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    • 79. 发明专利
    • Water-dispersible resin composition
    • 水分散树脂组合物
    • JPS59217702A
    • 1984-12-07
    • JP9193183
    • 1983-05-24
    • Nippon Paint Co Ltd
    • KIDA KATSUAKINAGATA JIYUNICHIROUKANDA KAZUNORIISHIKURA SHINICHI
    • C08F2/00C08F2/22C08F2/44C08F16/14C08F20/38C08F216/14C08F220/38C08F246/00C08L57/04C09D5/00C09D5/02C09D7/12C09D157/04C09D201/02
    • PURPOSE: To provide the titled stable composition giving a coating film having excellent water resistance, alkali resistance and blocking resistance, by polymerizing a monomer containing conjugated unsaturated bonds in the presence of colloidal silica and a specific amount of a monomer having emulsifying function in the molecule.
      CONSTITUTION: The objective resin composition can be prepared by polymerizing (A) one or more polymerizable monomers having conjugated unsaturated bonds in the presence of (B) 0.05W5wt%, based on the whole monomer, of a polymerizable monomer having emulsifying function in the molecule and (C) 0.1W4wt% of colloidal silica in terms of solid. The polymerizable monomer having emulsifying function in the molecule is e.g. a nonionic polymerization monomer of formula (R
      1 is H, lower alkyl, halogen or phenyl; R
      2 is ethylene or propylene; R
      3 is H or lower alkyl; n is integer of 4W25).
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过在胶体二氧化硅的存在下聚合含有共轭不饱和键的单体和在分子中具有乳化功能的单体的特定量,提供具有优异的耐水性,耐碱性和耐粘连性的涂膜的标题稳定组合物 。 构成:目标树脂组合物可以通过在(B)0.05-5重量%存在下(A)一种或多种具有共轭不饱和键的可聚合单体(基于整个单体)聚合(A)一种具有乳化功能的可聚合单体的聚合单体 分子和(C)以固体计0.1-4重量%的胶体二氧化硅。 分子中具有乳化功能的可聚合单体是例如。 式(R1为H,低级烷基,卤素或苯基; R2为乙烯或丙烯; R3为H或低级烷基; n为4-25的整数)的非离子聚合单体。
    • 80. 发明专利
    • Acrylic emulsion
    • 丙烯酸乳液
    • JPS58206604A
    • 1983-12-01
    • JP9106582
    • 1982-05-27
    • Nippon Paint Co Ltd
    • KUWAJIMA TERUAKIKANDA KAZUNORIISHIKURA SHINICHIMIZUGUCHI RIYUUZOU
    • C08F2/00C08F2/26C08F12/00C08F20/00C08F20/10C08F20/34C08F20/38C08F30/00C08F30/02C08F212/34C08F220/20C08F220/38C08F220/40C08F230/02C08G59/00C08G59/18C08G59/40C09D5/00C09D5/02C09D5/08C09D5/12C09D101/08C09D125/00C09D125/02C09D133/04
    • PURPOSE: The titled emulsion that is obtained by emulsion polymerization of α,β-ethylenically unsaturated monomers in the presence of a water-soluble polymeric emulsifier such as polyacrylic acid, thus giving coating films, which are chemically stable to metal ions and have high resistance to folding and scratching.
      CONSTITUTION: The objective emulsion is obtained by emulsion polymerization of α,β-ethylenically unsaturated monomers containing at least one selected from monomers having 2 or more radically polymerizable ethylenenically unsaturated groups in the molecule in an aqueous medium in the presence of an emulsifier of more than 5pts.wt., per 100pts.wt. of the monomer, of polyacrylic acid and/or a copolymer from more than 50% acrylic acid and at least one selected from methacrylic acid, acrylic or methacrylic acid amides and hydrophilic monomers of the formula (A is H, methyl; R is 2W4C alkylene; X is functional group containing at least one of O, P, S) such as 2-hydroxyethyl methacrylate.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:在水溶性聚合物乳化剂如聚丙烯酸存在下,通过α,β-烯键式不饱和单体的乳液聚合获得的标题乳液,从而得到与金属离子化学稳定并具有高电阻的涂膜 折叠和划伤。 构成:通过在水分介质中在乳化剂存在下,在含有选自具有2个或更多个可自由基聚合的烯属不饱和基团的单体中的至少一种选自α,β-烯键式不饱和单体的乳液聚合, 5pts.wt.,每100pts.wt。 的单体,聚丙烯酸和/或来自大于50%丙烯酸和选自甲基丙烯酸,丙烯酸或甲基丙烯酸酰胺中的至少一种的共聚物和/或下式的亲水性单体(A为H,甲基; R为2- 4C亚烷基; X是含有O,P,S中的至少一个的官能团),例如甲基丙烯酸2-羟乙酯。