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    • 1. 发明专利
    • Method device of removing unburned carbon in fly ash
    • 在飞灰中去除未燃烧的碳的方法装置
    • JP2010017616A
    • 2010-01-28
    • JP2008178254
    • 2008-07-08
    • Internat Center For Environmental Technol TransaferMitsui Eng & Shipbuild Co LtdTaiheiyo Cement Corp三井造船株式会社太平洋セメント株式会社財団法人国際環境技術移転研究センター
    • KATAKURA MASAHIKOSUZUKI TAKAONAKAMURA TOMOMICHI
    • B03D1/02B03B1/04B03D1/10C02F11/12
    • C04B18/08B03D1/02B03D1/10C04B2111/1087F23J2900/01005Y02W30/92C04B20/02
    • PROBLEM TO BE SOLVED: To provide a method and device of removing an unburned carbon in fly ash which exhibits a large throughput and can make available modified high-quality fly ash by increasing the dehydration rate and efficiency in a dehydration process, without decreasing the efficiency of floatation separation in a floatation process. SOLUTION: This method of removing the unburned carbon in the fly ash comprises: a slurry making process to obtain slurry by adding water to the fly ash; a surface modification process to add a collector to the slurry; a frother adding process to add a frother to the slurry; a floatation process to separate the slurry into a sediment and suspended matter by floatation; and a sediment dehydration process to dehydrate the slurry of the sediment obtained by the floatation process. In addition, after the floatation process, the slurry is dehydrated by a circulation enriching process to enrich the slurry of the sediment obtained by the floatation process by circulating the slurry between an intermediate tank for storing the slurry temporarily and a centrifugal separation-type dehydrator. Further, this dehydrated slurry is conveyed to the sediment dehydration process. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种去除飞灰中未燃碳的方法和装置,其显示出大量的生产能力,并且可以通过提高脱水过程中的脱水速率和效率来获得改性的高品质飞灰,而没有 降低漂浮过程中浮选分离的效率。 解决方案:这种去除飞灰中未燃碳的方法包括:通过向飞灰中加入水来获得浆料的浆料制备方法; 将浆料添加到浆料中的表面改性方法; 起泡剂添加方法以将浆料添加到浆料中; 通过浮选将浆料分离成沉淀物和悬浮物的浮选过程; 并通过沉淀物脱水工艺对通过浮选过程获得的沉淀物的浆液进行脱水。 此外,在浮选处理之后,通过循环富集工序使浆料脱水,通过使浆料临时储存浆料的中间槽与离心分离型脱水机之间循环,使浮选工序得到的沉淀物的浆料富集。 此外,将该脱水浆液输送至沉淀物脱水工序。 版权所有(C)2010,JPO&INPIT
    • 2. 发明专利
    • Decomposition/recovery method of thermosetting resin
    • 热分解树脂的分解/回收方法
    • JP2009155404A
    • 2009-07-16
    • JP2007333102
    • 2007-12-25
    • Internat Center For Environmental Technol TransaferPanasonic Electric Works Co Ltdパナソニック電工株式会社財団法人国際環境技術移転研究センター
    • HIDAKA MASARUNAKAGAWA NAOHARUSHIBATA KEIJIIZUMITANI TAKAAKI
    • C08J11/14B01J3/00C08G63/88C08J11/08
    • Y02W30/701Y02W30/704
    • PROBLEM TO BE SOLVED: To provide a decomposition/recovery method of a thermosetting resin, which unnecessitates the step of precipitating a styrene-fumaric acid copolymer by adding a strong acid to the liquid portion of the decomposition product of a thermosetting resin by subcritical water, which can directly precipitate the styrene-fumaric acid copolymer as solids of the decomposition product, and which also can recover the styrene-fumaric acid copolymer efficiently. SOLUTION: This method includes the process (A) of decomposing a thermosetting resin that contains a polyester part and its crosslinked part at a temperature whereat the fumaric acid structural part of the styrene-fumaric acid copolymer is decarbonated and with subcritical water substantially not containing an alkali, the process (B) of subjecting the obtained decomposition product to solid-liquid separation and recovering the solids containing the styrene-fumaric acid copolymer, and the process (C) of bringing the recovered solids into contact with a solvent having a polarity lower than water and dissolving the styrene-fumaric acid copolymer into the solvent to recover it. