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    • 81. 发明专利
    • NONLINEAR OPTICAL ELEMENT
    • JPS63204235A
    • 1988-08-23
    • JP3728887
    • 1987-02-20
    • NIPPON TELEGRAPH & TELEPHONE
    • SHUDO YOSHITOAMANO MICHIYUKITAKEUCHI YOSHIAKIYAMAMOTO FUMIO
    • G02B6/00C09K19/38G02B6/032G02F1/35G02F1/355G02F1/361G02F1/37G02F1/383
    • PURPOSE:To obtain a nonlinear optical element having excellent long-term reliability and high second harmonic wave by using a specific side chain type liquid crystal high polymer for a core member or clad member of an optical fiber type waveguide. CONSTITUTION:The side chain type liquid crystal high polymer which exhibits large spontaneous polarization in a thermotropic mesomorphic state is used for the core (clad) member and the material having the refractive index lower (higher) than the refractive index of the core (clad) member is used for the clad (core) member to form the optical fiber type waveguide. The side chain type liquid crystal high polymer to be used has chiral carbon atoms and carbonyl group in the side chain of the high polymer and exhibits at least >=1X10 C/m spontaneous polarization in a chiral smectic mesomorphic phase C. The units having the chiral carbon of the side chains are arranged in the direction perpendicular to the fiber axis in a stage for spinning (forming fiber) such side chain type liquid crystal high polymer and the material having the refractive index lower (or higher) than the refractive index of the side chain type liquid crystal high polymer is disposed on the outer (or inner) circumference of the liquid crystal high polymer simultaneously or in a separate state. The element exhibiting the high second harmonic wave is thereby obtd.
    • 82. 发明专利
    • OPTICAL FIBER CORE COVERED WITH LIQUID CRYSTAL HIGH-POLYMER
    • JPS6317410A
    • 1988-01-25
    • JP15985786
    • 1986-07-09
    • NIPPON TELEGRAPH & TELEPHONE
    • TAKEUCHI YOSHIAKISHIYUDO YOSHITOYAMAMOTO FUMIO
    • C03C25/10C08G63/60G02B6/44
    • PURPOSE:To improve the side pressure resistance characteristic of an optical fiber core by using a liquid crystal high polymer material having a rigid component at the main chain or the main chain and side chains as a secondary covering layer. CONSTITUTION:The cases of the composite type liquid crystal high polymer and the main chain type liquid crystal high polymer having the rigid side chains are illustrated. The rectangular parts shown in the figures indicate the rigid component and the waveform parts indicate a resilient component. The improvement in the modulus of elasticity in the longitudinal direction and in the direction perpendicular thereto is thus attained by orienting the rigid component in the side chains in said directions. The materials expressed by, for example, the formula I-formula IV are used as the liquid crystal type side chain. The materials among the formula I-formula IV which do not contain -O-(CH2)n- component are used as the rigid side chain. The side pressure resistance characteristic of the optical fiber core is improved and the reduction in the core diameter is permitted by using the liquid crystal high polymer having the rigid component oriented not only in the longitudinal direction but also in the direction perpendicular thereto as the secondary covering layer of the optical fiber core in the above-mentioned manner.
    • 84. 发明专利
    • OPTICAL FIBER CORE WIRE
    • JPS62115406A
    • 1987-05-27
    • JP25487185
    • 1985-11-15
    • NIPPON TELEGRAPH & TELEPHONE
    • SHIYUDO YOSHITOTAKEUCHI YOSHIAKIYAMAMOTO FUMIO
    • C03C25/10G02B6/44
    • PURPOSE:To obtain the titled wire having a less tendency for increasing the transmission loss due to a change of an used temperature and having an excellent bendability by arranging a coating layer composed of two layers comprising a thermoplastic resin which has a liquid crystal property in a melt state and displays a high elastic modulus and a low coefficient of a linear expansion and a thermoplastic resin having great bendability on the outer side of the optical fiber element wire. CONSTITUTION:The titled wire comprises the 2nd. coating layer 5 of the optical fiber having a relatively large orientation degree and the 3rd. coating layer 6 which is disposed on surroundings of said layer 5 and is the thin film (50-100mum the thickness) and is composed of the thermoplastic resin having a low orientation degree, such as polyamide and polyethylene, etc. In the titled wire, the usual 2nd. coating layer is constituted of a double layers. The distribution of the orientation degree of the 2nd. and 3rd. coating layers is adjusted in such a way that the orientation degree of the outer surface layer (the 3rd. coating layer) makes to the min. value, when the max. elongation force or the max. compression force at the bending of the core wire is loaded. Thus, as the outer surface layer (the 3rd. coating layer) has the lower elastic modulus locally in comparison with that of the inner layer (the 2nd. coating layer), and is rich in the elastic modulus, the titled wire may stand against the large elongation and compression forces resulted in giving the core wire having the excellent bendability.
    • 85. 发明专利
    • PRODUCTION OF OPTICAL FIBER CORE
    • JPS6236047A
    • 1987-02-17
    • JP17248285
    • 1985-08-07
    • NIPPON TELEGRAPH & TELEPHONE
    • YAMAMOTO FUMIOSHIYUDO YOSHITOTAKEUCHI YOSHIAKI
    • C03C25/10B29C47/02G02B6/44
    • PURPOSE:To obtain the titled optical fiber core consisting of a molten liq. crystalline high molecular substance exhibiting a stabilized characteristic by evacuating the space between an optical fiber strand and a molten thermoplastic resin and simultaneously compressing from the outer side of the thermoplastic resin. CONSTITUTION:In the production of an optical fiber core by forming the secondary coated layer 4 of a molten liq. crystalline high molecular substance (hereinafter referred to as LCP) on the outer periphery of an optical fiber strand 3, the space between the optical fiber strand 3 and the molten LCP is evacuated 5 and simultaneously the optical fiber strand 3 and the secondary coated layer 4 of LCP are firmly attached by compression 8 from the outside of LCP. By this method, since the attached point 9 between the optical fiber strand 3 and the secondary coated layer 4 of LCP is controlled by both evacuation and compression, the movement of the attached point 9 causing the variations of the diameter of the optical fiber core and the inclusion of air bubbles can be easily controlled and an optical fiber core exhibiting a stabilized characteristic can be obtained.