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    • 1. 发明专利
    • Method for producing syrup
    • 生产SYRUP的方法
    • JP2013204000A
    • 2013-10-07
    • JP2012077393
    • 2012-03-29
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HIRANO TAKAYUKI
    • C08F2/02C08F2/00C08F20/10
    • PROBLEM TO BE SOLVED: To provide a method capable of producing, when obtaining a syrup including a large amount of a low molecular weight polymer and having an appropriate viscosity by polymerizing it at a boiling point by partial polymerization of a polymer without using a chain transfer agent, the syrup in stable polymerization conditions.SOLUTION: A method for producing a syrup includes: partially polymerizing a radical polymerizable monomer by mass polymerization under the atmospheric pressure by a method including a specific polymerization condition, the syrup having a content of partial polymer of the radical polymerizable monomer of 20-50 mass% and a viscosity at 20°C of 500-20,000 mPa s.
    • 要解决的问题:提供一种能够通过在不使用链转移的情况下通过聚合物的部分聚合在沸点下获得含有大量低分子量聚合物并具有适当粘度的浆料时产生的方法 药剂,糖浆在稳定的聚合条件下。溶液:制备糖浆的方法包括:通过包括特定聚合条件的方法在大气压下通过大量聚合部分聚合可自由基聚合的单体, 20-50质量%的自由基聚合性单体,20℃下的粘度为500〜200mPa·s。
    • 2. 发明专利
    • Method for producing syrup
    • 生产SYRUP的方法
    • JP2013256619A
    • 2013-12-26
    • JP2012134580
    • 2012-06-14
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HIRANO AKIKOOKUBO TAKASHIHIRANO TAKAYUKI
    • C08F2/38C08F20/00
    • PROBLEM TO BE SOLVED: To provide a method for producing syrup excellent in colorless transparency and suppressed of cost.SOLUTION: There is disclosed a production method of syrup by polymerizing a vinyl monomer using a thermally degradable radical polymerization initiator including a process, where primary mercaptan containing only one SH group and containing no -OH group nor -COOH group in the molecule is added in a vinyl monomer after adding the radical polymerization initiator to the vinyl monomer in an amount Y (part mass) of 0.008 pt.mass or more and satisfying a formula: Y≤-1.7I+0.13 (wherein, I represents a part mass of the radical polymerization initiator remaining at the time of adding the primary mercaptan). However, each the part mass represents a part mass based on 100 pts.mass of the vinyl monomer before polymerization.
    • 要解决的问题:提供一种制备无色透明性优异且抑制成本低的糖浆的制备方法。解决方案:公开了一种使用可热降解的自由基聚合引发剂聚合乙烯基单体的糖浆的制备方法,其包括其中将伯硫醇 在乙烯基单体中加入Y(部分质量)为0.008pt.mass以上的乙烯基单体后,在乙烯基单体中仅含有一个SH基团,在分子中不含-OH基团和-COOH基团, 满足公式:Y≤-1.7I + 0.13(其中,I表示在添加伯硫醇时保留的自由基聚合引发剂的一部分质量)。 然而,每个部件质量是指聚合前基于100个聚乙烯基单体的部分质量。
    • 3. 发明专利
    • Method for continuous manufacture of resin laminate
    • 树脂层压板连续制造方法
    • JP2011189554A
    • 2011-09-29
    • JP2010055771
    • 2010-03-12
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HIRANO TAKAYUKIFUNAMI EITAOKUTSU HAJIME
    • B29C39/16B29C39/20C08J7/04
    • PROBLEM TO BE SOLVED: To provide a method for the continuous manufacture of a resin laminate which can efficiently and continuously manufacture the resin laminate which is high in adhesion of a functional layer, suppressed in layer peeling, superior in appearance and has good optical characteristics, especially a resin laminate which has a hard coat layer as the functional layer and is excellent in scratch resistance in a short time.
