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2. 发明专利

JP2008195964A Method for continuously producing low unsaturation polyoxyalkylene polyether polyol by continuously supplying starter 有权
标题翻译：连续供应起动机连续生产低不饱和聚氧乙烯聚醚多元醇的方法
公开(公告)号：JP2008195964A
公开(公告)日：2008-08-28
申请号：JP2008133324
申请日：2008-05-21
申请人： Bayer Antwerpen Comm V , バイエル・アントウエルペン・コマンディテーレ・フェンノートシャップBayer Antwerpen Comm.V.
发明人： PAZOS JOSE , SHIH T THOMAS
IPC分类号： C08G65/10 , C08G65/26
CPC分类号： C08G65/2663 , C08G65/2696
摘要： PROBLEM TO BE SOLVED: To provide a method for continuously producing a polyoxyalkylene ether having a very low unsaturation, a functionality valence close to a nominal value, and a small polydispercity. SOLUTION: The method for continuously producing the polyoxyalkylene polyether comprises: (a) introducing an effective amount for catalytic action of polyoxyalkylation of at least one DMC catalyst into a continuous reactor; (b) introducing continuously at least one alkylene oxide into the reactor; (c) introducing continuously a further activated or non-activated DMC catalyst into the reactor; (d) introducing at least one continuously supplying starter into the reactor along the reactor path during the progress of the polyoxyalkylation so that the continuously supplying starter has an average molecular weight of 18-45,000 Da and a continuously supplying starter concentration is maintained during an average residence time of the reactor; and (e) taking out continuously a polyoxyalkylene polyether product having an equivalent weight of greater than 1,000 Da. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种连续制备具有非常低的不饱和度，官能度接近标称值和小的多不饱和度的聚氧化烯醚的方法。解决方案：连续生产聚氧化烯聚醚的方法包括：（a）将至少一种DMC催化剂的聚氧烷基化催化作用的有效量引入连续反应器中; （b）连续引入至少一种环氧烷进入反应器; （c）将另外的活化或未活化的DMC催化剂连续引入反应器中; （d）在聚氧化烷基化过程中，沿着反应器路径将至少一个连续供应起动器引入反应器，使得连续供应的起动器的平均分子量为18-45,000Da，并且在平均值期间维持连续供应的起始剂浓度反应堆的停留时间; 和（e）连续取出当量重量大于1000Da的聚氧化烯聚醚产品。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP5331379B2 The continuous process low unsaturation polyoxyalkylene polyether polyols by continuously feeding starter 有权
公开(公告)号：JP5331379B2
公开(公告)日：2013-10-30
申请号：JP2008133324
申请日：2008-05-21
申请人：バイエル・アントウエルペン・コマンディテーレ・フェンノートシャップBayer Antwerpen Comm.V.
发明人：ジョーズ・パゾズ , ティー・トマス・シー
IPC分类号： C08G65/10 , C08G65/26
CPC分类号： C08G65/2663 , C08G65/2696
摘要： A continuous process for the preparation of polyoxyalkylene polyethers using DMC catalysts as the polyoxyalkylation catalyst employs continuous addition of alkylene oxide in conjunction with continuous addition of starter and catalyst to a continuous oxyalkylation reactor. Despite the continuous introduction of starter, the molecular weight distribution of the polyether product is quite narrow, as indicated by the exceptionally low polydispersity of the product. The presence of low molecular weight species during the majority of the polyoxyalkylation also substantially eliminates extremely high molecular weight fractions having molecular weights greater than 100,000 Da, again without appreciably broadening molecular weight distribution. By withdrawing intermediate molecular weight polyether product or diverting a portion of the end product to prepare a catalyst/starter mixture, rapid and sustained reaction rates can be achieved while employing low molecular weight starters. Continuous build ratios in excess of 0.98 can be achieved.

4. 发明专利

JP4279363B2 Method of manufacturing the polyol polymer dispersions 失效
公开(公告)号：JP4279363B2
公开(公告)日：2009-06-17
申请号：JP30347296
申请日：1996-10-30
申请人：バイエル・アントウエルペン・コマンディテーレ・フェンノートシャップBayer Antwerpen Comm.V.
发明人：ゾーシンフア , ヴイローズチャールズ , ダブリューシムロスドナルド
IPC分类号： C08G65/30 , C08J9/02 , B01J29/04 , C01B37/00 , C01B39/08 , C07D301/12 , C08G18/08 , C08G18/32 , C08G18/40 , C08G18/48 , C08G18/63 , C08G18/65 , C08G65/02 , C08G65/26 , C08G101/00 , C08L75/00 , C08L75/04
CPC分类号： B01J29/04 , C01B37/005 , C01B39/08 , C07D301/12 , C08G18/0876 , C08G18/409 , C08G18/4866 , C08G18/632 , C08G18/633 , C08G65/2663 , C08G65/30 , C08G2101/0008 , C08G2101/0083
摘要： Polymer polyols and polymer-modified polyols having substantially no transition metal content in the polyol continuous phase may be prepared from encapsulative double metal cyanide complex-catalyzed polyoxyalkylene polyether base polyols without substantial removal of double metal cyanide complex catalyst residues from the base polyol and subsequent in situ polymerization of one or more polymerizable monomers.

8. 发明专利

JP2007291411A Viscosity stable isocyanate-terminated prepolymer and polyoxyalkylene polyether polyol having improved storage stability 有权
标题翻译：粘度稳定的异氰酸酯封端的预聚物和具有改进的储存稳定性的聚氧乙烯聚醚多元醇
公开(公告)号：JP2007291411A
公开(公告)日：2007-11-08
申请号：JP2007212819
申请日：2007-08-17
申请人： Bayer Antwerpen Comm V , バイエル・アントウエルペン・コマンディテーレ・フェンノートシャップBayer Antwerpen Comm.V.
发明人： LAWREY BRUCE D , SENEKER STEPHEN D , BARKSBY NIGEL
IPC分类号： C08G18/48 , C08G65/10 , C08G18/10 , C08G65/02 , C08G65/26
CPC分类号： C08G65/2663 , C08G18/10 , C08G18/48 , C08G18/4866 , C08G18/307
摘要： PROBLEM TO BE SOLVED: To provide polyoxyalkylene polyols having improved storage stability which are prepared using a double metal cyanide complex catalyst.
SOLUTION: The polyoxyalkylene polyols contain from 10 to 1000 ppm (preferably 25 to 250 ppm), of double metal cyanide complex catalysts and/or double metal cyanide complex catalyst residues based on the weight of polyols. Favorably, stabilizing effective amount of antioxidants are added to the polyols. Isocyanate-terminated prepolymers prepared from such polyols are surprisingly viscosity-stable relative to similar prepolymers prepared from polyols not containing double metal cyanide complexes or residues thereof.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供使用双金属氰化物配合物催化剂制备的具有改善的储存稳定性的聚氧化烯多元醇。解决方案：基于多元醇的重量，聚氧化烯多元醇含有10至1000ppm（优选25至250ppm）双金属氰化物配合物催化剂和/或双金属氰化物配合物催化剂残余物。有利的是，将有效量的抗氧化剂稳定化到多元醇中。由这样的多元醇制备的异氰酸酯封端的预聚物相对于由不含双金属氰化物络合物或其残余物的多元醇制备的类似预聚物，令人惊奇的是粘度稳定。版权所有（C）2008，JPO＆INPIT

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