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种热固性树脂的分解/回收方法,其不需要通过在热固性树脂的分解产物的液体部分中加入强酸来沉淀苯乙烯 - 富马酸共聚物的步骤 亚临界水,其可以直接沉淀苯乙烯 - 富马酸共聚物作为分解产物的固体,并且还可以有效地回收苯乙烯 - 富马酸共聚物。 解决方案:该方法包括在苯乙烯 - 富马酸共聚物的富马酸结构部分脱碳的温度下分解包含聚酯部分的热固性树脂及其交联部分的方法(A),并且将亚临界水基本上 不含碱的方法(B)将所得分解产物进行固液分离和回收含有苯乙烯 - 富马酸共聚物的固体的方法(B),以及使回收的固体与具有苯乙烯 - 富马酸共聚物的溶剂接触的方法(C) 极性低于水,并将苯乙烯 - 富马酸共聚物溶解到溶剂中以回收。 版权所有(C)2009,JPO&INPIT
    • 3. 发明专利
    • Method for decomposing and recovering thermosetting resin
    • 分解和回收热固性树脂的方法
    • JP2008291188A
    • 2008-12-04
    • JP2007140829
    • 2007-05-28
    • Internat Center For Environmental Technol TransaferPanasonic Electric Works Co Ltdパナソニック電工株式会社財団法人国際環境技術移転研究センター
    • HIDAKA MASARUNAKAGAWA NAOHARUSHIBATA KEIJIIZUMITANI TAKAAKI
    • C08J11/14B01J3/00C08J11/08
    • Y02W30/701Y02W30/704
    • PROBLEM TO BE SOLVED: To provide a method for decomposing and recovering a thermosetting resin, by which a styrene-fumaric acid copolymer can be directly precipitated as the solid content of the decomposition product without requiring a step of precipitating a styrene-fumaric acid copolymer by adding a strong acid to the liquid component of the decomposition product of the thermosetting resin by sub-critical water, and a styrene-fumaric acid copolymer can be efficiently recovered. SOLUTION: The method includes steps of: (A) decomposing a thermosetting resin containing a polyester moiety and a crosslinked moiety with the sub-critical water substantially containing no alkali; (B) subjecting the obtained decomposition product to solid-liquid separation to recover a solid content containing a styrene-fumaric acid copolymer; and (C) bringing the recovered solid content into contact with a solvent having higher solubility with a styrene-fumaric acid copolymer than water so as to dissolve the styrene-fumaric acid copolymer in the solvent and to recover. COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:为了提供一种分解和回收热固性树脂的方法,通过该方法可以将苯乙烯 - 富马酸共聚物直接沉淀为分解产物的固体含量,而不需要沉淀苯乙烯 - 富马酸的步骤 可以有效地回收利用亚临界水向热分解产物的分解产物的液体组分加入强酸和苯乙烯 - 富马酸共聚物。 该方法包括以下步骤:(A)将基本上不含碱的亚临界水分解含有聚酯部分和交联部分的热固性树脂; (B)使得到的分解产物进行固液分离以回收含有苯乙烯 - 富马酸共聚物的固体含量; 和(C)使得回收的固体含量与溶于苯乙烯 - 富马酸共聚物的溶剂与水接触,以使苯乙烯 - 富马酸共聚物溶解在溶剂中并回收。 版权所有(C)2009,JPO&INPIT
    • 4. 发明专利
    • Method for decomposing and recovering thermosetting resin
    • 分解和回收热固性树脂的方法
    • JP2008291187A
    • 2008-12-04
    • JP2007140828
    • 2007-05-28
    • Internat Center For Environmental Technol TransaferPanasonic Electric Works Co Ltdパナソニック電工株式会社財団法人国際環境技術移転研究センター
    • HIDAKA MASARUNAKAGAWA NAOHARUSHIBATA KEIJIIZUMITANI TAKAAKI
    • C08J11/14
    • Y02W30/704
