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    • 3. 发明专利
    • METAL SHEET FOR BATTERY ELECTRODE PLATE AND ELECTRODE FOR BATTERY USING THE METAL SHEET
    • JPH1032006A
    • 1998-02-03
    • JP23436496
    • 1996-09-04
    • KATAYAMA TOKUSHU KOGYO KK
    • SUGIKAWA HIROFUMI
    • H01M4/66B22F3/11H01M4/70H01M4/74H01M4/76H01M4/80
    • PROBLEM TO BE SOLVED: To increase the holding force of an active material filled in the spaces surrounded by projections, and to increase the coating amount in the thickness direction, by formed the projections bent in the vertical direction of a porous metal member at a required pitch and having numerous hole on the outer periphery. SOLUTION: To a porous metal member 1 made of punched metal sheet S having round holes 2b and 3b at a specific pattern, projections 2 and projecting to the upper side and the lower side of a reference surface L are formed alternately at a required pitch. The projections 2 and 3 are made in a pyramid form, a conical form, or a wavy form, and the opening ratio of the metal member 1 is made 10 to 99%, preferably. A paste form active material is filled to spaces 6 and 7 surrounded by the projections 2 and 3, so as to make into an electrode for battery. Or in the other way, plural sheets of metal members 1 whose positions of projectings 2 and 3 are slipped are layered, or plate form of porous metal members are provided on the tops 2c and 3c of the upper and the lower projections of the metal member 1, and the active material may be filled to the spaces surrounded by those members. And, the metal member 1 may be formed by rolling a metal powder in a sheet form.
    • 8. 发明专利
    • ELECTRICALLY CONDUCTIVE FINE METAL POWDER AND ITS PRODUCTION
    • JPH0790309A
    • 1995-04-04
    • JP22928693
    • 1993-09-14
    • KATAYAMA TOKUSHU KOGYO KK
    • SUGIKAWA HIROFUMI
    • B22F1/02
    • PURPOSE:To improve the electric conductivity of the fine metal powder and to reduce its specific resistance by charging the fine metal powder and a soft metal powder having conductivity higher than that of the fine metal powder into a mixing agitator to form a pressure-coating film of the soft metal powder on the surface of the fine metal powder. CONSTITUTION:The fine metal powder 4 consisting of Ni, Cu, Ag, Al, Fe, Zn, a powdery mixture of Fe with Cr or a Fe-Cr alloy powder is prepared and a soft metal powder consisting of Au, Ag, Cu or In, each of which has conductivity higher than that of this fine metal powder 4, softness and ductility and is hardly oxidized, is also prepared. Then, this soft metal powder and the fine metal powder 4 are charged into a mixing agitator to form a pressure-coating film 11 of the soft metal powder on the surface of the fine metal powder 4. Thus, the conductive metal powder 10 which has spherical or flat flaky shape having a circular or elliptical cross section can be produced by coating the outer circumferential face of the fine metal powder 4 with the conductive pressure-coating film 11.
    • 9. 发明专利
    • COVERING FILM FORMING METHOD FOR BATTERY NEGATIVE TERMINAL PLATE
    • JPH0757718A
    • 1995-03-03
    • JP19834493
    • 1993-08-10
    • KATAYAMA TOKUSHU KOGYO KK
    • SUGIKAWA HIROFUMI
    • H01M2/26H01M4/64H01M4/66H01M6/12
    • PURPOSE:To retard hydrogen gas evolution during storage of a battery and to prevent decrease in discharge performance during use by coating the surface, in contact with a negative active material, of a negative terminal plate with a specific metal with a roller in a molten state. CONSTITUTION:A negative terminal plate is formed with a metal plate 8 prepared by forming a copper plating layer on the inside of a stainless steel plate and a nickel plating layer on the outside. The metal plate 8 is degreased with pretreating equipment 11, treated for acid activation, and dried with heating equipment 12 and heated to a temperature near the melting point of a specific metal. As the specific metal, the metal capable of alloying with zinc and heightening the hydrogen overpotential of the alloy, such as Sn-In alloy, us used. In covering film forming equipment 10, the copper plating layer of the metal plate 8 is coated with an Sn-In molten alloy 20 in a container 21 with a coating roll 23 through a pick-up roll 22. The metal plate 8 is annealed with an induction heater 13, cooled with cooling equipment 14, and pressed with a skin pass roll 15, then formed in the negative terminal plate.