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    • 1. 发明专利
    • Manufacturing method of cathode material for lithium-ion battery
    • 锂离子电池阴极材料的制造方法
    • JP2007250203A
    • 2007-09-27
    • JP2006067784
    • 2006-03-13
    • Akita Univ国立大学法人秋田大学
    • OKAWA KOICHIYABUKI JUNPEI
    • H01M4/58C01B25/37C01B25/45H01M4/02H01M10/05H01M10/0525
    • Y02P70/54
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a cathode material for a lithium-ion battery obtaining an iron-containing cathode active material by irradiating ultrasonic waves on a starting material for chemical reaction. SOLUTION: In a schematic diagram of an ultrasonic synthesizer, 1 is a multi-frequency ultrasonic generating device, 2 is an oscillator, 3 is an eggplant-shaped flask, 4 is a stirrer, 5 is a gas injection inlet, and 6 is a water tank. LiOH-H 2 O, FeSO 4 -7H 2 O, and (NH 4 ) 2 HPO 4 are used as starting materials for the ultrasonic synthesization of LiFePO 4 , which are weighed in a molar ratio of 2.5:1:1, put in the flask 3, and have preliminarily dried pure water added by 40 ml, after that, argon gas is injected from the gas injection inlet 5 and 200Hz, 200W ultrasonic waves are irradiated on them for three hours by the oscillator 2 of the multi-frequency ultrasonic generating device 1, and they are dried in the argon gas at 700°C to obtain the LiFePO 4 . COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:提供一种通过在化学反应原料上照射超声波来获得含铁正极活性物质的锂离子电池用正极材料的制造方法。 解决方案:在超声波合成器的示意图中,1是多频超声波发生装置,2是振荡器,3是茄形烧瓶,4是搅拌器,5是气体注入口, 6是水箱。 LiOH-H 2,SBSO 4,SBH 2,和(NH 4 SB SB)2 HPO 4 用作超声波合成LiFePO 4 SBB的原料,以2.5:1:1的摩尔比称量,放入 烧瓶3中,将预先干燥的纯水加入40ml,然后从气体注入口5和200Hz注入氩气,通过多频超声波振荡器2将200W超声波照射3小时 在700℃的氩气中进行干燥,得到LiFePO SB 7。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Ultrasonic irradiation apparatus
    • 超声波辐射装置
    • JP2011206094A
    • 2011-10-20
    • JP2010074014
    • 2010-03-29
    • Akita Univ国立大学法人秋田大学
    • OKAWA KOICHIKUME MAKOTOYAMAMOTO YUZOSUGAWARA KATSUYASUSATO KANA
    • A61B18/00
    • PROBLEM TO BE SOLVED: To provide an appropriate ultrasonic irradiation apparatus to be used for applying a pre-conditioning method for inducing the stress resistance in a solid organ of a living body.SOLUTION: The ultrasonic irradiation apparatus 10 includes: an ultrasonic transducer 20 for generating ultrasonic waves; a casing 30 as a transmission member for transmitting the ultrasonic waves generated in the ultrasonic transducer to an object 70 including a liquid; and a cooling part 40 for retaining the temperature of the object at target temperature. Cavitation is generated in the liquid by the irradiation of ultrasonic waves while the temperature of the object is retained at the target temperature by the cooling part, and an activated chemical species produced by the chemical action of the cavitation is loaded onto the object as an oxidation stress.
    • 要解决的问题:提供一种适用于在活体的实心器官中施加用于诱导抗压力的预调节方法的超声波照射装置。解决方案:超声波照射装置10包括:超声波换能器20,用于 产生超声波; 作为用于将超声波换能器中产生的超声波发送到包括液体的物体70的传递部件的壳体30; 以及用于将物体的温度保持在目标温度的冷却部40。 通过超声波的照射在液体中产生气蚀,同时通过冷却部将物体的温度保持在目标温度,并且通过空化的化学作用产生的活化化学物质作为氧化被加载到物体上 强调。
    • 6. 发明专利
    • Agent for and method of purifying heavy metal-containing solution
    • 净化重金属含量溶液的方法和方法
    • JP2008229426A
    • 2008-10-02
    • JP2007069669
    • 2007-03-17
    • Akita Univ国立大学法人秋田大学
    • OKAWA KOICHI
    • C02F1/70C01F11/00C01G37/033C01G49/00C02F1/62C09K3/00
    • PROBLEM TO BE SOLVED: To deposit metals contained in tuff or the like on the surface of the stone by using an acid to obtain deposits, the depositing solution, and the stone to which deposits stick as a purifying agent for a heavy metal-containing solution.