      SOLUTION: A light transmitting resin sheet with the functional layer formed is used in at least one of a lower part support sheet and an upper part support sheet moving in the same direction and at the same speed. The light transmitting resin sheet is arranged to make the functional layer side inside. While a photopolymerizable monomer mixture is supplied on the lower part support sheet, the upper part support sheet is laminated on the photopolymerizable mixture. After the photopolymerizable monomer mixture is polymerized/cured by being irradiated with active rays through the light transmitting resin sheet and integrated with the functional layer, the lower part support sheet and the upper part support sheet are peeled off to form the resin laminate.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供一种连续制造树脂层压体的方法,该树脂层压体能够有效且连续地制造功能层附着力高的树脂层压体,层剥离得到抑制,外观优异,成本优良 光学特性,特别是具有硬涂层作为功能层并且在短时间内耐划伤性优异的树脂层压体。 解决方案:具有形成功能层的透光树脂片用于沿相同方向和相同速度移动的下部支撑片和上部支撑片中的至少一个。 透光树脂片被布置成使功能层侧在内部。 当在下部支撑片材上提供可光聚合的单体混合物时,上部支撑片层压在可光聚合的混合物上。 光聚合性单体混合物在通过透光性树脂片照射活性射线并与功能层一体化而聚合/固化后,将下部支撑片和上部支撑片剥离形成树脂层压体。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Continuous production method of resin sheet-like object
    • 树脂类似对象的连续生产方法
    • JP2010264722A
    • 2010-11-25
    • JP2009120176
    • 2009-05-18
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HIRANO TAKAYUKIFUNAMI EITAMORIMOTO DAISUKEOKUTSU HAJIME
    • B29C39/16B29C39/42B29K35/00
    • PROBLEM TO BE SOLVED: To provide a production method of a transparent resin sheet-like object wherein deficiency due to foreign materials is small upon continuous production of a resin sheet by supplying a liquid polymerizable by an active energy ray onto a running belt and then covering the upper side thereof with a film so as to cure the liquid.
      SOLUTION: A continuous production method of the transparent resin sheet-like object comprises supplying a liquid polymerizable by an active energy ray onto a running belt, covering the upper side of the supplied liquid polymerizable by an active energy ray with a film 5 transmitting an active energy ray, spraying gas on the film, whereby foreign materials on the film are removed, and irradiating the liquid with an active energy ray polymerizable by an active energy ray from above the film, whereby the liquid polymerizable by an active energy ray is cured to give a sheet-like object.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 解决的问题:提供一种透明树脂片状物的制造方法,其中,通过将通过活性能量射线聚合的液体供给到行进带上,连续制造树脂片时,由于异物导致的缺陷小 然后用膜覆盖其上侧以使液体固化。 透明树脂片状物体的连续制造方法包括:将通过活性能量射线聚合的液体供给到行进带上,用膜5覆盖由活性能量射线聚合的供给液体的上侧 透射活性能量射线,在膜上喷射气体,由此去除膜上的异物,并且从膜上方以由活性能量射线聚合的活性能量射线照射液体,由此通过活性能量射线 固化得到片状物体。 版权所有(C)2011,JPO&INPIT
    • 5. 发明专利
    • Washing device of sheet-shaped article and washing method of sheet-shaped article
    • 薄片制品的洗涤装置和薄片制品的洗涤方法
    • JP2006289348A
    • 2006-10-26
    • JP2006045198
    • 2006-02-22
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • OKUTSU HAJIMEMURAKAMI TOMONARIHIRANO TAKAYUKIMIZOTA HIROTOSHI
    • B08B3/02B05C11/10B08B5/02
    • PROBLEM TO BE SOLVED: To provide a sheet-shaped article washing device and a washing method using the same capable of performing washing without leaving washing liquid and residual marks of the washing liquid, so-called watermark, and without generating an appearance defect of the sheet-shaped article on the sheet-shaped article continuously travelling.
