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    • 3. 发明专利
    • Exhaust gas cleaning method containing water-soluble volatile hydrocarbon of large amount and high humidity
    • 含有大量水溶性挥发油和高湿度的排气净化方法
    • JP2011025219A
    • 2011-02-10
    • JP2009213426
    • 2009-09-15
    • Epsilon Co LtdHiroshi Tawara株式会社エプシロン弘 田原
    • TAWARA HIROSHI
    • B01D53/44A61L9/01A61L9/16B01D53/04B01D53/26B01D53/72B01D53/81B01J20/10B01J20/18B01J20/20B01J20/34
    • PROBLEM TO BE SOLVED: To provide a treating method of a large amount of exhaust gas exceeding 10,000 m 3 /h of high humidity of 50% or more of R.H., and containing lean water-soluble VOC of several hundred to several thousand ppm in the exhaust gas. SOLUTION: In an exhaust gas treating method, an adsorbing apparatus is used for treating the exhaust gas containing lean water-soluble hydrocarbon and a large amount of moisture. The adsorbing apparatus consists of a layer packed with zeolite-made honeycomb or zeolum-made honeycomb as an adsorbent, so-called a molecular sieve adsorbent, wherein a pre-stage alternately performing adsorption and desorption, is packed with a honeycomb layer formed of zeolite or zeolum having a pore diameter of about 3 Å and/or a honeycomb layer consisting of hydrophobic silica gel, and a rear stage is packed with particulate meso-hole activated carbon and/or hydrophobic silica gel, with the upper and lower stages communicated with each other. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供超过10,000的高湿度为50%以上的RH的超过10,000m / h的废气的处理方法,并且含有贫水溶性 VOC在废气中几百到几千ppm。 解决方案:在废气处理方法中,使用吸附装置来处理含有贫水溶性烃和大量水分的废气。 吸附装置由填充有沸石制蜂窝或沸石制蜂窝作为吸附剂的层组成,即所谓的分子筛吸附剂,其中预先交替进行吸附和解吸附,其中填充有由沸石形成的蜂窝层 或孔径约为的沸石和/或由疏水性硅胶组成的蜂窝层和后级填充有颗粒状的中孔活性炭和/或疏水性硅胶,上层和下层与 彼此。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Method and apparatus for recovering hydrogen gas from mixed gas
    • 从混合气体回收氢气的方法和装置
    • JP2007153726A
    • 2007-06-21
    • JP2006133142
    • 2006-05-11
    • Epsilon Co Ltd株式会社エプシロン
    • TAWARA HIROSHIMINAMI ICHIROKAGAWA SHIYOUJI
    • C01B3/56C01B3/26C01B3/54C07B61/00C07C5/367C07C15/24
    • PROBLEM TO BE SOLVED: To provide a method and apparatus for recovering hydrogen gas from a mixed gas, which enable high pressure hydrogen to be separated with high purity without occurring a "dry up" phenomenon, and enable about 100% of hydrogen gas contained in the mixed gas to be recovered.
      SOLUTION: The apparatus 10 for recovering hydrogen gas from the mixed gas has first and second reactors 11, 12 in each of which a catalyst is filled. The first reactor 11 filled with the catalyst has such a constitution that a mixed gas-supplying piping 13 and a hydrogen-unsaturated aromatic compound circulation piping 14 are connected to the bottom part side, and an off-gas discharge piping 15 for discharging an off-gas from which hydrogen gas has been removed and a reaction product circulation piping 16 are connected to the top part side. The second reactor 12 filled with the catalyst has such a constitution that hydrogen a gas recovering piping 17 and the reaction product circulation piping 16 are connected to the top part side, and the hydrogen-unsaturated aromatic compound circulation piping 14 is connected to the bottom part side.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种从混合气体中回收氢气的方法和装置,其能够使高压氢气以高纯度分离而不发生“干燥”现象,并且能够实现约100%的氢 包含在要回收的混合气体中的气体。 解决方案:用于从混合气体中回收氢气的装置10具有填充有催化剂的第一和第二反应器11,12。 填充有催化剂的第一反应器11具有如下结构:混合气体供给配管13和氢不饱和芳香族化合物循环配管14与底部侧连接,排气口排出管15 从其中除去氢气的气体和反应产物循环管道16连接到顶部一侧。 填充有催化剂的第二反应器12具有如下结构:氢气回收管道17和反应产物循环管道16连接到顶部侧,而氢不饱和芳族化合物循环管道14连接到底部 侧。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Economical process for producing anhydrous alcohol or gasohol using ether solvent
    • 生产使用溶剂的无水酒精或酒精的经济方法
    • JP2009256294A
    • 2009-11-05
    • JP2008126477
    • 2008-04-14
    • Epsilon Co Ltd株式会社エプシロン
    • MINAMI ICHIROSAITO KIKEIMINAMI SATSUKI
    • C07C29/86C07C31/08C07C31/10C10L1/182
    • PROBLEM TO BE SOLVED: To provide an economical process for overcoming the problem of heavy heat consumption in producing an anhydrous alcohol to be used in gasohol by distillation.
