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    • 2. 发明专利
    • The positive electrode active material for a powder, the positive electrode active material and a sodium secondary battery
    • 空值
    • JP5309581B2
    • 2013-10-09
    • JP2008023673
    • 2008-02-04
    • 住友化学株式会社
    • 雅巳 牧寺武継 山本
    • H01M2/16H01M4/505H01M4/525H01M10/054
    • H01M2/1653H01M4/505H01M4/525H01M10/056Y10T428/2982
    • The present invention provides a positive electrode active material that can suppress the necessity of performing sieving and is suitable for use in secondary batteries, particularly sodium secondary batteries. Also provided is a powder for a positive electrode active material as a raw material for the positive electrode active material. The powder for a positive electrode active material of the present invention comprises Mn-containing particles. In the cumulative particle size distribution on the volume basis of particles constituting the powder, D50, which is the particle diameter at a 50% cumulation measured from the smallest particle, is in the range of from 0.1 µm to 10 µm, and 90 vol% or more of the particles constituting the powder are in the range of from 0.3 times to 3 times D50. The powder for a positive electrode active material comprises Mn-containing particles, and 90 vol% or more of the particles constituting the powder are in the range of from 0.6 µm to 6 µm. The positive electrode active material is a powdery positive electrode active material obtained by calcining a mixture of the powder for positive electrode active material and a sodium compound. The positive electrode for sodium rechargeable batteries comprises the positive electrode active material.
    • 本发明提供能够抑制进行筛分的必要性的正极活性物质,适用于二次电池,特别是钠二次电池。 还提供了作为正极活性物质的原料的正极活性物质的粉末。 本发明的正极活性物质用粉末含有Mn粒子。 在构成粉末的粒子的体积基础上的累积粒度分布中,从最小粒子测定的50%累积时的粒径D50为0.1μm〜10μm,90体积% 或更多的构成粉末的颗粒在D50的0.3倍至3倍的范围内。 用于正极活性物质的粉末包含含Mn颗粒,并且构成粉末的颗粒的90体积%以上在0.6μm至6μm的范围内。 正极活性物质是通过煅烧正极活性物质粉末和钠化合物的混合物而获得的粉末状正极活性物质。 钠可充电电池用正极包含正极活性物质。