      SOLUTION: The washing device that is provided on the sheet-shaped article continuously travelling substantially horizontally, and has an upstream gas nozzle and a downstream gas nozzle each jetting perpendicularly/downwardly directed upstream gas stream and downstream gas intersecting with a traveling direction of the sheet-shaped article and a washing liquid supplying nozzle that supplies the washing liquid onto an upper surface of the sheet-shaped article between the upstream gas stream and the downstream gas stream, and is provided with a movable gas nozzle jetting a gas stream that removes the washing liquid left on the upper surface of the sheet-shaped article between the upstream gas nozzle and the downstream gas nozzle.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种片状物品清洗装置和使用该洗涤装置的洗涤方法,其能够在不离开洗涤液体的情况下进行洗涤和洗涤液的残留标记,即所谓的水印,而不产生外观 片状物品上的片状物品的缺陷连续行进。 解决方案:设置在片状制品上大致水平连续行进的洗涤装置,具有上游气体喷嘴和下游气体喷嘴,每个喷射器垂直/向下指向上游气流,下游气体与行进方向相交 以及洗涤液供给喷嘴,所述洗涤液供给喷嘴将所述洗涤液供给到所述上游气体流和所述下游气体流之间的所述片状物品的上表面,并且设置有喷射气体流的可动气体喷嘴 从而去除留在上游气体喷嘴和下游气体喷嘴之间的片状物品的上表面的洗涤液。 版权所有(C)2007,JPO&INPIT
    • 6. 发明专利
    • 加熱対象物の温度測定方法
    • 测量加热对象温度的方法
    • JP2014215084A
    • 2014-11-17
    • JP2013090438
    • 2013-04-23
    • 三菱レイヨン株式会社Mitsubishi Rayon Co Ltd
    • HIRANO TAKAYUKIOKUBO TAKASHIHIRANO AKIKO
    • G01J5/00G01J5/06G01J5/48
    • G01J5/00G01J5/06G01J5/48
    • 【課題】加熱源によって加熱される加熱対象物の加熱を妨げることなく、多大で複雑な設備を用いずに、正確な温度を、短時間に測定することを目的とする。【解決手段】加熱炉(1)内の、加熱源(3)によって加熱される加熱対象物(2)の表面温度をサーモグラフィー(4,4')を用いて測定する方法に関する。加熱対象物(2)の温度測定領域を第1温度測定領域Aとし、同第1温度測定領域Aを加熱する加熱源(3)の一部または全部の加熱領域を対応加熱源領域Bとする。前記第1温度測定領域Aと前記対応加熱源領域Bとがサーモグラフィーの画像中に映るようにサーモグラフィーを定置する。サーモグラフィー(4)により得られる、第1温度測定領域Aから放射される第1輝度分布D1と対応加熱源領域Bから直接放射される第2輝度分布D2とを用いて、加熱対象物の表面温度TをW特定の演算式をもって求める。【選択図】図1
    • 要解决的问题:在短时间内测量正确的温度,而不会妨碍由加热源加热的加热物体的加热,并且不需要大量复杂的设备。解决方案:一种用于测量被加热物体的表面温度的方法( 2)通过使用热成像(4,4')在加热炉(1)中由加热源(3)加热。 将被加热物(2)的温度测量区域设为第一温度测量区域A,并且将用于加热第一温度测量区域A的加热源(3)的加热区域的一部分或全部制成为 作为相应的加热源区域B.将热像仪固定,以使第一温度测量区域A和对应的加热源区域B显示在热成像图像中。 通过使用从第一温度测量区域A辐射的第一亮度分布和通过热成像(4)获得的从相应的热源区域B直接辐射的第二亮度分布D,加热物体的表面温度T通过 一个W指定的计算表达式。
    • 8. 发明专利
    • Continuous manufacturing method of resin sheet
    • 树脂板连续制造方法
    • JP2010253796A
    • 2010-11-11
    • JP2009106403
    • 2009-04-24
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HIRANO TAKAYUKIOKUTSU HAJIMEFUNAMI EITA
    • B29C39/22B29C39/16C08J5/18
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a resin sheet without leaking an active energy ray polymerizable liquid from both ends in a film width direction when the active energy ray polymerizable liquid is supplied on a belt to be transferred covered with a film thereon and the liquid is cured to manufacture the resin sheet continuously.
      SOLUTION: The method comprises supplying the active energy ray polymerizable liquid on the belt to be transferred, covering the supplied liquid with the active energy ray permeable film, irradiating the liquid from above with active energy ray, and curing to manufacture continuously the resin sheet. The width of the film is to be the width or more of the liquid developed on the belt, both ends in the film width direction are stuck respectively on the belt with an adhesive tape to seal both ends.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种制造树脂片的方法,当活性能量射线可聚合液体被供给到要被转印的带被覆盖的带上时,不会从膜宽度方向的两端泄漏活性能量射线可聚合液体 将其上的膜固化,并连续地制造树脂片。 解决方案:该方法包括将活性能量射线可聚合液体供给到待转移的带上,用活性能量射线透过膜覆盖所提供的液体,用活性能量射线从上方照射液体,并固化以连续制造 树脂片。 膜的宽度应为在带上展开的液体的宽度或更多,膜宽度方向上的两端分别用胶带粘贴在带上以密封两端。 版权所有(C)2011,JPO&INPIT
    • 9. 发明专利
    • Coating method/device and manufacturing method of plate-like polymeric product with cured layer
    • 具有固化层的板状聚合物的涂布方法/装置和制造方法
    • JP2009136755A
    • 2009-06-25
    • JP2007315104
    • 2007-12-05
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • OKUTSU HAJIMEKAWAZOE TAKANARIHIRANO TAKAYUKI
    • B05D1/26B05B1/04B05B1/14B05C11/06
    • PROBLEM TO BE SOLVED: To provide a coating method which can prevent an optical distortion defect due to the supply of a coating fluid from being generated in a finished product, in a coating method by which a coating part is obtained on a sheet-like object, and to provide a coating device using this method.