      SOLUTION: (1) Green tuff, the acid, and water are mixed in the mixing process. The green tuff is desirably a fine particle having a particle size of 3 mm or less. A weak acid or a strong acid is used as the acid. The water infiltrates the porous parts of the stone to play a role in carrying the acid into the stone and a role in moving iron and other metal ions eluted from the inside of the stone to the surface thereof, (2) The mixed sample is sufficiently reacted in the standing process. (3) Unreacted remaining acid is removed in the washing process. (4) Compounds containing metals, mainly iron, deposited on the surface of the green tuff are removed efficiently, and collected efficiently in the ultrasonic treatment process.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:通过使用酸将凝灰岩等中含有的金属沉积在石材的表面上以获得沉积物,沉积溶液和沉积物作为重金属的净化剂粘附的石头 含有解决方案。

      解决方案:(1)在混合过程中,将绿色凝灰岩,酸和水混合。 绿色凝灰岩理想地为粒径为3mm以下的细小颗粒。 弱酸或强酸用作酸。 水渗入石头的多孔部分,起到将石灰携带的作用,并将铁和其他金属离子从石头内部洗脱到其表面的作用;(2)混合样品充分 在常规过程中作出反应。 (3)在洗涤过程中除去未反应的剩余酸。 (4)沉积在绿色凝灰岩表面上的金属(主要是铁)的化合物被有效去除,并在超声处理过程中有效地收集。 版权所有(C)2009,JPO&INPIT

    • 7. 发明专利
    • Method for inhibiting acicular whisker from forming on tin plating film
    • 用于抑制凝胶膜上形成乳化剂的方法
    • JP2008280559A
    • 2008-11-20
    • JP2007123976
    • 2007-05-08
    • Akita Univ国立大学法人秋田大学
    • MORIKAWA SHIGEHIROKAMIYA OSAMUOKAWA KOICHI
    • C25D5/48C25D7/00H01R43/00H01R43/16
    • PROBLEM TO BE SOLVED: To provide a method for inhibiting an acicular whisker from forming in a tin plating film on a connector or a terminal which is a small and high-density packaged electronic component plated with tin or a metal mainly containing tin and no lead.
      SOLUTION: This inhibiting method includes irradiating the connector or the terminal 2 plated with tin or the metal mainly containing tin and no lead with an ultrasonic wave in a solution 7 in which a reducing reaction field is formed. The method is regarded as a simple post-treatment of a plating process or a working process, which can supply the connector or the terminal component that makes no acicular whisker formed thereon similarly to a conventional plating film of a metal containing lead.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种抑制针状晶须在连接器或端子上形成的镀锡膜的方法,该连接器或端子是电镀锡或主要含有锡的金属的小而高密度封装的电子部件 没有铅。 解决方案:该抑制方法包括在形成还原反应场的溶液7中照射镀锡锡或主要含有锡的金属并且不含超声波的铅的端子2。 该方法被认为是电镀工艺或工作过程的简单后处理,其可以像常规的含金属铅的镀膜一样提供不形成针状晶须的连接器或端子部件。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Aqueous solution containing nitrogen using ultrasonic wave, fertilizer and device for producing fertilizer
    • 使用超声波,肥料和生产肥料的装置含有氮的水溶液
    • JP2008201637A
    • 2008-09-04
    • JP2007041553
    • 2007-02-22
    • Akita UnivNakano Sangyo Kk中野産業株式会社国立大学法人秋田大学
    • OKAWA KOICHITAKAHATA SHIGEYUKINAKAMURA TAKASHI
    • C01B21/38B01J19/10C05C5/00C05D1/00C05D5/00C05G1/00C05G5/00
    • PROBLEM TO BE SOLVED: To provide a technique for fixing nitrogen in an aqueous solution, and to provide, in particular, an aqueous solution containing nitrogen using an ultrasonic wave, a fertilizer produced by the technique and a device for producing the fertilizer.
