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    • 2. 发明专利
    • Silicon carbide semiconductor element manufacturing method and silicon carbide semiconductor element
    • 硅碳化硅半导体元件制造方法和碳化硅半导体元件
    • JP2014123768A
    • 2014-07-03
    • JP2014040546
    • 2014-03-03
    • Fuji Electric Co Ltd富士電機株式会社
    • KAWADA YASUYUKITAWARA TAKESHI
    • H01L29/78H01L21/3065H01L21/336H01L29/12
    • PROBLEM TO BE SOLVED: To provide a silicon carbide semiconductor element manufacturing method and a silicon carbide semiconductor element, which can reduce element defect.SOLUTION: A silicon carbide semiconductor element 100 comprises a trench 1 in which a trench connection part 5 is connected to a trench linear part 2. The trench linear part 2 includes a first line constitution part 2a and a second line constitution part 2b which are arranged in parallel with each other. The trench connection part 5 includes a first connection constitution part 3 perpendicular to the trench linear part 2, a second connection constitution part 4a for connecting the first line constitution part 2a and the first connection constitution part 3, and a third connection constitution part 4b for connecting the second line constitution part 2b and an extension of the first connection constitution part 3. An angle between the second connection constitution part 4a and the first line constitution part 2a is 30 degrees. An angle between the third connection constitution part 4b and an extension of the second line constitution part 2b is 30 degrees.
    • 要解决的问题:提供可以减少元件缺陷的碳化硅半导体元件制造方法和碳化硅半导体元件。解决方案:碳化硅半导体元件100包括沟槽1,其中沟槽连接部分5连接到 沟槽直线部分2包括彼此平行布置的第一线构成部分2a和第二线构成部分2b。 沟槽连接部分5包括垂直于沟槽线性部分2的第一连接构造部分3,用于连接第一线路构成部分2a和第一连接构造部分3的第二连接构造部分4a和用于 连接第二线路构成部分2b和第一连接构造部分3的延伸部分。第二连接构造部分4a和第一线路结构部分2a之间的角度为30度。 第三连接构造部4b与第二线构成部2b的延伸之间的角度为30度。
    • 4. 发明专利
    • Silicon carbide semiconductor device manufacturing method
    • 硅碳化硅半导体器件制造方法
    • JP2014099483A
    • 2014-05-29
    • JP2012249763
    • 2012-11-13
    • Fuji Electric Co Ltd富士電機株式会社
    • KAWADA YASUYUKIYONEZAWA YOSHIYUKI
    • H01L21/205C23C16/42C30B25/20C30B29/36H01L21/336H01L29/12H01L29/78
    • H01L21/02529C30B25/10C30B25/16C30B25/20C30B29/36H01L21/02378H01L21/0262H01L21/0445H01L29/045H01L29/1608H01L29/78
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a silicon carbide semiconductor device having a long carrier lifetime without performing an additional process after manufacturing an SiC single crystal substrate by a chemical vapor deposition method.SOLUTION: A silicon carbide semiconductor device manufacturing method comprises: adjusting a temperature inside a reaction furnace to 1700°C (step S5); subsequently, introducing a material gas, an added gas, a doping gas and a carrier gas into the reaction furnace (step S6); subsequently, growing an SiC epitaxial film on a surface of a 4H-SiC substrate by a CVD method (step S7); subsequently, cooling the 4H-SiC substrate on which the SiC epitaxial film is stacked in an atmosphere of a hydrogen gas diluted methyl methane gas until the temperature inside the reaction furnace decreases from 1700°C to 1300°C (step S8); and subsequently, cooling the 4H-SiC substrate on which the SiC epitaxial film is stacked in a hydrogen gas atmosphere until the temperature inside the reaction furnace decreases to a temperature lower than 1300°C (step S9).
    • 要解决的问题:提供一种具有长载流子寿命的碳化硅半导体器件的制造方法,而不需要通过化学气相沉积方法在制造SiC单晶衬底之后执行附加工艺。解决方案:一种碳化硅半导体器件制造方法包括 :将反应炉内的温度调节至1700℃(步骤S5); 随后将材料气体,添加的气体,掺杂气体和载气引入反应炉中(步骤S6); 随后,通过CVD法在4H-SiC衬底的表面上生长SiC外延膜(步骤S7); 随后,在氢气稀释的甲基甲烷气体的气氛中冷却其上层叠有SiC外延膜的4H-SiC衬底,直到反应炉内的温度从1700℃降低到1300℃(步骤S8); 然后在氢气气氛中冷却SiC外延膜层叠的4H-SiC基板,直到反应炉内的温度降低到低于1300℃的温度(步骤S9)。
    • 5. 发明专利
    • Silicon carbide semiconductor device manufacturing method
    • 硅碳化硅半导体器件制造方法
    • JP2014053511A
    • 2014-03-20
    • JP2012197948
    • 2012-09-07
    • Fuji Electric Co Ltd富士電機株式会社Mitsubishi Electric Corp三菱電機株式会社
    • KAWADA YASUYUKITOMITA NOBUYUKI
    • H01L21/205C23C16/42
    • PROBLEM TO BE SOLVED: To provide a silicon carbide semiconductor device manufacturing method which can grow a silicon carbide semiconductor film having high crystal quality at high speed.SOLUTION: A silicon carbide semiconductor device manufacturing method comprises: introducing a material gas, an added gas, a doping gas and a carrier gas into a reacting furnace (step S5); and subsequently growing an SiC epitaxial film on a surface of a 4H-SiC substrate in a CVD method by using the material gas, the added gas, the doping gas and the carrier gas to manufacture an SiC single crystal substrate (step S6). As the material gas, an Si-containing gas and a C-containing gas are used. As the added ga, a Cl-containing gas and a F-containing gas are used. As a carrier gas, an Hgas is used. The gas which contains Cl within a range where a ratio of the number of Cl atoms to the number of Si atoms in the Si-containing gas is 2.0 or more and 5.0 or less is added. The gas which contains F within a range where a ratio of the number of F atoms to the number of H atoms in the carrier gas is 0.1 or more and 0.2 or less is added.
