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    • 2. 发明专利
    • Conjugate fiber and porous fiber using the same
    • 使用相同的纤维和多孔纤维
    • JP2010189829A
    • 2010-09-02
    • JP2010007518
    • 2010-01-15
    • Nippon Synthetic Chem Ind Co Ltd:The日本合成化学工業株式会社
    • SHIBUYA MITSUOSAKAI NORITOINOUE KAORU
    • D01F8/10
    • PROBLEM TO BE SOLVED: To provide an EVOH-based porous fiber further improved in cool feeling property, and to provide a conjugate fiber for obtaining the porous fiber. SOLUTION: The conjugate fiber has a sea-island structure comprising an ethylene-vinylester copolymer saponified product as the sea component and a polyvinyl alcohol-based copolymer having a structural unit represented by the general formula (1) as the island component. [Wherein, R 1 , R 2 , and R 3 are each independently a hydrogen atom or an organic group; X is a single bond or a bonding chain; and R 4 , R 5 , and R 6 are each independently a hydrogen atom or an organic group]. The porous fiber is obtained by treating the conjugate fiber with water to dissolve and remove at least a part of the polyvinyl alcohol-based copolymer from the conjugate fiber. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供进一步提高冷感特性的EVOH基多孔纤维,并提供用于获得多孔纤维的复合纤维。 解决方案:复合纤维具有包含作为海成分的乙烯 - 乙烯基酯共聚物皂化产物和具有由通式(1)表示的结构单元作为岛成分的聚乙烯醇类共聚物的海岛结构。 [其中,R 1 ,R 2 和R 3 各自独立地为氢原子或有机基团; X是单键或键合链; R 4和R 6各自独立地为氢原子或有机基团。 多孔纤维通过用水处理复合纤维获得,从共轭纤维中溶解并除去至少一部分聚乙烯醇类共聚物。 版权所有(C)2010,JPO&INPIT
    • 6. 发明专利
    • Multilayer structure
    • 多层结构
    • JP2011051175A
    • 2011-03-17
    • JP2009200938
    • 2009-08-31
    • Mitsubishi Chemicals CorpNippon Synthetic Chem Ind Co Ltd:The三菱化学株式会社日本合成化学工業株式会社
    • KAWABE MASAYUKISHIBUYA MITSUOINOUE KAORUSAKAI NORITO
    • B32B27/30
    • PROBLEM TO BE SOLVED: To provide a multilayer structure which is improved in interlayer adhesion and excellent in interlayer peeling resistance. SOLUTION: The multilayer structure has a layer structure in which a layer (A) containing a polyethylene terephthalate resin as a main component which comprises a dicarboxylic acid component unit having terephthalic acid and a diol component unit containing ethylene glycol as a main component and contains a polyethylene terephthalate resin having a terminal carboxyl group concentration of 15-60 equivalent/ton and a layer (B) containing a polyvinyl alcohol resin having a structural unit expressed by a specified formula as a main component which is adjacent to the layer (A) are laminated. COPYRIGHT: (C)2011,JPO&INPIT
    • 解决的问题:提供层间粘合性提高,层间剥离性优异的多层结构。 解决方案:多层结构具有层结构,其中包含以聚对苯二甲酸乙二醇酯树脂为主要成分的层(A),其包含具有对苯二甲酸的二羧酸组分单元和含有乙二醇作为主要成分的二醇组分单元 并且含有末端羧基浓度为15〜60当量/吨的聚对苯二甲酸乙二醇酯树脂和含有具有以规定式表示的结构单元作为主要成分的与该层相邻的聚乙烯醇树脂的层(B) A)层压。 版权所有(C)2011,JPO&INPIT
    • 7. 发明专利
    • Multilayer structure
    • 多层结构
    • JP2011051173A
    • 2011-03-17
    • JP2009200936
    • 2009-08-31
    • Mitsubishi Chemicals CorpNippon Synthetic Chem Ind Co Ltd:The三菱化学株式会社日本合成化学工業株式会社
    • KAWABE MASAYUKISHIBUYA MITSUOINOUE KAORUSAKAI NORITO
    • B32B27/30
    • PROBLEM TO BE SOLVED: To provide a multilayer structure which is improved in interlayer adhesion and excellent in interlayer peeling resistance. SOLUTION: The multilayer structure has a layer structure in which a layer (A) containing a polyethylene terephthalate resin which has a dicarboxylic acid component unit having terephthalic acid and a diol component unit having ethylene glycol as a main component and in which the copolymerization ratio of dicarboxylic acids other than terephthalic acid in the dicarboxylic acid component is 15-40 mol% of a total dicarboxylic acid component as a main component and a layer (B) containing a polyvinyl alcohol resin having a structural unit expressed by a specified formula as a main component which is adjacent to the layer (A) are laminated. COPYRIGHT: (C)2011,JPO&INPIT