      SOLUTION: The technique for fixing nitrogen in air to an aqueous solution comprises radiating the ultrasonic wave to water and an aqueous solution. A multi frequency ultrasonic wave generator is indicated by 1; a vibrator is indicated by 2; an eggplant-shaped flask is indicated by 3; a water tank is indicated by 4 and a gas introduction pipe is indicated by 5. Necessary starting materials are only water and air and the trouble for collecting materials and material costs are eliminated. The aqueous solution contains nitrogen and is best suited as a fertilizer. Optionally, by adding a natural mineral and a natural stone such as green tuff to the aqueous solution either before or after irradiation of the ultrasonic wave, minerals from the stone can be used and buffering action by eluted minerals maintains the pH around neutral.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种将氮固定在水溶液中的技术,特别是使用超声波提供含氮的水溶液,通过该技术生产的肥料和用于生产肥料的装置 。 解决方案:将空气中的氮固定在水溶液中的技术包括将超声波辐射到水和水溶液中。 多频超声波发生器由1表示; 振动器由2表示; 茄形烧瓶由3表示; 一个水箱由4表示,气体引入管由5表示。必要的起始材料只是水和空气,消除了收集材料和材料成本的麻烦。 水溶液含氮,最适合作为肥料。 任选地,通过在超声波照射之前或之后向水溶液中加入天然矿物和天然石料如绿色凝灰岩,可以使用来自石头的矿物质,并且通过洗脱的矿物质的缓冲作用将pH保持在中性附近。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • POSITIVE ELECTRODE ACTIVE MATERIAL FOR Li ION BATTERY, AND ITS MANUFACTURING METHOD
    • 用于锂离子电池的正极电极活性材料及其制造方法
    • JP2011210376A
    • 2011-10-20
    • JP2010073965
    • 2010-03-28
    • Akita UnivNiigata Univ国立大学法人 新潟大学国立大学法人秋田大学
    • SATO MINEOUEMATSU KAZUYOSHITSUJI HIROETSUTODA KENJIISHIGAKI MASAOKAWA KOICHI
    • H01M4/58C01B25/45C01B31/02H01M4/36
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a positive electrode active material for Li ion battery having a very large discharge capacity and excellent cycle characteristics and its manufacturing method.SOLUTION: The manufacturing method of a positive electrode active material for Li ion battery in which carbon particulates exist on the surface of LiFePOcomprises in order (A) a step in which a lithium compound, an iron compound, and a phosphate compound are mixed and a raw material mixture is produced, (B) a step in which the raw material mixture is temporarily calcined in an inert atmosphere, a reducing atmosphere, or in a vacuum atmosphere, and the temporary calcined object is produced, (C) a step in which a polymer material is mixed in the temporary calcined object, and a calcined object is produced, and (D) a step in which the calcined object is calcined in an inert atmosphere, a reducing atmosphere, or a vacuum atmosphere. The positive electrode active material for Li ion battery manufactured by this manufacturing method is provided.
    • 要解决的问题:提供具有非常大的放电容量和优异的循环特性的锂离子电池用正极活性物质及其制造方法。解决方案:其中碳粒子的锂离子电池用正极活性物质的制造方法 按照(A)将锂化合物,铁化合物和磷酸盐化合物混合并制造原料混合物的步骤,(B)将原料混合物暂时性化的工序,存在于LiFePO组装体的表面上 在惰性气氛中还原气氛中或在真空气氛中煅烧,并制备临时煅烧物体,(C)将聚合物材料混合在临时煅烧物中的步骤,生成煅烧物, (D)煅烧物体在惰性气氛,还原气氛或真空气氛中煅烧的步骤。 提供了通过该制造方法制造的用于锂离子电池的正极活性物质。