碱添加的回收再生液。 版权所有(C)2006,JPO&NCIPI
    • 7. 发明专利
    • Coal gasification equipment
    • 煤气化设备
    • JP2003020486A
    • 2003-01-24
    • JP2001205644
    • 2001-07-06
    • Babcock Hitachi Kkバブコック日立株式会社
    • YAMADA RIKUOUEDA AKIOYOSHIDA KUNIKATSUYAMAGUCHI EIJI
    • C10J3/00C10J3/02
    • Y02E20/18Y02P20/124
    • PROBLEM TO BE SOLVED: To prevent condensation of inorganic compounds at the heat recovery unit and the char recovery unit of coal gasification equipment. SOLUTION: This coal gasification equipment is equipped with a coal gasification furnace, the heat recovery unit, the char recovery unit and a feeder line. The heat recovery unit recovers heat in generated gas generated in the coal gasification furnace. The char recovery unit recovers char contained in the generated gas exhausted from the heat recovery unit and returns recovered char to the coal gasification furnace. The feeder line feeds a second inorganic compound for converting a first inorganic compound contained in the generated gas and condensed at least at either one temperature of the heat recovery unit or the char recovery unit.
    • 要解决的问题:防止煤气化设备的热回收装置和炭回收装置的无机化合物的冷凝。 解决方案:该煤气化设备配备了煤气化炉,热回收装置,炭回收装置和送料线。 热回收装置回收煤气化炉产生的气体中的热量。 炭回收单元回收从热回收单元排出的产生的气体中包含的焦炭,并将回收的焦炭返回到煤气化炉。 供料管线供给第二无机化合物,用于转化产生的气体中所含的第一无机化合物,并至少在热回收单元或炭回收单元的一个温度下冷凝。
    • 9. 发明专利
    • Method for treating waste water containing tetraalkylammonium hydroxide
    • 用于处理含有四氢氨基氢氧化镁的废水的方法
    • JP2003340449A
    • 2003-12-02
    • JP2002152352
    • 2002-05-27
    • Babcock Hitachi Kkバブコック日立株式会社
    • YAMADA RIKUOSATO KAZUNORITANIGUCHI YUKIHISAMIZOGUCHI TADAAKI
    • C02F1/42B01D9/02B01J49/00C02F1/58
    • PROBLEM TO BE SOLVED: To provide a method for treating waste water containing a tetraalkylammonium hydroxide (TMAH) by which waste water containing the tetraalkylammonium hydroxide and containing a photoresist is efficiently treated and the TMAH can be regenerated and recovered. SOLUTION: The method for adsorbing and removing tetraalkylammonium cations by using a cation exchange resin and for recovering the cations as salts from waste water containing the photoresist and the tetraalkylammonium hydroxide includes the following processes: the photoresist is preliminarily removed while keeping the waste water near neutral to weak acid; then the waste liquid is passed through the cation exchange resin to adsorb the tetraalkylammonium cations; the cation exchange resin is regenerated by an acid, while the tetraalkylammonium salts are recovered in a regenerating liquid; an aqueous solution of perchloric acid is added to the liquid to crystallize the perchlorate of tetraalkylammonium to be recovered. COPYRIGHT: (C)2004,JPO
    • 要解决的问题:提供一种处理含有四烷基氢氧化铵(TMAH)的废水的方法,通过该方法可以有效地处理含有四烷基氢氧化铵的废水并含有光致抗蚀剂,并且可以再生和回收TMAH。 解决方案:通过使用阳离子交换树脂吸附和除去四烷基铵阳离子并从含有光致抗蚀剂和四烷基氢氧化铵的废水中回收阳离子的方法包括以下过程:预先除去光致抗蚀剂,同时保持废物 水接近中性至弱酸; 然后废液通过阳离子交换树脂吸附四烷基铵阳离子; 阳离子交换树脂由酸再生,而四烷基铵盐在再生液中回收; 将高氯酸水溶液加入到液体中以结晶待回收的四烷基铵的高氯酸盐。 版权所有(C)2004,JPO