    • 解决的问题:提供层间粘合性提高,层间剥离性优异的多层结构。 解决方案:多层结构具有层结构,其中含有具有对苯二甲酸的二羧酸组分单元和具有乙二醇作为主要成分的二醇组分单元的聚对苯二甲酸乙二醇酯树脂的层(A),其中, 二羧酸成分中的对苯二甲酸以外的二羧酸的共聚比为总二羧酸成分为主要成分的15〜40摩尔%,含有具有由规定式表示的结构单元的聚乙烯醇树脂的层(B) 作为与层(A)相邻的主要成分。 版权所有(C)2011,JPO&INPIT
    • 8. 发明专利
    • Polyvinyl alcohol-based resin composition, method for producing the same, and film using the resin composition
    • 基于聚乙烯醇的树脂组合物,其制备方法和使用树脂组合物的薄膜
    • JP2013227530A
    • 2013-11-07
    • JP2013061382
    • 2013-03-25
    • Nippon Synthetic Chem Ind Co Ltd:The日本合成化学工業株式会社
    • INOUE KAORUSAKAI NORITO
    • C08L29/04C08J3/20C08K5/053
    • PROBLEM TO BE SOLVED: To provide a polyvinyl alcohol-based resin composition from which molded articles, such as films, having all of gas barrier property, flexibility, and biodegradability can be produced, and to provide a method for producing the resin composition and films using the resin composition.SOLUTION: A polyvinyl alcohol-based resin composition has a sea-island structure where an island phase containing a polyvinyl alcohol-based resin (B) having a degree of saponification of 70-90 mol% and a polyhydric alcohol compound (C) is formed in a sea phase of a polyvinyl alcohol-based resin (A) having a degree of saponification of ≥95 mol%. A method for producing the polyvinyl alcohol-based resin composition includes preparing a mixture of the polyvinyl alcohol-based resin (B) and the polyhydric alcohol compound (C) and then melt-kneading the mixture and the polyvinyl alcohol-based resin (A). A film at least has a layer containing the polyvinyl alcohol-based resin composition.
    • 要解决的问题:提供一种聚乙烯醇系树脂组合物,可以制造具有全部阻气性,柔软性和生物降解性的成膜体,例如膜,并且提供一种树脂组合物和膜的制造方法 使用树脂组合物。解决方案:聚乙烯醇类树脂组合物具有海岛结构,其中含有皂化度为70〜90摩尔%的聚乙烯醇系树脂(B)和多元醇化合物 (C)在皂化度≥95摩尔%的聚乙烯醇系树脂(A)的海相中形成。 聚乙烯醇类树脂组合物的制造方法包括制备聚乙烯醇类树脂(B)和多元醇化合物(C)的混合物,然后将混合物和聚乙烯醇系树脂(A)熔融混炼, 。 膜至少具有含有聚乙烯醇系树脂组合物的层。
    • 10. 发明专利
    • Resin composition and molded article thereof
    • 树脂组合物及其成型品
    • JP2011074364A
    • 2011-04-14
    • JP2010191878
    • 2010-08-30
    • Nippon Synthetic Chem Ind Co Ltd:The日本合成化学工業株式会社
    • SHIBUYA MITSUOTSUJI KAZUTOSHIINOUE KAORUSAKAI NORITO
    • C08L29/04C08F8/12C08F16/04C08L53/02
    • C08L29/04C08L53/02C08L53/025C08L2205/02C08L2205/03
    • PROBLEM TO BE SOLVED: To provide a resin composition, from which a melt-molded article with superior gas barrier properties and flex fatigue resistance can be obtained.
      SOLUTION: The resin composition contains: a polyvinyl alcohol polymer (A) which has a structure unit expressed by general formula (1); and a block copolymer (B) which has a polymer block of an aromatic vinyl compound and a polymer block of a conjugated diene compound and/or a hydrogenated block thereof, wherein the block copolymer (B) is a combination of a block copolymer (B1) which has no carboxyl group and a block copolymer (B2) which has a carboxyl group. In the formula, R
      1 , R
      2 and R
      3 respectively and independently denote a hydrogen atom or an organic group, X denotes a single bond or a bonding chain and R
      4 , R
      5 and R
      6 respectively and independently denote a hydrogen atom or an organic group.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 待解决的问题:为了提供一种树脂组合物,可以获得具有优异的阻气性和抗挠曲疲劳性的熔融模塑制品。 解决方案:树脂组合物包含:具有由通式(1)表示的结构单元的聚乙烯醇聚合物(A); 和具有芳族乙烯基化合物的聚合物嵌段和共轭二烯化合物的聚合物嵌段和/或其氢化嵌段的嵌段共聚物(B),其中嵌段共聚物(B)是嵌段共聚物(B1 )和具有羧基的嵌段共聚物(B2)。 在该式中,R“SP”1,R“SP”2“和”SP“3分别独立地表示氢原子或有机基团,X表示单键 或者R 4 ,R SP< SP>和< SP> 6< SP>分别独立地表示氢原子或有机基团。 版权所有(C)2011,JPO&INPIT