    • PROBLEM TO BE SOLVED: To provide a method for decomposing and recovering a thermosetting resin, by which a styrene-fumaric acid copolymer can be directly precipitated as the solid content of the decomposition product without requiring a step of precipitating a styrene-fumaric acid copolymer by adding a strong acid to the liquid component of the decomposition product of the thermosetting resin by sub-critical water, and a styrene-fumaric acid copolymer can be efficiently recovered in an easily reusable form. SOLUTION: The method includes steps of: (A) decomposing a thermosetting resin containing a polyester moiety and a crosslinked moiety with sub-critical water substantially containing no alkali; (B) subjecting the obtained decomposition product to solid-liquid separation to recover a solid content containing a styrene-fumaric acid copolymer; and (C) bringing the recovered solid content into contact with alcohol to esterify the styrene-fumaric acid copolymer in the solid content and to recover an alcohol-modified product of the styrene-fumaric acid copolymer. COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:为了提供一种分解和回收热固性树脂的方法,通过该方法可以将苯乙烯 - 富马酸共聚物直接沉淀为分解产物的固体含量,而不需要沉淀苯乙烯 - 富马酸的步骤 通过用临界水向热分解产物的分解产物的液体组分中加入强酸和苯乙烯 - 富马酸共聚物可以以易于重复使用的形式有效地回收酸性共聚物。 解决方案:该方法包括以下步骤:(A)将基本上不含碱的亚临界水分解含有聚酯部分和交联部分的热固性树脂; (B)使得到的分解产物进行固液分离以回收含有苯乙烯 - 富马酸共聚物的固体含量; 和(C)使回收的固体含量与醇接触以使固体含量的苯乙烯 - 富马酸共聚物酯化,并回收苯乙烯 - 富马酸共聚物的醇改性产物。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Method of manufacturing conductive polycrystalline substance
    • 制造导电多晶体物质的方法
    • JP2006315932A
    • 2006-11-24
    • JP2005142518
    • 2005-05-16
    • Internat Center For Environmental Technol TransaferToyota Central Res & Dev Lab Inc株式会社豊田中央研究所財団法人国際環境技術移転研究センター
    • ITAHARA HIROSHITANI TOSHIHIKOASAHI RYOJI
    • C04B35/64B22F3/10C04B35/00H01B13/00H01L35/14H01L35/34H01L39/24
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a polycrystalline substance by which the deterioration of electro-conductivity caused by an impurity phase, abnormal grain growth or macro-crack can be suppressed.
      SOLUTION: The method of manufacturing a conductive polycrystalline substance is provided with: a compacting step for compacting powder blended so that a conductive material having a target composition can be obtained; a first heat treatment step for heating the compact at a prescribed temperature T
      1 for a prescribed time (t
      1 ); and a second heat treatment step for heating the compact at a prescribed temperature T
      2 for a prescribed time (t
      2 ). Wherein, the temperature T
      1 is equal to or above a temperature causing the abnormal grain growth and lower than the melting point of the conductive material. The time (t
      1 ) is shorter than the time till the occurrence of particles having a particle diameter five or more times of the average particle diameter is recognized. The temperature T
      2 is equal to or above a temperature causing densification and lower than a temperature causing the abnormal grain growth, and the time (t
      2 ) is equal to or above the time causing the densification enough.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:提供一种制造多晶物质的方法,通过该方法可以抑制由杂质相引起的导电性劣化,异常晶粒生长或宏观裂纹。 解决方案:制造导电多晶物质的方法设置有:压实粉末混合的压实步骤,从而可以获得具有目标组成的导电材料; 第一热处理步骤,用于在预定温度T 1 下加热所述压块达预定时间(t 1 ); 以及第二热处理步骤,用于在预定温度T 2 下加热所述压块达预定时间(t SB> 2 )。 其中,温度T 1 等于或高于导致异常晶粒生长并低于导电材料的熔点的温度。 时间(t 1 )比直到发现具有平均粒径的五倍以上的粒子的时间短。 温度T 2 等于或高于导致致密化的温度并且低于引起异常晶粒生长的温度,并且时间(t SB> 2 )等于或高于 导致致密化的时间就够了。 版权所有(C)2007,JPO&INPIT
    • 7. 发明专利
    • Method for recovering inorganic substance from plastic
    • 从塑料中回收无机物质的方法
    • JP2005336323A
    • 2005-12-08
    • JP2004156859