    • 要解决的问题:提供一种可以高速生长具有高晶体质量的碳化硅半导体膜的碳化硅半导体器件制造方法。解决方案:一种碳化硅半导体器件的制造方法,包括:引入原料气体,添加的气体, 掺杂气体和载气进入反应炉(步骤S5); 然后通过使用原料气体,添加的气体,掺杂气体和载气在CVD法中在4H-SiC衬底的表面上生长SiC外延膜,制造SiC单晶衬底(步骤S6)。 作为原料气体,使用含Si气体和含C气体。 作为添加的ga,使用含Cl的气体和含F的气体。 作为载气,使用H气。 在含有气体中的Cl原子数与Si原子数的比例为2.0以上且5.0以下的范围内含有Cl的气体。 在载体气体中F原子数与H原子数的比例为0.1以上且0.2以下的范围内含有F的气体。
    • 7. 发明专利
    • Method for producing silicon carbide semiconductor device
    • 生产碳化硅半导体器件的方法
    • JP2014047090A
    • 2014-03-17
    • JP2012190096
    • 2012-08-30
    • Fuji Electric Co Ltd富士電機株式会社
    • KAWADA YASUYUKIYONEZAWA YOSHIYUKI
    • C30B29/36C30B25/16H01L21/205
    • H01L21/02529C30B25/02C30B29/36H01L21/02378H01L21/0262
    • PROBLEM TO BE SOLVED: To provide a method for producing a silicon carbide semiconductor device that enables rapid growth of a silicon carbide semiconductor film.SOLUTION: A method for producing a silicon carbide semiconductor device comprises: S5 of introducing gas containing Si, gas containing C and gas containing Cl in a reaction furnace; S6 (a first step) of growing an SiC epitaxial film on a 4H-SiC substrate by a CVD process in a gas atmosphere consisting of the raw material gas introduced in the step S5, added gas, doping gas and carrier gas; and a second step of gradually reducing the introduction amount ratio of the gas containing Cl to the gas containing Si in the gas atmosphere. At the beginning of the first step, the number of Cl atoms in the gas containing Cl in the gas atmosphere is 3 times of the number of Si atoms in the gas containing Si. In the second step, the number of Cl atoms in the gas containing Cl in the gas atmosphere to the number of Si atoms in the gas containing Si is reduced at the rate of 0.5% per minute to 1.0% per minute.
    • 要解决的问题:提供一种能够快速生长碳化硅半导体膜的碳化硅半导体器件的制造方法。解决方案:一种制造碳化硅半导体器件的方法,包括:引入含有Si的气体的S5,含有C 和在反应炉中含有Cl的气体; S6(第一步骤)在由在步骤S5中导入的原料气体,添加气体,掺杂气体和载气组成的气体气氛中通过CVD工艺在4H-SiC衬底上生长SiC外延膜; 以及在气体气氛中逐渐降低含有Cl的气体与含有Si的气体的引入量比的第二步骤。 在第一步开始时,气体气氛中含有Cl的气体中的Cl原子数是含有Si的气体中的Si原子数的3倍。 在第二步骤中,含有气体气氛中的Cl的气体中的Cl原子数与含有Si的气体中的Si原子数目以每分钟0.5%的速率降低至1.0%/分钟。
    • 8. 发明专利
    • Method of manufacturing silicon carbide semiconductor device
    • 制造碳化硅半导体器件的方法
    • JP2013051435A
    • 2013-03-14
    • JP2012243974
    • 2012-11-05
    • Fuji Electric Co Ltd富士電機株式会社
    • KAWADA YASUYUKITAWARA TAKESHINAKAMURA SHUNICHIGOTO MASAHIDE
    • H01L21/28H01L21/336H01L29/12H01L29/78
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a silicon carbide semiconductor device that is low in contact resistance between an electrode film and a wiring conductor element piece, and in which the wiring conductor element piece is hardly peeled off from the electrode film.SOLUTION: On a surface of an n-type silicon carbide substrate or an n-type silicon carbide region 1, a nickel film 2 and a nickel oxide film 3 are laminated in this order and then heat-treated in a state of not being subjected to oxidation. By performing such heat treatment, a part of the nickel film 2 becomes a nickel silicide film 4. After that, the nickel oxide film 3 is removed with a hydrochloric acid solution, and on a surface of the nickel silicide film 4, a nickel aluminum film 5 and an aluminum film 6 are laminated in this order.
    • 要解决的问题:提供一种制造电极膜和布线导体元件之间的接触电阻低的碳化硅半导体器件的方法,并且其中布线导体元件片几乎不从 电极膜。 解决方案:在n型碳化硅衬底或n型碳化硅区域1的表面上,依次层压镍膜2和氧化镍膜3,然后以 不被氧化。 通过进行这样的热处理,镍膜2的一部分成为硅化镍膜4.之后,用盐酸溶液除去氧化镍膜3,在硅化镍膜4的表面上形成镍铝 膜5和铝膜6依次层叠。 版权所有(C)2013,JPO&INPIT