      SOLUTION: First, a coating fluid is supplied to the upper surface of the sheet-like object which is substantially traveling horizontally, then a gas is blown to the coating fluid on the sheet-like object from a main nozzle arranged on the downstream side of a position to which the coating fluid is supplied, and thereby, the coating part with a uniform thickness, is formed on the downstream side of the main nozzle. In addition, a residue of the coating fluid is generated on the upstream side of the main nozzle, and further, the gas is blown to the residue of the coating fluid from a pair of side nozzles arranged at a position which is on the upstream side of and close to the main nozzle and also, is adjacent to both ends of the sheet-like object in the width direction. Consequently, the spread of the coating fluid in the width direction can be controlled. Besides, the supply position of the coating fluid is found on one side or both sides near both the end parts of the sheet-like object in the width direction.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种涂布方法,其可以防止在最终产品中产生涂布液的供应引起的光学变形缺陷,在涂布方法中,在片材上获得涂布部分 并且提供使用该方法的涂布装置。 解决方案:首先,向基本上水平行进的片状物体的上表面供给涂布液,然后从设置在该片状物上的主喷嘴向片状物体上的涂布液吹送气体 在主喷嘴的下游侧形成有供给涂布液的位置的下游侧,由此形成均匀厚度的涂布部。 此外,在主喷嘴的上游侧产生涂布液的残渣,另外,从设置在上游侧的位置的一对侧面喷嘴将气体吹送到涂布液的残渣 并且靠近主喷嘴,并且在宽度方向上与片状物体的两端相邻。 因此,可以控制涂布液在宽度方向上的铺展。 此外,在片状物体的宽度方向的两端部附近的一侧或两侧发现涂布液的供给位置。 版权所有(C)2009,JPO&INPIT
    • 10. 发明专利
    • Laminate and method for manufacturing the same
    • 层压板及其制造方法
    • JP2011031575A
    • 2011-02-17
    • JP2009182520
    • 2009-08-05
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • OKAFUJI HIROSHIHIRANO TAKAYUKIFUNAMI EITAOKUTSU HAJIMENISHIDA NAOKIYAMAZAWA HIDETOTAKAYAMA DAISUKEISHIHARA YUTAKA
    • B29C39/18B29C39/20B29C71/02B29K23/00B29L9/00B32B27/30
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a rein laminate short in a curing time of polymerization which has a functional layer excellent in an anti-heating property, a low heat shrinking property, favorable optical characteristics, a low bending property and a high adhesive property. SOLUTION: A method for manufacturing a resin laminate comprises a first step of supplying a polymerized liquid capable of being cured by an active energy ray into a die, a second step of covering the supplied polymerized liquid with a functional transcribing film obtained by forming a peelable functional layer on one surface of a film penetrating an active energy ray in such a way that the functional layer side of the functional transcribing film is adhered to the polymerized liquid, a third step of radiating an active energy ray over the film so as to cure the polymerized liquid to form a resin base material, and a fourth step of peeling the resin laminate integrally comprising the functional layer and the resin base material from the die and the film. COPYRIGHT: (C)2011,JPO&INPIT
    • 解决问题的方案:提供一种聚合固化时间短的憎水层压板的制造方法,其具有防热性能优异,热收缩性低,光学特性良好,弯曲性低的功能层 性能和高粘合性。 解决方案:一种用于制造树脂层压体的方法包括:将能够通过活性能量射线固化的聚合液体供应到模具中的第一步骤;第二步骤,用由下述获得的功能转录膜覆盖所提供的聚合液体: 在穿透活性能量射线的膜的一个表面上形成可剥离的功能层,使得功能转录膜的功能层侧粘附到聚合液体上,第三步骤将活性能量射线照射在膜上 为了固化聚合液体以形成树脂基材,以及第四步骤,从模具和膜剥离由功能层和树脂基材一体地组成的树脂层压材料。 版权所有(C)2011,JPO&INPIT