    • 2004-05-26
    • Internat Center For Environmental Technol TransaferMatsushita Electric Works Ltd松下電工株式会社財団法人国際環境技術移転研究センター
    • OKA KENJIMIYAZAKI TOSHIHIRO
    • B01D9/02B01J3/00C08J11/14
    • Y02W30/704
    • PROBLEM TO BE SOLVED: To provide a method for recovering inorganic substances from plastics which permits isolation and recovery of a glass fiber from a plastic molded article containing the glass fiber, aluminum hydroxide and calcium carbonate. SOLUTION: The glass fiber is isolated and recovered by steps comprising a step for treating the plastic molded article containing the glass fiber and aluminum hydroxide as the inorganic substances with a subcritical fluid to decompose the plastics into monomers and oligomers and to cause the inorganic substances to leave from the plastics, a step for separating inorganic substances from monomers and oligomers from the plastics, a step for causing aluminum hydroxide to dissolve in water by supplying an acid to water containing the separated inorganic substances, and a step for separating the glass fiber by filtering water where aluminum hydroxide is dissolved. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供从塑料中回收无机物质的方法,其允许从含有玻璃纤维,氢氧化铝和碳酸钙的塑料模制品中分离和回收玻璃纤维。 解决方案:玻璃纤维通过以下步骤分离和回收,所述步骤包括用亚临界流体处理含有玻璃纤维和氢氧化铝作为无机物质的塑料模制品的步骤,以将塑料分解成单体和低聚物,并使 从塑料中脱离的无机物质,从塑料中分离无机物质与单体和低聚物的步骤,通过向含有分离的无机物质的水提供酸而使氢氧化铝溶解在水中的步骤,以及分离 玻璃纤维通过过滤溶解有氢氧化铝的水。 版权所有(C)2006,JPO&NCIPI
    • 10. 发明专利
    • Decomposition-separation process for plastic
    • 塑料分解分离方法
    • JP2010163620A
    • 2010-07-29
    • JP2010030137
    • 2010-02-15
    • Internat Center For Environmental Technol TransaferPanasonic Electric Works Co Ltdパナソニック電工株式会社財団法人国際環境技術移転研究センター
    • SHIMOKAGE TAKUJIMAEKAWA TETSUYA
    • C08J11/16C07C27/02C07C31/20C07C51/09C07C57/145
    • Y02W30/705
    • PROBLEM TO BE SOLVED: To provide a decomposition-separation process for plastic, by which the treatment cost for dehydration can be kept low and plastic produced from raw materials containing polyhydric alcohol and organic acid can be recovered as user-friendly plastic again. SOLUTION: The process comprises a step of treating plastic comprising an unsaturated polyester part and its crosslinking part with subcritical water at a temperature less than decomposition temperature in the presence of alkali, so as to decompose the plastic into polyhydric alcohol that is a raw material monomer of plastic, an organic acid salt that is a raw material monomer of plastic, and a crosslinking part-acid copolymer salt that is an organic acid compound composed of a crosslinking part and an unsaturated polyester part and a step of supplying a solvent with a dissolution parameter of 9 or more and acid to an aqueous solution containing the polyhydric alcohol, the organic acid salt, and the crosslinking part-acid copolymer salt obtained in the previous decomposition step, so as to separate the solution into a solid content of the crosslinking part-acid copolymer and an liquid phase. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供塑料的分解分解过程,由此可以将脱水的处理成本保持在低水平,并且可以再次将用于多元醇和有机酸的原料生产的塑料作为用户友好的塑料回收 。 解决方案:该方法包括在碱存在下,在低于分解温度的温度下用亚临界水处理包含不饱和聚酯部分及其交联部分的塑料的步骤,以将塑料分解成多元醇,其为 塑料的原料单体,作为塑料的原料单体的有机酸盐,作为由交联部和不饱和聚酯部构成的有机酸化合物的交联部分酸共聚物盐,以及供给溶剂的工序 溶解参数为9以上,并且酸与含有上述分解步骤中得到的多元醇,有机酸盐和交联部分 - 酸共聚物盐的水溶液反应,以将溶液分离成固体含量 交联部分酸共聚物和液相。 版权所有(C)2010,JPO&INPIT