      SOLUTION: The anhydrous alcohol is economically produced by dehydrating a diluted alcohol and mixed water by liquid-liquid extraction with the use of an ether solvent 2 to a saturation solubility in the mixture of the solvent and the alcohol to omit an alcohol condensation step, recovering a small amount of the alcohol in the residual water of extraction by stripping with low heat consumption by utilizing the property of the ether solvent (the alcohol concentration being low in the aqueous phase), and recycling the recovered alcohol to the raw material. This anhydrous alcohol is mixed with gasoline 6 to form gasohol 7. According to the conventional alcohol concentration and dehydration method by distillation, in the process of from fermented unrefined product to 90% rough distillate alcohol to 100% anhydrous alcohol, about 1.8 t steam per kL anhydrous alcohol is needed but according to this process, 0.9 t correspondig to about half the steam consumption volume is enough to obtain an enhanced energy-saving economical effect.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种经济的方法来克服通过蒸馏生产用于汽油中的无水醇的重的热消耗问题。 解决方案:通过使用乙醚溶剂2的液 - 液萃取将稀释的醇和混合水脱水至在溶剂和醇的混合物中的饱和溶解度来省去醇缩合而经济地制备无水醇 通过利用醚溶剂的性质(酒精浓度在水相中低),以低热消耗汽提回收少量的提取残留水中的醇,并将回收的醇再循环到原料中 。 将这种无水酒精与汽油6混合形成气柱7.根据常规的酒精浓缩和蒸馏脱水方法,在从发酵的未精制产物到90%粗馏分醇至100%无水乙醇的过程​​中,约1.8t蒸汽 需要kL无水酒精,但根据这个过程,相当于蒸汽消耗量约一半的0.9 t足以获得增强的节能经济效果。 版权所有(C)2010,JPO&INPIT
    • 6. 发明专利
    • Method of economically manufacturing gasohol (mixture of gasoline and alcohol)
    • 汽油生产方法(汽油和酒精混合物)
    • JP2009013385A
    • 2009-01-22
    • JP2007196697
    • 2007-07-02
    • Epsilon Co Ltd株式会社エプシロン
    • MINAMI ICHIROMINAMI SATSUKI
    • C10L1/02B01D11/04C10L1/00C10L1/06
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a gasohol by directly mixing hydrated alcohol, containing a large amount of water, with a gasoline fraction to remove the water by liquid-liquid extraction and liquid phase adsorption and dehydration.
      SOLUTION: For the purpose of minimizing an alcohol concentrating process, the properties of gasoline (formation of a heterophase with water and possible contamination with a very small amount of hydrocarbon impurities included in an alcohol) are utilized to directly mix an aqueous alcohol solution with the gasoline, and the water is removed to saturation solubility in the gasohol 7 by the liquid-liquid extraction, followed by dehydration by the liquid phase adsorption, to economically manufacture the gasohol.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种通过将含有大量水的水合醇与汽油馏分直接混合以通过液 - 液萃取和液相吸附和脱水来除去水来制备汽油醇的方法。 解决方案:为了使酒精浓缩过程最小化,使用汽油的性质(与水形成异相和可能被包含在醇中的非常少量的烃杂质污染)直接混合含水酒精 用汽油除去溶液,通过液 - 液萃取将水除去至汽油醇7中的饱和溶解度,随后通过液相吸附脱水,以经济地制备汽油。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Manufacturing of hydrogen from by-produced glycerin in biodiesel fuel (bdf) manufacturing
    • 在生物柴油(BDF)制造中生产的甘油的氢制造
    • JP2009013041A
    • 2009-01-22
    • JP2007196696
    • 2007-07-02
    • Epsilon Co Ltd株式会社エプシロン
    • MINAMI ICHIROMINAMI SATSUKI
    • C01B3/38C10L1/02
    • Y02E50/13
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of hydrogen from glycerin which is by-produced and becoming a mass industrial waste in manufacturing biodiesel fuel (BDF) which is a notable carbon neutral diesel alternative.
