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1. 发明专利

JP2005297220A Resin-made panel 有权
标题翻译：树脂制板
公开(公告)号：JP2005297220A
公开(公告)日：2005-10-27
申请号：JP2004112482
申请日：2004-04-06
申请人： Asahi Glass Matex Co Ltd , Kajima Corp , Showa Highpolymer Co Ltd , 旭硝子マテックス株式会社 , 昭和高分子株式会社 , 鹿島建設株式会社
发明人： NAKAGAWA HIROAKI , OUCHI TOMIO , INABA YOHEI , SASAKI MASAHARU , NISHIMOTO TAKASHI , ITOHIYA TAKESHI , HASHIBA TAKASHI , MAKIYO TAKESHI
IPC分类号： E04B1/94 , B29C44/00 , B29C70/52 , B29C70/68 , B29K61/04 , B29L31/10 , B32B3/18 , B32B5/24 , B32B27/42 , E04C2/20
摘要： PROBLEM TO BE SOLVED: To obtain a resin-made panel with improved fire resistant performances such as heat resistance, fire resistance and explosion resistance while such FRP characteristics as lightweight and high specific strength are sufficiently exhibited.
SOLUTION: The resin-made panel is prepared by wrapping a core material comprising a phenolic resin foam in a panel-like outer skin material comprising a fiber-reinforced phenolic resin. It is characterized by that the core material comprises the phenolic resin foam with a density of 0.05-0.35 g/cm
3 comprising 30-150 pts.wt. filler to 100 pts.wt. phenolic resin, the outer skin material comprises the fiber-reinforced phenolic resin with a water content of ≤1 wt.%, the core material and the outer skin material are tightly stuck together, and a sheet composed of a fiber is buried in the outer skin material.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：获得具有耐热性，耐火性和耐爆性的耐火性能提高的树脂制面板，同时充分发挥轻质，高比强度的FRP特性。解决方案：通过将包含酚醛树脂泡沫的芯材包裹在包含纤维增强酚醛树脂的面板状外皮材料中来制备树脂制面板。其特征在于芯材包括密度为0.05-0.35g / cm 3的三元酚醛树脂泡沫，包括30-150重量份。填料至100重量份酚醛树脂，外皮材料包括水含量≤1重量％的纤维增强酚醛树脂，芯材和外皮材料紧紧粘合在一起，由纤维组成的片材埋在外层皮肤材料。版权所有（C）2006，JPO＆NCIPI

2. 发明专利

JP2002052617A METHOD FOR MANUFACTURING FIBER REINFORCED COMPOSITE MATERIAL 失效
公开(公告)号：JP2002052617A
公开(公告)日：2002-02-19
申请号：JP2000238278
申请日：2000-08-07
申请人： SHOWA HIGHPOLYMER , ASAHI GLASS MATEX CO LTD
发明人： MAKIYO TAKESHI , HASHIBA TAKASHI , NISHIMOTO SATOSHI , OSHIMA GEN
IPC分类号： C08J9/14 , B29C39/16 , B29C39/18 , B29C69/02
摘要： PROBLEM TO BE SOLVED: To provide a method for continuously manufacturing a fiber reinforced composite material internally filled with uniform foam, having an arbitrary cross section and having a skin layer of which the thickness is constant in a length direction. SOLUTION: A fiber reinforcing material impregnated with a liquid fire retardant thermosetting resin material is continuously drawn in the gap between the inner and outer molds of a heating mold having the inner and outer molds and cured under heating to mold a surface material. After the surface temperature of the surface material is cooled to 100 deg.C or lower, a low temperature curable phenolic resin foamable liquid containing a foaming agent is continuously discharged in the internal space of the surface material, foamed and cured to manufacture the reinforced composite material having a foamed layer therein.

3. 发明专利

JPS61136527A Production of fiber-reinforced phenolic resin molding 失效
标题翻译：生产纤维增强酚醛树脂模塑
公开(公告)号：JPS61136527A
公开(公告)日：1986-06-24
申请号：JP25769184
申请日：1984-12-07
申请人： Showa Highpolymer Co Ltd
发明人： HASHIBA TAKASHI
IPC分类号： C08L61/00 , C08J5/24 , C08K5/52 , C08L61/04 , C08L61/14
摘要： PURPOSE: To obtain a room temperature or medium temperature-curable fiber- reinforced phenolic resin molding excellent in workability, curability and corrosiveness, by impregnating fiber with a liquid resol phenolic resin containing a specified acidic curing agent and curing the resin.
CONSTITUTION: The desired fiber-reinforced phenolic resin molding is obtained by adding an acidic curing agent comprising 90W20wt% (in terms of solids) sulfonated resin of a degree of sulfonation (100 × the ratio of the number of sulfonated phenolic nuclei to the total number of phenolic nuclei) of 20W70 and 10W80wt% (in terms of solids) acidic phosphate ester to a liquid resol phenolic resin, impregnating fiber with the obtained mixture and curing the mixture.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过用含有特定酸性固化剂的液体酚醛树脂浸渍纤维并固化树脂，获得加工性，固化性和腐蚀性优异的室温或中温固化纤维增强酚醛树脂成型。构成：所需的纤维增强酚醛树脂成型是通过加入含有90〜20wt％（以固体计）的磺化磺化树脂的酸性固化剂（100X，磺化酚醛核的数量与酚核的总数）为20-70和10-80wt％（以固体计）的酸性磷酸酯与液体酚醛树脂酚醛树脂，用所得混合物浸渍纤维并固化该混合物。

4. 发明专利

JPS59140236A Production of phenolic resin foam 失效
标题翻译：苯酚树脂泡沫的生产
公开(公告)号：JPS59140236A
公开(公告)日：1984-08-11
申请号：JP1379583
申请日：1983-02-01
申请人： Showa Highpolymer Co Ltd
发明人： HASHIBA TAKASHI
IPC分类号： C08J9/04
摘要： PURPOSE: To obtain a phenolic resin foam improved in corrosiveness, by mixing a resol phenolic resin with sodium sulfite, adding an acidic curing agent, and foaming and curing the mixture.
CONSTITUTION: The desired phenolic resin foam is produced by adding 5W 40pts.wt. sodium sulfite to 100pts.wt. resol phenolic resin in the presence of an acidic curing agent, a blowing agent, and a surfactant, and foaming and curing the mixture. The sodium sulfite to be used above may be anhydrous or hydrated, and its form is preferably fine powder of about 40W100 mesh. It is preferably predispersed in the resol phenolic resin.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过将酚醛树脂酚醛树脂与亚硫酸钠混合，加入酸性固化剂，发泡和固化混合物，获得改善了腐蚀性的酚醛树脂泡沫。构成：所需的酚醛树脂泡沫是通过加入5-40pts.wt。亚硫酸钠至100pts.wt。在酸性固化剂，发泡剂和表面活性剂的存在下，分解酚醛树脂，并使混合物发泡和固化。上述使用的亚硫酸钠可以是无水或水合的，其形式优选为约40-100目的细粉末。优选在分解酚醛树脂中预先分散。

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