      SOLUTION: In this invention, water is added to the glycerin which is by-produced in manufacturing biodiesel fuel and heated to make it transferable, then hydrogen is obtained at a high recovery rate of 60-80% by a steam reforming reaction. The steam reforming reaction is carried out at a S/C (ratio of molar number of steam to the number of carbon element) of not lower than 1 but not higher than 5, a reaction pressure of not lower than atmospheric pressure but less than 1 MPa, and a reaction temperature in the range of 500°C-900°C.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种生产生物柴油(BDF)的副产的甘油和成为大规模工业废弃物的氢的制造方法,该生物柴油燃料是显着的碳中和柴油替代品。 解决方案:在本发明中,将水加入到生产生物柴油燃料中副产的甘油中并加热使其转移,然后通过蒸汽重整反应以60-80%的高回收率获得氢气 。 蒸汽重整反应以不低于1但不高于5的S / C(蒸汽摩尔数与碳元素的比率)进行,反应压力不低于大气压但小于1 并且反应温度在500℃-900℃的范围内。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Method for production of polycrystalline silicon
    • 生产多晶硅的方法
    • JP2013006741A
    • 2013-01-10
    • JP2011140651
    • 2011-06-24
    • Epsilon Co Ltd株式会社エプシロンI'msep Co Ltdアイ’エムセップ株式会社Tadashi Ogasawara忠司 小笠原
    • OGASAWARA TADASHIMINAMI ICHIROITO YASUHIKOTSUJIMURA HIROYUKI
    • C01B33/033
    • PROBLEM TO BE SOLVED: To provide a method for production of polycrystalline silicon capable of continuously, stably and massively producing silicon by adopting a reaction made in a low-temperature liquid phase without using a gas phase reaction at high temperature.SOLUTION: The position of a reduction reaction part for generating polycrystalline silicon and zinc chloride as reaction products by reacting chlorosilane and metallic zinc in a molten metallic zinc, is below the position of an electrolysis part for generating chlorine and metallic zinc by electrolyzing zinc chloride being the reaction product. The polycrystalline silicon and zinc chloride are generated as reaction products by reacting the chlorosilane with the metallic zinc in the reduction reaction part. The polycrystalline silicon being one of reaction products is separated, and chlorine and metallic zinc are generated by electrolyzing zinc chloride. Chlorine is used for production of chlorosilane, and the metallic zinc is used for reaction with chlorosilane.
    • 待解决的问题:提供一种能够通过在低温液相下进行反应而连续,稳定和大量生产硅的多晶硅的生产方法,而不需要在高温下使用气相反应。 解决方案:通过在熔融金属锌中使氯硅烷与金属锌反应产生多晶硅和氯化锌作为反应产物的还原反应部分的位置低于通过电解产生氯和金属锌的电解部分的位置 氯化锌是反应产物。 通过在还原反应部分中使氯代硅烷与金属锌反应,产生多晶硅和氯化锌作为反应产物。 分离作为反应产物之一的多晶硅,通过电解氯化锌产生氯和金属锌。 氯用于生产氯硅烷,金属锌用于与氯硅烷的反应。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Method and apparatus for refining hydrogen by using organic hydride
    • 通过使用有机氢气精炼氢的方法和装置
    • JP2008290927A
    • 2008-12-04
    • JP2007161879
    • 2007-05-24
    • Epsilon Co Ltd株式会社エプシロン
    • TANAKA TSUTOMUMINAMI ICHIRO
    • C01B3/58H01M8/06
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a method and an apparatus for removing a gas from hydrogenation products and performing a dehydrogenation reaction effectively when only hydrogen in a gaseous mixture is added selectively to a hydrogen-unsaturated aromatic compound in a hydrogenation catalyst reactor, high-purity hydrogen is separated from the produced hydrogen-saturated aromatic compound in a dehydrogenation catalyst reactor and the hydrogen-unsaturated aromatic compound produced simultaneously is circulated in the hydrogenation catalyst reactor to alternately perform hydrogenation and dehydrogenation reactions. SOLUTION: The method and the apparatus for refining hydrogen from the gaseous mixture are characterized in that hydrogen is added beforehand to the aromatic compound to decrease the boiling point of the aromatic compound so that the dehydrogenation reaction is performed in a gas phase under conditions of high temperature and high pressure and the gas is removed effectively in a gas removal column. As a result, high-purity hydrogen having ≥99% purity can be obtained from a wide range of hydrogen-mixed gasses from biotechnology, COG, etc. at almost 100% recovery rate without performing special pretreatment to remove impurities. The pressure of a product can economically be made higher than that of a raw material without compressing the gas. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种在氢化催化剂反应器中仅将氢气在氢气不饱和芳族化合物中选择性加入时,有效地从氢化产物中除去气体并进行脱氢反应的方法和装置 在脱氢催化剂反应器中将高纯度氢气与产生的饱和饱和的芳香族化合物分离,同时生产的不饱和氢的芳族化合物在氢化催化剂反应器中循环,交替进行氢化和脱氢反应。 解决方案:从气态混合物中精炼氢的方法和装置的特征在于预先将氢气加入到芳族化合物中以降低芳族化合物的沸点,从而使脱氢反应在气相中进行 在高温高压条件下,气体在气体去除塔中被有效去除。 因此,从几乎100%回收率的生物技术,COG等的大量氢混合气体中可以获得纯度≥99%的高纯度氢,而不进行特殊的预处理以去除杂质。 在不压缩气体的情况下,产品的压力经济地可以比原料的压力高。 版权所有(C)2009,JPO&INPIT